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Development of ultrathin niobium nitride and niobium titanium nitride films for THz hot-electron bolometers

S. Bedorf

Published Jan 1, 2005• 4 citations
Publisher

Abstract

The main focus of this work is the development of ultrathin NbN and NbTiN films. A reproducible and reliable deposition process for ultrathin NbN and NbTiN films for the use in phonon-cooled HEB devices was established. The ultrathin films were deposited on silicon (Si) substrates and on 2æm Si3N4 membranes by DC reactive magnetron sputtering. A method for the precise control of the nitrogen partial pressure by monitoring the target voltage has been introduced to deposit high quality, ultrathin NbN (3-4nm, Tc=8.5 K) and NbTiN (4-5nm, Tc=8K) films. Substrate heating of at least 600ʿC during the deposition is essential for the fabrication of ultrathin NbN and NbTiN films on Si substrates and Si3N4 membranes. The fabrication process required for HEB devices to be used in a quasi-optical mixer was developed. The ultrathin film was patterned by electron beam lithography (EBL), resulting in bolometer devices that measure areas of about 0.4 æm x 4 æm. The nature of the contact determines the interface transparency between the bolometer and the contact structure. Different cleaning processes have been performed and the influence on the contact resistance has been instigated. A better interface transparency gives less RF losses and could improve the HEB sensitivity and local oscillator (LO) requirement ...

DOI
10.23689/fidgeo-131

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The main focus of this work is the development of ultrathin NbN and NbTiN films. A reproducible and reliable deposition process for ultrathin NbN and NbTiN films for the use in phonon-cooled HEB devices was established. The ultrathin films were deposited on silicon (Si) substrates and on 2æm Si3N4 membranes by DC reactive magnetron sputtering. A method for the precise control of the nitrogen partial pressure by monitoring the target voltage has been introduced to deposit high quality, ultrathin NbN (3-4nm, Tc=8.5 K) and NbTiN (4-5nm, Tc=8K) films. Substrate heating of at least 600ʿC during the deposition is essential for the fabrication of ultrathin NbN and NbTiN films on Si substrates and Si3N4 membranes. The fabrication process required for HEB devices to be used in a quasi-optical mixer was developed. The ultrathin film was patterned by electron beam lithography (EBL), resulting in bolometer devices that measure areas of about 0.4 æm x 4 æm. The nature of the contact determines the interface transparency between the bolometer and the contact structure. Different cleaning processes have been performed and the influence on the contact resistance has been instigated. A better interface transparency gives less RF losses and could improve the HEB sensitivity and local oscillator (LO) requirement ...
Experimental work on the development of a quasi-optical heterodyne receiver for the THz frequency range is reported. The mixing device is a superconducting hot electron bolometer (HEB) made from ultrathin, d = 3 - 5 nm, niobium nitride (NbN) films. Work described in this thesis comprises: The design of a prototype receiver using quasi-optical coupling. Device fabrication involving reactive magnetron sputtering of NbN films and lithographic definition of the antenna integrated mixer. An investigation of the receiver performance at frequencies between 0.6 THz and 2.5 THz. The best performance is obtained with HEB mixers made from NbN films with a thickness d = 3-3.5 nm and a critical temperature T c = 9 - 9.5 K. Double-side band receiver noise temperatures are 530 K at 0.6 THz, 650 K at 1.6 THz and 1100 K at 2.5 THz. Corrected for losses in the receiver input optics, these values amount to only 10 times the theoretical quantum limit. MgO as the substrate material has been shown to provide improved acoustic coupling between NbN film and the substrate compared to other materials such as Si or sapphire. A maximum IF gain bandwidth of 4.5 GHz has been measured under the same operating conditions which yield lowest noise temperature. The local oscilltor power requirement is ~250 nW absorbed in the bolometer. Quasi-optically coupled HEB mixers have become the device-of-choice for radio astronomical applications in the frequency regime at and above 1 THz.
Hot electron bolometer mixers (HEBM) are expected to be used as low-noise heterodyne mixers in the terahertz frequency range. We are developing quasi-optical HEBMs for applications such as atmospheric remote sensing and radio astronomy in the terahertz frequency range. Therefore, we developed a fabrication method using niobium nitride (NbN) ultrathin films deposited on a silicone (Si) substrate for terahertz applications. First, a magnesium oxide buffer layer 50 nm thick was deposited on a Si substrate at approximately 525 °C. After deposition of this layer, NbN ultrathin films were deposited at ambient temperature. Using the buffer layers, we found the transition temperature of the 3.5-nm-thick NbN thin films to be approximately 10 K. The same method was applied to fabricate NbN-HEBMs on a Si substrate. The fabricated quasi-optical mixers were designed to operate at 3.1 THz. The receiver noise temperature was found to be approximately 1930 K (DSB) at 3.1 THz.
The key of improving hot-electron bolometer (HEB) mixer performance lies inevitably in the quality of ultra-thin NbN films itself. This work presents a thorough investigation of crucial process parameters of NbN films deposited by means of reactive DC-sputtering on Si-substrates at elevated temperatures up to 750°C.The polycrystalline NbN films with thickness of 4 to 10nm were characterized by DC resistivity measurements, ellipsometry and high resolution transmission electron microscopy (HRTEM) in order to confirm thickness and film structure. Since the macroscopic properties such as critical temperature, thickness as well as the transition width to the superconducting state are directly linked to HEB mixer noise temperature and IF bandwidth, a set of experiments were conducted to enhance aforementioned properties. We considered deposition temperature, RF biasing, nitrogen and argon partial and total pressure during deposition as major process variable parameters. Careful optimization of the deposition conditions allowed setting up a process resulting in high-quality NbN ultra-thin films with thickness of 5.5nm exhibiting Tc of 10.5K. Moreover, the transition width could be kept as low as 1.4K. The produced films were stored at ambient conditions and re-characterized over a period of 4 month without measurable degradation.
Superconducting Hot-electron Bolometric (HE.B) mixers employing thin films ofNbN have become the devices of choice for heterodyne detection at tera,hertz frequen- cies. HEB mixers are inherently insensitive to the bandgap frequency of the superconducting material used in the device, in contrast to SIS mixers,. We have developed a fabrication pro- cess for thin NbN films at the National Institute of Standards and Technology in Boulder, CO. A two-fold approach can be taken. The first is to maximize the critical temperature of the superconducting device by growing thicker films at the expense of IF bandwidth, whereas the second approach focuses on maximizing the IF bandwidth at the expense of the critical tem- perature. So far, we have developed a film-deposition process utilizing our DC reactive mag- netron sputtering chamber. By current-biasing the RF plasma in a mixture of Ar and N2, while using a Nb target, we can control the film stoichiometry and produce films with thicknesses of 5 nm. The films are deposited on MgO substrates that are heated to about 800 °C during depo- sition. A typical critical temperature (TO is about 10 K and the transition width is very small (0.5 K). The films are evaluated by measuring their superconducting characteristics as well as their thickness and surface roughness by means of AFM analysis. Phonon-cooled HEB devices are fabricated from the films to study their performance as HEB mixers. The device fabrication process at UMass/Amherst involves lift-off lithography of the antenna (gold), and Reactive ion etching (R1E) or wet etching of the NbN. The I-V char- acteristics and noise temperatures of the devices were measured in order to determine their quality for PHEB applications.
The paper reports the latest development and the measured results of NbTiN hot electron bolometer mixers at THz frequencies. The devices are based on 4-7 nm thin NbTiN films, which were deposited by reactive magnetron sputtering of NbTi target in an Ar/N2 atmosphere, on heated high-resistivity Si substrates over a 20 nm thick AlN buffer layer. The quality parameters of the film are transition temperature and normal-state resistivity, which were optimized by varying the sputtering parameters. The resistivity and the critical temperature of the films are about 400 μΩcm and 9 K, respectively. Bolometers (4 μm wide and 0.7 μm long), integrated with logarithmic spiral antennas are fabricated. Mixer noise performance is tested in a quasi-optical receiver in 1.5-4 GHz IF band. The DSB receiver noise temperature of 700 K, 1100 K and 3000 K is obtained at 0.7, 1.6 and 2.6 THz LO frequencies, respectively.
This work is devoted to the investigation of the applicability of NbZr as a new material for wideband hot- electron bolometer (HEB) mixer, which is a device of choice for most of low noise heterodyne receivers operating above 1 THz in astronomy applications. Although currently 10-nm NbZr films offer a maximum gain bandwidth of only 450 MHz at Tc on sapphire substrates, there is every reason to believe that the above result can be improved by decreasing the film thickness and using other substrate material which will provide better acoustic match with NbZr. operation can be described by relatively simple equations for the heat balance, and the mixer's roll-off frequency is completely determined by several time constants of the film material ((10),(11)). The values of these characteristic times can be obtained from the dependence of the gain bandwidth on temperature and film thickness. For the electron temperature to be uniform throughout the bridge it is necessary that either the LO frequency be greater than the superconductor gap frequency, or that the ambient temperature be about Tc (in the latter case the LO frequency need not exceed the gap frequency of the unheated superconductor). Also the bolometer bias should be small and the power levels of the oscillators should not influence the operating point of the bolometer. In this paper we study deposition process of ultrathin NbZr films on sapphire substrates, gain bandwidth of NbZr bolometers and the possibly of using this material as a new material for HEB mixers.