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arXiv:2107.05952 · Physical Review A

Thermodynamics of a continuous quantum heat engine: Interplay between population and coherence

Pablo Bayona-Pena, Kazutaka Takahashi

Published Oct 5, 2021• 11 citations
arXivHTMLPDF

Abstract

We present a detailed thermodynamic analysis of a three-level quantum heat engine coupled continuously to hot and cold reservoirs. The system is driven by an oscillating external field and is described by the Markovian quantum master equation. We use the general form of the dissipator which is consistent with thermodynamics. We calculate the heat, power, and efficiency of the system for the heat-engine operating regime and also examine the thermodynamic uncertainty relation. The efficiency of the system is strongly dependent on the structure of the dissipator, and the correlations between different levels can be an obstacle for ideal operation. In quantum systems, the heat flux is decomposed into the population and coherent parts. The coherent part is specific to quantum systems, and in contrast to the population part, it cannot be expressed by a simple series expansion in the linear-response regime. We discuss how the interplay between the population and coherent parts affects the performance of the heat engine.

DOI
10.1103/physreva.104.042203

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We present a detailed thermodynamic analysis of a three-level quantum heat engine coupled continuously to hot and cold reservoirs. The system is driven by an oscillating external field and is described by the Markovian quantum master equation. We use the general form of the dissipator which is consistent with thermodynamics. We calculate the heat, power, and efficiency of the system for the heat-engine operating regime and also examine the thermodynamic uncertainty relation. The efficiency of the system is strongly dependent on the structure of the dissipator, and the correlations between different levels can be an obstacle for ideal operation. In quantum systems, the heat flux is decomposed into the population and coherent parts. The coherent part is specific to quantum systems, and in contrast to the population part, it cannot be expressed by a simple series expansion in the linear-response regime. We discuss how the interplay between the population and coherent parts affects the performance of the heat engine.
We consider a recently proposed four-level quantum heat engine (QHE) model to analyze the role of quantum coherences in determining the thermodynamic properties of the engine, such as flux, output power, and efficiency. A quantitative analysis of the relative effects of the coherences induced by the two thermal baths is brought out. By taking account of the dissipation in the cavity mode, we define useful work obtained from the QHE and present some analytical results for the optimal values of relative coherences that maximizes flux (hence output power) through the engine. We also analyze the role of quantum effects in inducing population inversion (lasing) between the states coupled to the cavity mode. The universal behavior of the efficiency at maximum power (EMP\mathrm{EMP}EMP) is examined. In accordance with earlier theoretical predictions, to leading order, we find that $\mathrm{EMP}\ensuremath{\sim}{\ensuremath{\eta}}_{c}/2$, where ${\ensuremath{\eta}}_{c}$ is Carnot efficiency. However, the next higher order coefficient is system dependent and hence nonuniversal.
Quantum coherence can affect the thermodynamics of small quantum systems. Coherences have been shown to affect the power generated by a quantum heat engine (QHE) which is coupled to two thermal photon reservoirs and to an additional cavity mode. We show that the fluctuations of the heat exchanged between the QHE and the reservoirs strongly depend on quantum coherence, especially when the engine operates as a refrigerator, i.e., heat current flows from the cold bath to the hot bath. Intriguingly, we find that the ratio of positive and negative (with respect to the thermodynamic force) fluctuations in the heat current satisfies a universal coherence-independent fluctuation theorem.
Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to a single few-level system coupled to the environment. Once the environment is split into three (a hot, cold, and work reservoir), a heat engine can operate. The device converts the positive gain into power, with the gain obtained from population inversion between the components of the device. Reversing the operation transforms the device into a quantum refrigerator. The quantum tricycle, a device connected by three external leads to three heat reservoirs, is used as a template for engines and refrigerators. The equation of motion for the heat currents and power can be derived from first principles. Only a global description of the coupling of the device to the reservoirs is consistent with the first and second laws of thermodynamics. Optimization of the devices leads to a balanced set of parameters in which the couplings to the three reservoirs are of the same order and the external driving field is in resonance. When analyzing refrigerators, one needs to devote special attention to a dynamical version of the third law of thermodynamics. Bounds on the rate of cooling when Tc→0 are obtained by optimizing the cooling current. All refrigerators as Tc→0 show universal behavior. The dynamical version of the third law imposes restrictions on the scaling as Tc→0 of the relaxation rate γc and heat capacity cV of the cold bath.
We study the unitary time evolution of a simple quantum Hamiltonian describing a heat engine coupled to two heat baths. The engine is modeled as a three-level system. Each heat bath consists of a single harmonic oscillator. The engine is operated via time-dependent external fields. The S-matrix of the thermodynamic cycle is obtained in analytic form. We conjecture that the spectrum of this S-matrix contains a continuous part, and that this is a requirement for the operation as a heat engine. Energy currents flow in both directions through the engine. The balance of these currents determines whether the engine performs work or whether its operation requires the application of external forces.
Abstract We work on a comprehensive theoretical investigation of a three-level quantum heat engine operating with engineered squeezed thermal reservoirs. Unlike conventional quantum heat engines that use thermal reservoirs, we demonstrate that squeezed reservoirs can significantly enhance the engine's performance by increasing both efficiency and output power. Using a rigorous open-quantum-system approach, we derive the full Lindblad master equation for a three-level system interacting with hot and cold squeezed thermal baths. Through a detailed analysis of the steady-state thermodynamics, we obtain explicit expressions for heat currents, work output, and efficiency. Our results reveal that moderate squeezing parameters (r≈0.5r \approx 0.5r≈0.5) combined with optimal squeezing phase (ϕ=π/2\phi = \pi/2ϕ=π/2) enhance the engine efficiency by up to 40\% compared to the classical Carnot limit for the same temperature ratio. The power output shows a non-monotonic behavior with squeezing, exhibiting an optimal squeezing parameter that maximizes performance. We identify three distinct operational regimes: (i) heat engine regime, (ii) refrigerator regime, and (iii) heat pump regime, which can be tuned by adjusting the squeezing phase. The efficiency at maximum power follows a universal scaling ηMP≈ηCarnot/2+Δη(r)\eta_{MP} \approx \eta_{Carnot}/2 + \Delta\eta(r)ηMP​≈ηCarnot​/2+Δη(r), where Δη(r)\Delta\eta(r)Δη(r) represents the squeezing-induced enhancement. Our findings provide fundamental insights into the role of non-thermal reservoirs in quantum thermodynamics and offer practical guidelines for designing high-performance quantum heat engines using squeezed light and engineered baths.
We investigate the quantum thermodynamics of two quantum systems, a two-level system and a four-level quantum photocell, each driven by photon pulses as a quantum heat engine. We set these systems to be in thermal contact only with a cold reservoir while the heat (energy) source, conventionally given from a hot thermal reservoir, is supplied by a sequence of photon pulses. The dynamics of each system is governed by a coherent interaction due to photon pulses in terms of the Jaynes-Cummings Hamiltonian together with the system-bath interaction described by the Lindblad master equation. We calculate the thermodynamic quantities for the two-level system and the quantum photocell including the change in system energy, the power delivered by photon pulses, the power output to an external load, the heat dissipated to a cold bath, and the entropy production. We thereby demonstrate how a quantum photocell in the cold bath can operate as a continuum quantum heat engine with a sequence of photon pulses continuously applied. We specifically introduce the power efficiency of the quantum photocell in terms of the ratio of output power delivered to an external load with current and voltage to the input power delivered by the photon pulse. Our study indicates a possibility that a quantum system driven by external fields can act as an efficient quantum heat engine under non-equilibrium thermodynamics.