Quantum coherence can affect the thermodynamics of small quantum systems. Coherences have been shown to affect the power generated by a quantum heat engine (QHE) which is coupled to two thermal photon reservoirs and to an additional cavity mode. We show that the fluctuations of the heat exchanged between the QHE and the reservoirs strongly depend on quantum coherence, especially when the engine operates as a refrigerator, i.e., heat current flows from the cold bath to the hot bath. Intriguingly, we find that the ratio of positive and negative (with respect to the thermodynamic force) fluctuations in the heat current satisfies a universal coherence-independent fluctuation theorem.
Quantum coherence can affect the thermodynamics of small quantum systems. Coherences have been shown to affect the power generated by a quantum heat engine (QHE) which is coupled to two thermal photon reservoirs and to an additional cavity mode. We show that the fluctuations of the heat exchanged between the QHE and the reservoirs strongly depend on quantum coherence, especially when the engine operates as a refrigerator, i.e., heat current flows from the cold bath to the hot bath. Intriguingly, we find that the ratio of positive and negative (with respect to the thermodynamic force) fluctuations in the heat current satisfies a universal coherence-independent fluctuation theorem.
We consider a recently proposed four-level quantum heat engine (QHE) model to analyze the role of quantum coherences in determining the thermodynamic properties of the engine, such as flux, output power, and efficiency. A quantitative analysis of the relative effects of the coherences induced by the two thermal baths is brought out. By taking account of the dissipation in the cavity mode, we define useful work obtained from the QHE and present some analytical results for the optimal values of relative coherences that maximizes flux (hence output power) through the engine. We also analyze the role of quantum effects in inducing population inversion (lasing) between the states coupled to the cavity mode. The universal behavior of the efficiency at maximum power (EMP) is examined. In accordance with earlier theoretical predictions, to leading order, we find that $\mathrm{EMP}\ensuremath{\sim}{\ensuremath{\eta}}_{c}/2$, where ${\ensuremath{\eta}}_{c}$ is Carnot efficiency. However, the next higher order coefficient is system dependent and hence nonuniversal.
At the very foundation of the second law of thermodynamics lies the fact that no heat engine operating between two reservoirs of temperatures T C ⩽ T H can outperform the ideal Carnot engine: 〈 W 〉/〈 Q H 〉 ⩽ 1 − T C / T H . This inequality follows from an exact fluctuation relation involving the nonequilibrium work W and heat exchanged with the hot bath Q H . In a previous work (Sinitsyn 2011 J. Phys. A: Math. Theor. 44 405001) this fluctuation relation was obtained under the assumption that the heat engine undergoes a stochastic jump process. Here we provide the general quantum derivation, and also extend it to the case of refrigerators, in which case Carnot's statement reads 〈 Q C 〉/|〈 W 〉| ⩽ ( T H / T C − 1) −1 .
The single-atom version of the quantum heat engine based on electromagnetically induced transparency is theoretically investigated in this paper. In contact with a hot and a cold bath, the atom trapped in an optical cavity is coherently coupled by a coherent field, thus generating photons as output through a process that mimics a heat engine. Using semiclassical theory, we obtain the conditions for the classical gain parameter being positive. Then by taking a full quantum approach, we discuss the statistical property of the generated photons depicted by the photon number distribution and Wigner function, and show that it can be effectively tuned by the coupling field. Investigations on the energy and entropy balances of the heat engine process lead to an interesting result that the power of the engine is simply the energy per time provided by the hot reservoir. The coupling field plays a critical role in supporting the heat-engine process. However, the energy that it provides is all dumped into the cold reservoir. The total energy exchange conforms to the first law of thermodynamics. The efficiency of the engine depends on the temperatures of the two reservoirs and the strength of the coupling field. The entropy change of the heat-engine process suggests that when working far above the threshold of lasing, the efficiency approaches that of its atomic-ensemble-based partner.
We present a detailed thermodynamic analysis of a three-level quantum heat engine coupled continuously to hot and cold reservoirs. The system is driven by an oscillating external field and is described by the Markovian quantum master equation. We use the general form of the dissipator which is consistent with thermodynamics. We calculate the heat, power, and efficiency of the system for the heat-engine operating regime and also examine the thermodynamic uncertainty relation. The efficiency of the system is strongly dependent on the structure of the dissipator, and the correlations between different levels can be an obstacle for ideal operation. In quantum systems, the heat flux is decomposed into the population and coherent parts. The coherent part is specific to quantum systems, and in contrast to the population part, it cannot be expressed by a simple series expansion in the linear-response regime. We discuss how the interplay between the population and coherent parts affects the performance of the heat engine.
Abstract Understanding how coherence of quantum systems affects thermodynamic quantities, such as work and heat, is essential for harnessing quantumness effectively in thermal quantum technologies. Here, we study the unique contributions of quantum coherence among different subsystems of a multipartite system, specifically in non-equilibrium steady states, to work and heat currents. Our system comprises two coupled ensembles, each consisting of N particles, interacting with two baths of different temperatures, respectively. The particles in an ensemble interact with their bath either simultaneously or sequentially, leading to non-local dissipation and enabling the decomposition of work and heat currents into local and non-local components. We find that the non-local heat current, as well as both the local and non-local work currents, are linked to the system quantum coherence. We provide explicit expressions of coherence-related quantities that determine the work currents under various intrasystem interactions. Our scheme is versatile, capable of functioning as a refrigerator, an engine, and an accelerator, with its performance being highly sensitive to the configuration settings. These findings establish a connection between thermodynamic quantities and quantum coherence, supplying valuable insights for the design of quantum thermal machines.
Understanding how coherence of quantum systems affects thermodynamic quantities, such as work and heat, is essential for harnessing quantumness effectively in thermal quantum technologies. Here, we study the unique contributions of quantum coherence among different subsystems of a multipartite system, specifically in non-equilibrium steady states, to work and heat currents. Our system comprises two coupled ensembles, each consisting of N particles, interacting with two baths of different temperatures, respectively. The particles in an ensemble interact with their bath either simultaneously or sequentially, leading to non-local dissipation and enabling the decomposition of work and heat currents into local and non-local components. We find that the non-local heat current, as well as both the local and non-local work currents, are linked to the system quantum coherence. We provide explicit expressions of coherence-related quantities that determine the work currents under various intrasystem interactions. Our scheme is versatile, capable of functioning as a refrigerator, an engine, and an accelerator, with its performance being highly sensitive to the configuration settings. These findings establish a connection between thermodynamic quantities and quantum coherence, supplying valuable insights for the design of quantum thermal machines.