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Physical Review A

Thermodynamics of quantum heat engines

Himangshu Prabal Goswami, Upendra Harbola

Published Jul 26, 2013• 75 citations
Publisher

Abstract

We consider a recently proposed four-level quantum heat engine (QHE) model to analyze the role of quantum coherences in determining the thermodynamic properties of the engine, such as flux, output power, and efficiency. A quantitative analysis of the relative effects of the coherences induced by the two thermal baths is brought out. By taking account of the dissipation in the cavity mode, we define useful work obtained from the QHE and present some analytical results for the optimal values of relative coherences that maximizes flux (hence output power) through the engine. We also analyze the role of quantum effects in inducing population inversion (lasing) between the states coupled to the cavity mode. The universal behavior of the efficiency at maximum power ($\mathrm{EMP}$) is examined. In accordance with earlier theoretical predictions, to leading order, we find that $\mathrm{EMP}\ensuremath{\sim}{\ensuremath{\eta}}_{c}/2$, where ${\ensuremath{\eta}}_{c}$ is Carnot efficiency. However, the next higher order coefficient is system dependent and hence nonuniversal.

DOI
10.1103/physreva.88.013842

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We consider a recently proposed four-level quantum heat engine (QHE) model to analyze the role of quantum coherences in determining the thermodynamic properties of the engine, such as flux, output power, and efficiency. A quantitative analysis of the relative effects of the coherences induced by the two thermal baths is brought out. By taking account of the dissipation in the cavity mode, we define useful work obtained from the QHE and present some analytical results for the optimal values of relative coherences that maximizes flux (hence output power) through the engine. We also analyze the role of quantum effects in inducing population inversion (lasing) between the states coupled to the cavity mode. The universal behavior of the efficiency at maximum power (EMP\mathrm{EMP}EMP) is examined. In accordance with earlier theoretical predictions, to leading order, we find that EMP\ensuremath∼\ensuremathηc/2\mathrm{EMP}\ensuremath{\sim}{\ensuremath{\eta}}_{c}/2EMP\ensuremath∼\ensuremathηc​/2, where \ensuremathηc{\ensuremath{\eta}}_{c}\ensuremathηc​ is Carnot efficiency. However, the next higher order coefficient is system dependent and hence nonuniversal.
Quantum coherence has been demonstrated in various systems including organic solar cells and solid state devices. In this article, we report the lower and upper bounds for the performance of quantum heat engines determined by the efficiency at maximum power. Our prediction based on the canonical three-level Scovil and Schulz-Dubois maser model strongly depends on the ratio of system-bath couplings for the hot and cold baths and recovers the theoretical bounds established previously for the Carnot engine. Further, introducing a fourth level to the maser model can enhance the maximal power and its efficiency, thus demonstrating the importance of quantum coherence in the thermodynamics and operation of the heat engines beyond the classical limit.
Quantum coherence can affect the thermodynamics of small quantum systems. Coherences have been shown to affect the power generated by a quantum heat engine (QHE) which is coupled to two thermal photon reservoirs and to an additional cavity mode. We show that the fluctuations of the heat exchanged between the QHE and the reservoirs strongly depend on quantum coherence, especially when the engine operates as a refrigerator, i.e., heat current flows from the cold bath to the hot bath. Intriguingly, we find that the ratio of positive and negative (with respect to the thermodynamic force) fluctuations in the heat current satisfies a universal coherence-independent fluctuation theorem.
We generalize the quantum heat engine (QHE) model which was first proposed by Bender et al. [J. Phys. A 33, 4427 (2000)] to the case in which an ideal Fermi gas with an arbitrary number N of particles in a box trap is used as the working substance. Besides two quantum adiabatic processes, the engine model contains two isoenergetic processes, during which the particles are coupled to energy baths at a high constant energy E(h) and a low constant energy E(c), respectively. Directly employing the finite-time thermodynamics, we find that the power output is enhanced by increasing particle number N (or decreasing minimum trap size L(A)) for given L(A) (or N), without reduction in the efficiency. By use of global optimization, the efficiency at possible maximum power output (EPMP) is found to be universal and independent of any parameter contained in the engine model. For an engine model with any particle-number N, the efficiency at maximum power output (EMP) can be determined under the condition that it should be closest to the EPMP. Moreover, we extend the heat engine to a more general multilevel engine model with an arbitrary 1D power-law potential. Comparison between our engine model and the Carnot cycle shows that, under the same conditions, the efficiency η = 1 - E(c)/E(h) of the engine cycle is bounded from above the Carnot value η(c) =1 - T(c)/T(h).
In this paper, we consider a model of two-level quantum heat engine to investigate the explicit analytic expression for the thermodynamics quantities in different condition under the finite-time operation. In this engine, the working substance is composed of a spin-half particles immersed in a magnetic field. The finite-time thermodynamic processes consisting of two quantum adiabatic and two quantum isothermal processes. This processes working between two heat reservoirs with an inverse temperatures β1β_{1}β1​ and β2β_{2}β2​ (<β1<β_{1}<β1​). In this processes, we obtain the work, heat, power and efficiency at maximum power output of the model. Our result of the efficiency at maximum power agree with the universal value in the first order of Carnot efficiency.
Quantum heat engines (QHE) are thermal machines where the working substance is quantum. In the extreme case the working medium can be a single particle or a few level quantum system. The study of QHE has shown a remarkable similarity with the standard thermodynamical models, thus raising the issue what is quantum in quantum thermodynamics. Our main result is thermodynamical equivalence of all engine type in the quantum regime of small action. They have the same power, the same heat, the same efficiency, and they even have the same relaxation rates and relaxation modes. Furthermore, it is shown that QHE have quantum-thermodynamic signature, i.e thermodynamic measurements can confirm the presence of quantum coherence in the device. The coherent work extraction mechanism enables power outputs that greatly exceed the power of stochastic (dephased) engines.
Abstract We work on a comprehensive theoretical investigation of a three-level quantum heat engine operating with engineered squeezed thermal reservoirs. Unlike conventional quantum heat engines that use thermal reservoirs, we demonstrate that squeezed reservoirs can significantly enhance the engine's performance by increasing both efficiency and output power. Using a rigorous open-quantum-system approach, we derive the full Lindblad master equation for a three-level system interacting with hot and cold squeezed thermal baths. Through a detailed analysis of the steady-state thermodynamics, we obtain explicit expressions for heat currents, work output, and efficiency. Our results reveal that moderate squeezing parameters (r≈0.5r \approx 0.5r≈0.5) combined with optimal squeezing phase (ϕ=π/2\phi = \pi/2ϕ=π/2) enhance the engine efficiency by up to 40\% compared to the classical Carnot limit for the same temperature ratio. The power output shows a non-monotonic behavior with squeezing, exhibiting an optimal squeezing parameter that maximizes performance. We identify three distinct operational regimes: (i) heat engine regime, (ii) refrigerator regime, and (iii) heat pump regime, which can be tuned by adjusting the squeezing phase. The efficiency at maximum power follows a universal scaling ηMP≈ηCarnot/2+Δη(r)\eta_{MP} \approx \eta_{Carnot}/2 + \Delta\eta(r)ηMP​≈ηCarnot​/2+Δη(r), where Δη(r)\Delta\eta(r)Δη(r) represents the squeezing-induced enhancement. Our findings provide fundamental insights into the role of non-thermal reservoirs in quantum thermodynamics and offer practical guidelines for designing high-performance quantum heat engines using squeezed light and engineered baths.