Micro-fabricated superconducting circuits have emerged as a leading candidate for quantum computers. However, typical error rates of 10-3 for quantum gates remain a challenge for performing error correction and need to be further decreased for achieving practical quantum computation. Improving qubit coherence times for superconducting qubits is a continuous endeavor in order to decrease error rates. As part of this effort, a topic addressed in this dissertation is the study of the generation mechanism and dynamics of non-equilibrium quasiparticles (QPs), which are electron-like excitations of a superconductor. This source of decoherence was studied by measuring the rate of single-electron changes in the parity state of multiple charge-sensitive transmon qubits under different conditions. The presence of non-equilibrium QPs in superconducting resonators and qubits operating at millikelvin temperature has been known for decades. Understanding the sources and dynamics of these QPs is crucial to evaluate and improve the performance of the devices. Specifically, for superconducting qubits, a single QP tunneling across the Josephson junction changes the total charge parity from even to odd or vice versa, and can induce energy relaxation and dephasing, limiting the coherence of the device. To study the dynamics of non-equilibrium QPs, I utilized a Ramsey-like pulse sequence to measure the rate of single-electron parity changes in transmon qubits, which had a weak charge dispersion, with different shunting capacitor geometries and materials. I started out by measuring a charge parity rate of ~ 33 s-1 for a grounded "x-mon" qubit and ~ 17 s-1 for a galvanically isolated "two-pads" qubit with our standard setup. These rates decreased to ~ 5 s-1 and ~ 2 s-1 for the x-mon and two-pads respectively when IR-filters and extra layers of shielding were installed. From my measurements, I found that the charge parity rates are sensitive to the geometry of the shunting capacitor, weakly depend on the amount of shielding surrounding the device, and independent of using Al or Ta for the superconducting shunting capacitor. To distinguish between two possible mechanisms for the parity switching, I measured the parity rates after cooling one of the qubit devices in an external magnetic field to induce vortices in the superconducting electrodes. After increasing the magnetic field above 23 μT, I measured a faster QP trapping rate and a much smaller T1, suggesting that at least one vortex was added to the superconducting electrode near the Josephson junction. On the other hand, the measured charge parity rates exhibited no clear dependence on the background QP trapping rates. These data suggest that a large portion of parity switching events occurs from QPs being produced at the Josephson junction, where pair-breaking radiation is rectified into QPs by the junction, as opposed to tunneling of QPs residing in the electrodes. To understand the difference in the measured parity rates, I simulated the absorption efficiency of pair-breaking radiation for my two designs and observed a similar difference in absorption rates when a single-mode blackbody radiation with an effective temperature T* ~ 300 mK was assumed to be illuminating the devices. This large T*, which is significantly higher than the device's nominal temperature of 20 mK, is consistent with values reported in the literature. However, its physical origin remains not fully understood. For the other part of my dissertation, I developed a new simplified process for making superconducting air bridges. Air bridges are used to suppress unwanted extraneous high frequency chip modes parasitic to superconducting quantum circuits that can couple to qubits and cause decoherence. Traditional ways of making air bridges utilize thermal reflow to create arched photoresist scaffolds that are limited in heights. This results in insufficient mechanical strength of the bridges which tend to collapse when spanning to larger lengths. My simplified fabrication method that utilizes two-photon lithography, a technique that enables creation of three-dimensional micron-scale structures, relaxes this limitation and is capable of making mechanically stable bridges with lengths up to 100 μm. The resulting Al air bridges, having a superconducting transition temperature of Tc = 1.08 mK and a dc residual resistivity ratio of 3.85, were confirmed to form a good electrical contact with the base metal layers and exhibit a small measurable amount of rf loss when placed over coplanar waveguide resonators, on par with other air bridge fabrication methods.
Micro-fabricated superconducting circuits have emerged as a leading candidate for quantum computers. However, typical error rates of 10-3 for quantum gates remain a challenge for performing error correction and need to be further decreased for achieving practical quantum computation. Improving qubit coherence times for superconducting qubits is a continuous endeavor in order to decrease error rates. As part of this effort, a topic addressed in this dissertation is the study of the generation mechanism and dynamics of non-equilibrium quasiparticles (QPs), which are electron-like excitations of a superconductor. This source of decoherence was studied by measuring the rate of single-electron changes in the parity state of multiple charge-sensitive transmon qubits under different conditions. The presence of non-equilibrium QPs in superconducting resonators and qubits operating at millikelvin temperature has been known for decades. Understanding the sources and dynamics of these QPs is crucial to evaluate and improve the performance of the devices. Specifically, for superconducting qubits, a single QP tunneling across the Josephson junction changes the total charge parity from even to odd or vice versa, and can induce energy relaxation and dephasing, limiting the coherence of the device. To study the dynamics of non-equilibrium QPs, I utilized a Ramsey-like pulse sequence to measure the rate of single-electron parity changes in transmon qubits, which had a weak charge dispersion, with different shunting capacitor geometries and materials. I started out by measuring a charge parity rate of ~ 33 s-1 for a grounded "x-mon" qubit and ~ 17 s-1 for a galvanically isolated "two-pads" qubit with our standard setup. These rates decreased to ~ 5 s-1 and ~ 2 s-1 for the x-mon and two-pads respectively when IR-filters and extra layers of shielding were installed. From my measurements, I found that the charge parity rates are sensitive to the geometry of the shunting capacitor, weakly depend on the amount of shielding surrounding the device, and independent of using Al or Ta for the superconducting shunting capacitor. To distinguish between two possible mechanisms for the parity switching, I measured the parity rates after cooling one of the qubit devices in an external magnetic field to induce vortices in the superconducting electrodes. After increasing the magnetic field above 23 μT, I measured a faster QP trapping rate and a much smaller T1, suggesting that at least one vortex was added to the superconducting electrode near the Josephson junction. On the other hand, the measured charge parity rates exhibited no clear dependence on the background QP trapping rates. These data suggest that a large portion of parity switching events occurs from QPs being produced at the Josephson junction, where pair-breaking radiation is rectified into QPs by the junction, as opposed to tunneling of QPs residing in the electrodes. To understand the difference in the measured parity rates, I simulated the absorption efficiency of pair-breaking radiation for my two designs and observed a similar difference in absorption rates when a single-mode blackbody radiation with an effective temperature T* ~ 300 mK was assumed to be illuminating the devices. This large T*, which is significantly higher than the device's nominal temperature of 20 mK, is consistent with values reported in the literature. However, its physical origin remains not fully understood. For the other part of my dissertation, I developed a new simplified process for making superconducting air bridges. Air bridges are used to suppress unwanted extraneous high frequency chip modes parasitic to superconducting quantum circuits that can couple to qubits and cause decoherence. Traditional ways of making air bridges utilize thermal reflow to create arched photoresist scaffolds that are limited in heights. This results in insufficient mechanical strength of the bridges which tend to collapse when spanning to larger lengths. My simplified fabrication method that utilizes two-photon lithography, a technique that enables creation of three-dimensional micron-scale structures, relaxes this limitation and is capable of making mechanically stable bridges with lengths up to 100 μm. The resulting Al air bridges, having a superconducting transition temperature of Tc = 1.08 mK and a dc residual resistivity ratio of 3.85, were confirmed to form a good electrical contact with the base metal layers and exhibit a small measurable amount of rf loss when placed over coplanar waveguide resonators, on par with other air bridge fabrication methods.
Abstract Non-equilibrium quasiparticles are possible sources for decoherence in superconducting qubits because they can lead to energy decay or dephasing upon tunneling across Josephson junctions (JJs). Here, we investigate the impact of the intrinsic properties of two-dimensional transmon qubits on quasiparticle tunneling (QPT) and discuss how we can use quasiparticle dynamics to gain critical information about the quality of JJ barrier. We find the tunneling rate of the non-equilibrium quasiparticles to be sensitive to the choice of the shunting capacitor material and their geometry in qubits. In some devices, we observe an anomalous temperature dependence of the QPT rate below 100 mK that deviates from a constant background associated with non-equilibrium quasiparticles. We speculate that this behavior is caused by high transmission sites/defects within the oxide barriers of the JJs, leading to spatially localized subgap states. We model this by assuming that such defects generate regions with a smaller effective gap. Our results present a unique in situ characterization tool to assess the uniformity of tunnel barriers in qubit junctions and shed light on how quasiparticles can interact with various elements of the qubit circuit.
The tunnelling of quasiparticles across Josephson junctions in superconducting quantum circuits is an intrinsic decoherence mechanism for qubit degrees of freedom. Understanding the limits imposed by quasiparticle tunnelling on qubit relaxation and dephasing is of theoretical and experimental interest, particularly as improved understanding of extrinsic mechanisms has allowed crossing the 100 microsecond mark in transmon-type charge qubits. Here, by integrating recent developments in high-fidelity qubit readout and feedback control in circuit quantum electrodynamics, we transform a state-of-the-art transmon into its own real-time charge-parity detector. We directly measure the tunnelling of quasiparticles across the single junction and isolate the contribution of this tunnelling to qubit relaxation and dephasing, without reliance on theory. The millisecond timescales measured demonstrate that quasiparticle tunnelling does not presently bottleneck transmon qubit coherence, leaving room for yet another order of magnitude increase. Superconducting circuits are promising for quantum computing, but quasiparticle tunnelling across Josephson junctions introduces qubit decoherence. Ristè et al. convert a transmon qubit into its own real-time quasiparticle tunnelling detector and accurately measure induced decoherence in the millisecond range.
Quantum computing relies on the operation of qubits in an environment as free of noise as possible. Assessing the quality of this environment is a key aspect of ensuring high-fidelity implementations based on superconducting qubits. Relaxation, decoherence, dephasing, and quasiparticle tunneling rates have been measured for various shielding configurations used in the measurement environment for state-of-the-art transmon qubits. An ensemble of approximately 120 control devices was used for this study, with five different capacitor pad designs. The shielding elements varied in the configuration included an indium gasket at the qubit can's lid, Cryoperm magnetic shielding, the mixing chamber shield of the dilution refrigerator, the inclusion of a vacuum pump-out port, and capping unused subminiature version A connectors at the top of the measurement can's lid. It was found that the qubit lifetimes T1, T2, and Tϕ are robust to the all of configuration changes tried until the mixing chamber shield was removed, significantly increasing blackbody radiation levels in the qubit measurement space, where in that limit it was found that tapering the qubit pads reduced the amount of loss. In contrast, the quasiparticle tunneling rates were found to be extremely sensitive to all configuration changes tested. Consistent with earlier reports [McEwen et al., arXiv:2104.05219 (2021); Cardani et al., Nat. Commun. 12, 2733 (2021); Wilen et al., Nature 594, 369–373 (2021); Ristè et al. Nat. Commun. 4, 1913 (2013)], the findings from this study indicate that non-equilibrium quasiparticles do not currently limit the lifetimes of well-shielded transmon qubits.
Nonequilibrium quasiparticle excitations degrade the performance of a variety of superconducting circuits. Understanding the energy distribution of these quasiparticles will yield insight into their generation mechanisms, the limitations they impose on superconducting devices, and how to efficiently mitigate quasiparticle-induced qubit decoherence. To probe this energy distribution, we systematically correlate qubit relaxation and excitation with charge-parity switches in an offset-charge-sensitive transmon qubit, and find that quasiparticle-induced excitation events are the dominant mechanism behind the residual excited-state population in our samples. By itself, the observed quasiparticle distribution would limit T_{1} to ≈200 μs, which indicates that quasiparticle loss in our devices is on equal footing with all other loss mechanisms. Furthermore, the measured rate of quasiparticle-induced excitation events is greater than that of relaxation events, which signifies that the quasiparticles are more energetic than would be predicted from a thermal distribution describing their apparent density.
The performance of various superconducting devices operating at ultra-low temperatures is impaired by the presence of non-equilibrium quasiparticles. Inelastic quasiparticle (QP) tunneling across Josephson junctions in superconducting qubits results in decoherence and spurious excitations and, notably, can trigger correlated errors that severely impede quantum error correction. In this work, we use "gap engineering" to suppress the tunneling of low-energy quasiparticles in Al-based transmon qubits, a leading building block for superconducting quantum processors. By implementing potential barriers for QP, we strongly suppress QP tunneling across the junction and preserve charge parity for over 103 seconds. The suppression of QP tunneling also results in a reduction in the qubit energy relaxation rates. The demonstrated approach to gap engineering can be easily implemented in all Al-based circuits with Josephson junctions.
Superconducting quantum computing is a solid state quantum computing technology based on Josephson junction circuits. It becomes one of the most promising candidates for realizing practical quantum computer/simulator, because of its scalability, easy to coupling and control, compatibility to semiconductor technologies, etc. As the complicated electromagnetic environment in solid state metal and insulator, superconducting quantum bits (qubits) suffered from shot coherence time since its early development. In this review, we described some recently developed superconducting qubit structures, including Transmon/Xmon, Fluxonium and C-shunt flux qubit. Although these new qubit structures have very different circuit parameters and energy scales, they all find their way to effectively suppress environmental noises. As a result, their coherence time were improved significantly. Transmon, a transmission-line shunted plasma oscillation qubit, was now among the most popular structures for building a multi-qubit superconducting quantum circuit. It introduced a relatively large shunt capacitor to remarkably reduce the charge dispersion. Although the non-linearity is also decreased, by operating in a properly chosen EJ/Ec, transmon can greatly reduce the charge noise while only sacrificing a small amount of non-linearity. Xmon can be considered as a modified version of transmon. It is designed and optimized for multi-qubit operation and measurement with separate X/Y and Z control lines for each qubit, and a readout bus (a transmission line or a low-Q bandpass filter) for simultaneous readout of all the qubits. Fluxonium provide another solution for suppressing the charge noise in Cooper-pair box (CPB). It introduces a large shunt inductance to filter low-frequency offset charge in the small capacitor of the phase-slip junction (the small junction). To keep the qubit operating in the charge region, the shunt inductor should be large enough to keep the impedance larger than the superconducting impedance quantum RQ~1 kΩ. As a result, the inductance can only be provided by a large series of Josephson junctions. Fluxonium keeps the advantage of high anharmonicity of CPB. In addition, it introduces another degree of freedom: external flux Φext. Quasiparticles (electrons or holes) tunneling at the small junction add coherently to produce a ″1+cosφ″ term. As a result, when Φext= Φ0/2, dissipation caused by quasiparticle tunneling is suppressed and the energy relaxation time (T1) increases drastically. C-shunt flux qubit (CSFQ) decreases α and EJ to suppress flux noise in the qubit. While the charge noise becomes the dominant noise source, a large shunt capacitor is added to suppress the charge noise, similar to that in a transmon qubit. It is worth to notice that in CSFQ, the α decreases to below but near 1/2. As a result, the double-well potential no longer exists. The energy structure become similar to transmon, with the anharmonicity be opposite. CSFQ can get a much improved coherence time, while its anharmonicity can be larger than that of transmon. Those new superconducting qubit structures provide different solutions to improve the coherence time. Although it looks much different in circuit models and parameters, they have ideas in common, and may act as guides to other novel designs with longer coherence time. We can summarize as below. (1) The qubit circuit should be free of small superconducting islands. Charge fluctuation in small islands is a major source of decoherence. As a result, increase the area of the islands, that is, increase the capacitance becomes a straight forward way to suppress the charge noise. In Fluxonium, the small junction is connected with a large series of large junctions that there is also no small islands in the whole loop. (2) Remove superconducting loops in the qubit circuit, or minimize the loop size and loop current to suppress flux noise. (3) Bias the phase difference of the small junction to π, where dissipation caused by quasiparticle tunneling can be suppressed coherently. (4) Decrease the coupling bandwidth of qubit to the environment. In a circuit-QED readout scheme, a high-Q readout resonator that dispersively coupled to the qubit protects the qubit from exposed to the electromagnetic environment of the readout circuit. A ″Purcell filter″ can also be added to suppress such decoherence further. In conclusion, we overviewed some qubit engineering techniques or ideas to improve the coherence time, which is a very important figure for building practical quantum computer/simulator. We hope that someone can combine and optimize these ideas, while interact with developments in materials and micro-fabrication technologies, to develop novel new generation superconducting qubit structures in the near future.