Abstract Previouschapters built on the assumption that central thermodynamic quantities can be defined without disturbing the dynamics of the system. This assumption cannot be kepted in light of real experiments, where quantum measurements are disturbing. This chapter starts by discussing why it is necessary to overcome the semiclassical two-point measurement scheme. Then, consistent notions of internal energy, heat, work and system entropy are defined for a (Markovian and non-Markovian) quantum stochastic process, whichonly relies on interventions performed on the system. The thermodynamic description of quantum measurements, feedback control and Maxwell’s demon is studied in detail. The chapter concludes with applying these ‘operational’ definitions to a Nobel-prize-winning experiment in quantum optics.
Abstract Previouschapters built on the assumption that central thermodynamic quantities can be defined without disturbing the dynamics of the system. This assumption cannot be kepted in light of real experiments, where quantum measurements are disturbing. This chapter starts by discussing why it is necessary to overcome the semiclassical two-point measurement scheme. Then, consistent notions of internal energy, heat, work and system entropy are defined for a (Markovian and non-Markovian) quantum stochastic process, whichonly relies on interventions performed on the system. The thermodynamic description of quantum measurements, feedback control and Maxwell’s demon is studied in detail. The chapter concludes with applying these ‘operational’ definitions to a Nobel-prize-winning experiment in quantum optics.
We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from the repeated interaction framework, we define internal energy, heat, work, and entropy at the trajectory level. The validity of the first law (at the trajectory level) and the second law (on average) is established. The theory naturally allows one to treat incomplete information and it is able to smoothly interpolate between a trajectory-based and an ensemble level description. We use our theory to compute the thermodynamic efficiency of recent experiments reporting on the stabilization of photon number states using real-time quantum feedback control. Special attention is paid to limiting cases of our general theory, where we recover or contrast it with previous results. We point out various interesting problems, which the theory is able to address rigorously, such as the detection of quantum effects in thermodynamics.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.
We discuss the thermodynamic aspects of a single qubit based device, powered by weak quantum measurements, and feedback controlled by a quantum Maxwell's demon. We discuss both discrete and time-continuous operation of the measurement based device at finite temperature of the reservoir. In the discrete example where a demon acquires information via discrete weak measurements, we find that the thermodynamic variables including the heat exchanged, extractable work, and the entropy produced are completely determined by an information theoretic measure of the demon's perceived arrow of time. We also discuss a realistic time-continuous operation of the device where the feedback is applied after a sequence of weak measurements. In the time-continuous limit, we derive the exact finite-time statistics of work, heat and entropy changes along individual quantum trajectories of the quantum measurement process, and relate them to the demon's arrow of time.
We now turn to the subject of thermodynamics, and to describing the process of thermalization of quantum systems. A quantum system that interacts with another system large enough to obey the usual rules of thermodynamics, is referred to as an open system. The thermal system with which it interacts is often referred to as a thermal bath , or simply as the environment. We will use these terms interchangeably. Modeling the behavior of open quantum systems has many applications. One of these is to model the noise that they are subjected to by their surroundings, noise that we will wish to control using measurement and feedback loops in Chapter 5. There are also two important connections between quantum measurements, information theory, and thermodynamics. The first of these is that the thermodynamic entropy of a macroscopic system can be identified with the information-theoretic entropy that characterizes the lack of knowledge of an observer about the microstates of the system. In turn, if an observer is allowed to make microscopic measurements on the system, then this modifies the thermodynamic rules regarding the conversion of heat to work. Such is the subject of Maxwell’s demon. Curiously it took more than a century to understand how Maxwell’s demon, essentially a microscopic measurement and feedback process, fits within the second law of thermodynamics. In another twist, it turns out that the process of erasing information requires an increase in the thermodynamic entropy of the environment, and this increase is directly related to the amount of information erased.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.