We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
The goal of this thesis is to define the concept of coarse-graining in quantum systems through measurements and to develop a unified mathematical framework for macroscopic states, operations, correlations, and entropy.Within this framework, irreversible phenomena arise from the loss of statistical information that is accessible to macroscopic observers.To achieve this goal, we rigorously define macroscopicity.This thesis investigates observational entropy, a concept that unifies Boltzmann entropy, Gibbs entropy, von Neumann's macroscopic entropy, and diagonal entropy.Our approach to explaining how irreversibility arises in isolated quantum systems is based on this unified perspective.When the initial state is "macroscopic," we use Petz's theory of statistical sufficiency to show that observational entropy strictly increases with unitary time evolution.Furthermore, we show that, for any initial state, the probability of the system's observational entropy increasing and rapidly reaching its maximum value under random unitary time evolution is extremely high.Specifically, we demonstrate that when measurements on a quantum system are sufficiently coarse-grained relative to its size, its initial state (whether pure or mixed) becomes indistinguishable from the maximally mixed state through random time evolution.We show that this holds not only for random time evolutions sampled according to the Haar measure, but also for approximate 2-designs, which are considered more physically realistic models.Next, we extend this framework by introducing positive operator-valued measures (POVMs) and quantum prior states.This allows us to construct a unified inferential framework for macroscopic states.A macroscopic state can be characterized using equivalent algebraic and constructive formulations based on quantum statistical sufficiency.This approach is based on the concept of an observational deficit, which quantifies the degree to which a state is "irretrodictable" relative to prior and measurement.This structure is formulated as an "inferential reference frame" that encapsulates the observer's informational perspective.Furthermore, we treat macroscopic states as free states and construct the resource theory of microscopicity.This theory unifies existing theories of coherence, athermality and asymmetry.Finally, we extend this framework to the study of quantum correlations under observational constraints.This enables us to show that quantum correlations, such as entanglement and quantum discord, are context-dependent resources that depend on the observer's reference frame.I would like to express my deepest gratitude to my supervisor,
Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.
We investigate the detailed properties of observational entropy, introduced by \ifmmode \check{S}\else \v{S}\fi{}afr\'anek et al. [Phys. Rev. A 99, 010101 (2019)] as a generalization of Boltzmann entropy to quantum mechanics. This quantity can involve multiple coarse grainings, even those that do not commute with each other, without losing any of its properties. It is well-defined out of equilibrium, and for some coarse grainings it generically rises to the correct thermodynamic value even in a genuinely isolated quantum system. The quantity contains several other entropy definitions as special cases, it has interesting information-theoretic interpretations, and mathematical properties---such as extensivity and upper and lower bounds---suitable for an entropy. Here we describe and provide proofs for many of its properties, discuss its interpretation and connection to other quantities, and provide numerous simulations and analytic arguments supporting the claims of its relationship to thermodynamic entropy. This quantity may thus provide a clear and well-defined foundation on which to build a satisfactory understanding of the second thermodynamical law in quantum mechanics.
Abstract To understand the emergence of macroscopic irreversibility from microscopic reversible dynamics, the idea of coarse-graining plays a fundamental role. In this work, we develop a unified inferential framework for macroscopic states , that is, coarse descriptions of microscopic quantum systems that can be inferred from macroscopic measurements. Building on quantum statistical sufficiency and Bayesian retrodiction, we characterize macroscopic states through equivalent abstract (algebraic) and explicit (constructive) formulations. Central to our approach is the notion of observational deficit , which quantifies the degree of irretrodictability of a state relative to a prior and a measurement. This leads to a general definition of macroscopic entropy as an inferentially grounded measure of asymmetry under Bayesian inversion. We formalize this structure in terms of inferential reference frames , defined by the pair consisting of a prior and a measurement, which encapsulate the observer’s informational perspective. We then formulate a resource theory of microscopicity, treating macroscopic states as free states and introducing a hierarchy of microscopicity-non-generating operations . This theory unifies and extends existing resource theories of coherence, athermality, and asymmetry. Finally, we apply the framework to study quantum correlations under observational constraints, introducing the notion of observational discord and deriving necessary and sufficient conditions for their vanishing in terms of information recoverability. This work is dedicated to Professor Ryszard Horodecki on the occasion of his 80th birthday, in deep admiration and gratitude for his pioneering contributions to quantum information theory.
Quantum-Induced Stochastic Dynamics arises from the coupling between a classical system and a quantum environment. Unlike standard thermal reservoirs, this environment acts as a dynamic bath, capable of simultaneously exchanging heat and performing work. We formulate a thermodynamic framework for this semi-classical regime, defining heat, work, and entropy production. We derive a modified Second Law that accounts for non-equilibrium quantum features, such as squeezing. The framework is exemplified by an optomechanical setup, where we characterize the thermodynamics of the non-stationary noise induced by the cavity field.
We extend classical coarse-grained entropy, commonly used in many branches of physics, to the quantum realm. We find two coarse grainings, one using measurements of local particle numbers and then total energy, and the second using local energy measurements, which lead to an entropy that is defined outside of equilibrium, is in accord with the thermodynamic entropy for equilibrium systems, and reaches the thermodynamic entropy in the long-time limit, even in genuinely isolated quantum systems. This answers the long-standing conceptual problem, as to which entropy is relevant for the formulation of the second thermodynamic law in closed quantum systems. This entropy could be in principle measured, especially now that experiments on such systems are becoming feasible.