Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:1911.01730 · Quantum

Thermodynamics of Quantum Causal Models: An Inclusive, Hamiltonian Approach

Philipp Strasberg

Published Mar 2, 2020• 28 citations
arXivHTMLPDF

Abstract

Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.

DOI
10.22331/q-2020-03-02-240

Related papers

Operational approach to quantum stochastic thermodynamics

Philipp Strasberg

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from the repeated interaction framework, we define internal energy, heat, work, and entropy at the trajectory level. The validity of the first law (at the trajectory level) and the second law (on average) is established. The theory naturally allows one to treat incomplete information and it is able to smoothly interpolate between a trajectory-based and an ensemble level description. We use our theory to compute the thermodynamic efficiency of recent experiments reporting on the stabilization of photon number states using real-time quantum feedback control. Special attention is paid to limiting cases of our general theory, where we recover or contrast it with previous results. We point out various interesting problems, which the theory is able to address rigorously, such as the detection of quantum effects in thermodynamics.

arXiv:1810.00698•Physical review. E•Aug 21, 2019•66 citations

Quantum stochastic thermodynamics of macroscopic systems: an algebraic approach

Antoine Rignon-Bret, Cyril Elouard

We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.

quant-pharXiv:2607.09242•Jul 13, 2026•0 citations

Operational Quantum Stochastic Thermodynamics

Philipp Strasberg

Abstract Previouschapters built on the assumption that central thermodynamic quantities can be defined without disturbing the dynamics of the system. This assumption cannot be kepted in light of real experiments, where quantum measurements are disturbing. This chapter starts by discussing why it is necessary to overcome the semiclassical two-point measurement scheme. Then, consistent notions of internal energy, heat, work and system entropy are defined for a (Markovian and non-Markovian) quantum stochastic process, whichonly relies on interventions performed on the system. The thermodynamic description of quantum measurements, feedback control and Maxwell’s demon is studied in detail. The chapter concludes with applying these ‘operational’ definitions to a Nobel-prize-winning experiment in quantum optics.

•Jan 28, 2022•0 citations

Randomness, catalysis and partial knowledge in quantum thermodynamics

Paul Boës

Quantum thermodynamics is a blossoming research program that uses tools and ideas from quantum information theory to extend the laws of thermodynamics to the domain of systems to which the laws of quantum mechanics apply and the thermodynamic limit does not necessarily apply. The contributions of this program are both foundational, in providing an approach to constructively derive the laws of phenomenological thermodynamics from the postulates of unitary quantum mechanics in a rigorous and bottom-up fashion, but also prac- tical, in providing the theory for an increasing number of experiments that attempt to build thermodynamic machines at scales that were previously inaccessible. One key mathematical tool used in quantum thermodynamics is the framework of resource theories, specifically the resource theory of thermal operations, in which the thermodynamic interaction of a system with a heat bath and various additional components such as work batteries, clocks or catalysts are modeled. In this cumulative thesis, various extensions and modifications of this framework are studied in order to derive novel results and insights about the possible thermodynamic evolution of quantum systems. In particular, following a system- atic exposition of the resource theory of thermal operations from first principles, I develop answers to the following questions: i) What is the smallest heat bath required to provide the necessary randomness for a system to undergo a given stochastic or thermodynamical evolution? ii) Does this size differ depending on whether the interaction between bath and system is quantum or classical? iii) How can quantum systems thermodynamically evolve in the presence of catalytic bystander systems and how can this be put to use? iv) What are the thermodynamic state transitions that an agent can operationally affect when she only has access to partial information about the underlying states of system and bath? v) How can we understand the emergence of the canonical ensemble in statistical thermodynamics from quantum mechanics? These questions cover a wide ground, but it will become clear that they can in fact all be discussed using the same formal tools. As such, the answers to the above questions provided in this thesis are both interesting in their own right — showing for example that there exists a gap in how efficiently randomness can be exploited quantumly as compared to classically or that catalytic bystander systems can be used to extract finite amounts of work per particle from macroscopic systems with non-vanishing probability — as well as illustrate the power of quantum thermodynamics as a set of tools to connect quantum mechanics and the theory of thermodynamics more generally.

•Jan 1, 2021•0 citations

Repeated Interactions and Quantum Stochastic Thermodynamics at Strong Coupling

Philipp Strasberg

The thermodynamic framework of repeated interactions is generalized to an arbitrary open quantum system in contact with a heat bath. Based on these findings, the theory is then extended to arbitrary measurements performed on the system. This constitutes a direct experimentally testable framework in strong coupling quantum thermodynamics. By construction, it provides many quantum stochastic processes and quantum causal models with a consistent thermodynamic interpretation. The setting can be further used, for instance, to rigorously investigate the interplay between non-Markovianity and nonequilibrium thermodynamics.

arXiv:1907.01804•Physical Review Letters•Oct 31, 2019•84 citations

First and Second Law of Quantum Thermodynamics: A Consistent Derivation Based on a Microscopic Definition of Entropy

Philipp Strasberg, Andreas Winter

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics.This tutorial focuses on the derivation of the first and second law for isolated and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies.The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat, and temperature.These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of states and processes.The consistency with previous results is demonstrated.The framework applies to multiple baths including particle transport and accounts for processes with, e.g., a changing temperature of the bath, which is determined microscopically.An integral fluctuation theorem for entropy production is satisfied.In summary, this tutorial introduces a consistent and versatile framework to understand and apply the laws of thermodynamics in the quantum regime and beyond.

arXiv:2002.08817•PRX Quantum•Aug 19, 2021•129 citations
Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.
We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from the repeated interaction framework, we define internal energy, heat, work, and entropy at the trajectory level. The validity of the first law (at the trajectory level) and the second law (on average) is established. The theory naturally allows one to treat incomplete information and it is able to smoothly interpolate between a trajectory-based and an ensemble level description. We use our theory to compute the thermodynamic efficiency of recent experiments reporting on the stabilization of photon number states using real-time quantum feedback control. Special attention is paid to limiting cases of our general theory, where we recover or contrast it with previous results. We point out various interesting problems, which the theory is able to address rigorously, such as the detection of quantum effects in thermodynamics.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
Abstract Previouschapters built on the assumption that central thermodynamic quantities can be defined without disturbing the dynamics of the system. This assumption cannot be kepted in light of real experiments, where quantum measurements are disturbing. This chapter starts by discussing why it is necessary to overcome the semiclassical two-point measurement scheme. Then, consistent notions of internal energy, heat, work and system entropy are defined for a (Markovian and non-Markovian) quantum stochastic process, whichonly relies on interventions performed on the system. The thermodynamic description of quantum measurements, feedback control and Maxwell’s demon is studied in detail. The chapter concludes with applying these ‘operational’ definitions to a Nobel-prize-winning experiment in quantum optics.
Quantum thermodynamics is a blossoming research program that uses tools and ideas from quantum information theory to extend the laws of thermodynamics to the domain of systems to which the laws of quantum mechanics apply and the thermodynamic limit does not necessarily apply. The contributions of this program are both foundational, in providing an approach to constructively derive the laws of phenomenological thermodynamics from the postulates of unitary quantum mechanics in a rigorous and bottom-up fashion, but also prac- tical, in providing the theory for an increasing number of experiments that attempt to build thermodynamic machines at scales that were previously inaccessible. One key mathematical tool used in quantum thermodynamics is the framework of resource theories, specifically the resource theory of thermal operations, in which the thermodynamic interaction of a system with a heat bath and various additional components such as work batteries, clocks or catalysts are modeled. In this cumulative thesis, various extensions and modifications of this framework are studied in order to derive novel results and insights about the possible thermodynamic evolution of quantum systems. In particular, following a system- atic exposition of the resource theory of thermal operations from first principles, I develop answers to the following questions: i) What is the smallest heat bath required to provide the necessary randomness for a system to undergo a given stochastic or thermodynamical evolution? ii) Does this size differ depending on whether the interaction between bath and system is quantum or classical? iii) How can quantum systems thermodynamically evolve in the presence of catalytic bystander systems and how can this be put to use? iv) What are the thermodynamic state transitions that an agent can operationally affect when she only has access to partial information about the underlying states of system and bath? v) How can we understand the emergence of the canonical ensemble in statistical thermodynamics from quantum mechanics? These questions cover a wide ground, but it will become clear that they can in fact all be discussed using the same formal tools. As such, the answers to the above questions provided in this thesis are both interesting in their own right — showing for example that there exists a gap in how efficiently randomness can be exploited quantumly as compared to classically or that catalytic bystander systems can be used to extract finite amounts of work per particle from macroscopic systems with non-vanishing probability — as well as illustrate the power of quantum thermodynamics as a set of tools to connect quantum mechanics and the theory of thermodynamics more generally.
The thermodynamic framework of repeated interactions is generalized to an arbitrary open quantum system in contact with a heat bath. Based on these findings, the theory is then extended to arbitrary measurements performed on the system. This constitutes a direct experimentally testable framework in strong coupling quantum thermodynamics. By construction, it provides many quantum stochastic processes and quantum causal models with a consistent thermodynamic interpretation. The setting can be further used, for instance, to rigorously investigate the interplay between non-Markovianity and nonequilibrium thermodynamics.
Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics.This tutorial focuses on the derivation of the first and second law for isolated and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies.The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat, and temperature.These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of states and processes.The consistency with previous results is demonstrated.The framework applies to multiple baths including particle transport and accounts for processes with, e.g., a changing temperature of the bath, which is determined microscopically.An integral fluctuation theorem for entropy production is satisfied.In summary, this tutorial introduces a consistent and versatile framework to understand and apply the laws of thermodynamics in the quantum regime and beyond.