The aim of this thesis it to contribute to three open problems in the theory of itinerant electron systems in two spatial dimensions. Firstly, the mechanism for charge density wave formation in the transition metal dichalcogenides is a debated subject. In this thesis it is shown that charge density wave formation is possible via a purely electronic mechanism in monolayer vanadium diselenide. The competition of superconductivity and density wave formation is taken into account using the renormalisation group. As the Fermi surface is tuned to perfect nesting, a charge density wave phase emerges when the Heisenberg exchange interaction is of the order of the contact Coulomb repulsion. Secondly, the search for materials which exhibit topological superconductivity is ongoing. Possible candidates are strongly spin-orbit-coupled metals. In this thesis a square-lattice Hubbard model with strong Rashba spin-orbit coupling and one of the Fermi surfaces close to a Lifshitz transition is examined. The metal is shown to be generically unstable to the formation of mixed-parity superconductivity with a helical triplet component via a renormalisation group analysis. Thirdly, the breakdown of Fermi liquid theory close to a quantum critical point is still not well understood. In this thesis a functional renormalisation group analysis is presented using a soft frequency cutoff, investigating a general class of Pomeranchuk instabilities with 𝑁_𝑏 flavours of boson. At small 𝑁_𝑏 the theory is characterised by weakly non-Fermi-liquid behaviour of the electrons and 𝑧≈2 dynamics for the order parameter fluctuations. For large 𝑁_𝑏, the theory crosses over to 𝑧≈1 scaling and non-Fermi-liquid behaviour.
The aim of this thesis it to contribute to three open problems in the theory of itinerant electron systems in two spatial dimensions. Firstly, the mechanism for charge density wave formation in the transition metal dichalcogenides is a debated subject. In this thesis it is shown that charge density wave formation is possible via a purely electronic mechanism in monolayer vanadium diselenide. The competition of superconductivity and density wave formation is taken into account using the renormalisation group. As the Fermi surface is tuned to perfect nesting, a charge density wave phase emerges when the Heisenberg exchange interaction is of the order of the contact Coulomb repulsion. Secondly, the search for materials which exhibit topological superconductivity is ongoing. Possible candidates are strongly spin-orbit-coupled metals. In this thesis a square-lattice Hubbard model with strong Rashba spin-orbit coupling and one of the Fermi surfaces close to a Lifshitz transition is examined. The metal is shown to be generically unstable to the formation of mixed-parity superconductivity with a helical triplet component via a renormalisation group analysis. Thirdly, the breakdown of Fermi liquid theory close to a quantum critical point is still not well understood. In this thesis a functional renormalisation group analysis is presented using a soft frequency cutoff, investigating a general class of Pomeranchuk instabilities with 𝑁_𝑏 flavours of boson. At small 𝑁_𝑏 the theory is characterised by weakly non-Fermi-liquid behaviour of the electrons and 𝑧≈2 dynamics for the order parameter fluctuations. For large 𝑁_𝑏, the theory crosses over to 𝑧≈1 scaling and non-Fermi-liquid behaviour.
This thesis details quantum-field-theoretical analyses of four distinct strongly correlated metallic systems in two spatial dimensions. It begins by examining two driving mechanisms proposed in the literature for the exotic charge-density-wave phase in monolayer vanadium diselenide. The spectral-function-fitting method used to analyse the first proves quite indeterminate, leading to only speculative conclusions. The second mechanism is tested by producing mean-field phase diagrams of the system, yielding an appreciable region of phase space in which it does drive the charge-density wave. In the next chapter, the square-lattice Hubbard model with first-, second- and third-nearest-neighbour hoppings is considered. Phase diagrams are predicted using the few-patch parquet renormalization group and compared with those produced by a colleague using another method, and with those from another patch scheme in the literature. It is concluded that few-patch parquet-renormalization-group schemes are not sophisticated enough to correctly describe many features of this system, and likely other systems. The second half of the thesis studies non-Fermi liquids. First, the non-Fermi liquid resulting from coupling finite-density fermions to a U(1) gauge field is examined. The functional renormalization group, with a soft frequency regulator for the fermions, is used, and gauge-symmetry constraints are imposed. The resulting bosonic dynamical exponent is z_A = 2, and the fermionic self-energy scales as Σ(ω,k_F) ~ √ω at small frequency. Enforcement of the symmetry constraints leaves the results largely unchanged, but does make the bosonic mass term irrelevant about criticality. In the final research chapter, the non-equilibrium modes of two-dimensional non-Fermi liquids in incipient itinerant ferromagnets are analysed. Linearized quantum Boltzmann equations are solved to find the spectra of charge- and spin-density modes. Whether collective modes are present is found to depend on both universal and non-universal information, in ways previously overlooked. Preliminary results are also given for the spectra when coupling to a classical magnetic field is reincluded.
In the present thesis, we consider interaction induced instabilities in different electronic models consisting of multiple orbitals. We employ the functional renormalization group method, to tackle the many-particle problem. The main goal of this work is the identification of leading instabilities of different interacting electron systems and the relevant energy scales for the onset of correlations. First, we recapitulate the functional renormalization group formalism and discuss details of its application. We proceed with the investigation of two models, a continuum model and a model on a checkerboard lattice, which exhibit a single quadratic band crossing point at the Fermi level. Here, we find that electron-electron interactions can lead to ordering with non-trivial topological properties, i.e. the existence of topologically protected edge states. We further discuss the emergence of superconductivity, when the band crossing point is shifted away from the Fermi surface. Then, we turn to more realistic models featuring quadratic and cubic band crossing points, namely the honeycomb bi- and trilayer, which are used to describe the graphene layered systems. We obtain rich phase diagrams, with antiferromagnetic spin-density, two types of charge-density waves and a quantum spin Hall phase, which features in the case of the trilayer topologically protected edge states. With interaction parameters extracted from ab initio calculations, we observe a close competition between the antiferromagnetic and quantum spin Hall state. Here, the precise shape of the interaction decides which instability is the leading one. A comparison of the energy scales of the ordering phenomena in tri-, bi- and single layer reveals that when the interaction parameters from ab initio are appropriately rescaled, the functional renormalization group can qualitatively reproduce experimental gap sizes in the respective materials consistently. Afterwards, we study a multiband model of the copper-based unconventional superconductors. This is motivated by a puzzling material trend in copper-based high-Tc superconductors, pointed out by Pavarini et al. [PRL. 87, 047003 (2001)]: Compounds with larger next-nearest-neighbor hopping generally exhibit larger critical temperatures, which cannot be easily understood within spin-fluctuation theories of the one-band Hubbard model. Therefore, we consider the extension of the original model by including additional orbitals. We investigate a two-band model with an additional 4s orbital within a two-patch approximation and the N-patch-scheme. By this, a general understanding of the influence of the additional orbitals is established. Afterwards, we additionally include the 3dz2 orbital and show that the material trend, found in experiments, can, at least, qualitatively be reproduced. Lastly, we go back to the single band Hubbard model and examine the consequences of the widely used approximation of neglecting the self-energy and the frequency dependence of the interaction vertex. We establish that the phase diagram obtained from the functional renormalization group is only quantitatively affected. From this study, we conclude that neglecting self-energy and frequency dependence, is a sensible approach, in order to obtain a reliable qualitative picture of the low energy behavior of a weakly or moderately coupled system at reasonable expense.
In this thesis we study the scaling properties of unconventional metals that arise at quantum critical points using low-energy effective field theories. Due to high rate of scatterings between electrons and critical fluctuations of the order parameter associated with spontaneous symmetry breaking, Landau’s Fermi liquid theory breaks down at the critical points. The theories that describe these critical points generally flow into strong coupling regimes at low energy in two space dimensions. Here we develop and utilize renormalization group methods that are suitable for the interacting non-Fermi liquids. We focus on the critical points arising at excitonic, and commensurate spin and charge density wave transitions. By controlled analyses we find stable non-Fermi liquid and marginal Fermi liquid states, and extract the scaling behaviour. The field theories for the non-Fermi liquids are characterized by symmetry groups, local curvature of the Fermi surface, the dispersion of the order parameter fluctuations, and dimensions of space and Fermi surface.
Materials with strongly correlated electrons show a multitude of unconventional phenomena, such as superconductivity or magnetism, that cannot be explained in a single-particle picture and necessitate to take many-body effects into account. A route to explain the origin of these phenomena consists in constructing effective models for these materials that are then solved, often using numerical techniques. Paradigmatic models for two different classes of strongly correlated electron systems are investigated in this thesis: The Hubbard model is a paradigmatic model to describe the Mott metal-insulator transition (MIT) and the Kondo lattice model describes the low-energy physics in heavy fermion compounds. Both models are analyzed numerically using different variations of a quantum cluster technique, the variational cluster approximation (VCA). The first part focuses on the MIT, as it is investigated experimentally in quasi-two-dimensional charge-transfer salts. Its nature and associated universality class are still heavily discussed and both experiments and theoretical approaches come to different conclusions. In this thesis, the Mott transition is investigated on an anisotropic two-dimensional Hubbard model at half-filling. By using a control parameter, which induces this anisotropy, strong evidence for Mott quantum criticality is found in weakly coupled Hubbard chains. The results at zero temperature show that the second-order critical end point Tc of the interaction-driven metal-insulator transition can be tuned down to zero at strong anisotropy. Further results for the antiferromagnetic phase suggest a similar picture and motivate adding the anisotropy as a new axis in the phase diagram to account for a low-temperature critical end point of the Mott transition. The second part of this thesis focuses on unconventional phases that emerge in a paradigmatic model for heavy fermion systems, the Kondo lattice model. Using the VCA, the two-dimensional Kondo lattice model is investigated in the paramagnetic phase as well as in phases with broken symmetry. An antiferromagnetic phase at weak coupling and a phase with Kondo-singlet formation at strong coupling are analyzed. Within the antiferromagnetically ordered region, two phases with different Fermi-surface topology, which are separated by a discontinuous transition, are identified. The model is also tested for s-wave superconductivity as found recently using dynamical mean-field theory, but no indications for robust local pairing are seen within VCA. Instead, nodal d-wave superconductivity is found and analyzed in a large range of couplings and electron fillings, and its interplay with antiferromagnetic order at weak coupling is discussed. This motivates further studies on extended models that might allow for a close comparison with experiments on heavy fermion systems. Understanding the formation of unconventional phases in strongly correlated electron systems is not only of fundamental interest, but it is also essential for designing new functional materials. Although the results of approximate cluster techniques have to be handled with care, the new aspects presented in this thesis pave the way for further investigations in this direction.
Plenty experimental evidence indicates that quantum critical phenomena give rise to much of the rich physics observed in strongly correlated itinerant electron systems such as the high temperature superconductors. A quantum critical point of particular interest is found at the zero-temperature onset of spin-density wave order in two- dimensional metals. The appropriate low-energy theory poses an exceptionally hard problem to analytic theory, therefore the unbiased and controlled numerical approach pursued in this thesis provides important contributions on the road to comprehensive understanding. After discussing the phenomenology of quantum criticality, a sign- problem-free determinantal quantum Monte Carlo approach is introduced and an extensive toolbox of numerical methods is described in a self-contained way. By the means of large-scale computer simulations we have solved a lattice realization of the universal effective theory of interest. The finite-temperature phase diagram, showing both a quasi-long-range spin-density wave ordered phase and a d-wave superconducting dome, is discussed in its entirety. Close to the quantum phase transition we find evidence for unusual scaling of the order parameter correlations and for non-Fermi liquid behavior at isolated hot spots on the Fermi surface.
"This thesis is devoted to the investigation of the quantum liquid crystal phases in strongly correlated electronic systems. Such phases are characterized by their partially broken spatial symmetries and are observed in various strongly correlated systems as being summarized in Chapter 1. In quantum liquid crystal phases formed by fermions, behaviors beyond Landau's theory of the Fermi liquids appear naturally, signed by the absence of well-defined quasiparticle excitations. Although quantum liquid crystal phases often involve strong-coupling physics, the associated symmetry analysis can often be carried out also in a relatively weak coupling regime and this is the main approach taken in this thesis. Two different quantum liquid crystal phases, the nematic state and the smectic state, are studied in Chapters 2 and 3 respectively, by investigating various instabilities of a Landau Fermi liquid. A nematic phase is a state that breaks the rotational symmetry spontaneously but preserves the translational symmetries. It can be reached by the Pomeranchuk instability of a Landau Fermi liquid. The Pomeranchuk instability in the charge (spin-singlet) sector of a Fermi liquid was studied previously within a random phase approximation and by a high-dimensional bosonization method. In Chapter 2, we concentrate on the Pomeranchuk instability in the spin-triplet sector, and two different classes of ordered phases are discovered, dubbed the a and ,8-phases by analogy to the superfluid 3He-A and B-phases. The Fermi surfaces in the a-phases exhibit spontaneous anisotropic distortions, while in the ,8-phases the Fermi surfaces remain circular or spherical with topologically non-trivial spin configurations in momentum space. The behaviors of the low energy bosonic excitations are studied both in the order phases (a and .B) and at the quantum critical point separating the ordered phases from the Fermi liquid phase. In Chapter 3, the smectic phase and the quantum phase transition between a metallic nematic state and a metallic smectic phase are investigated using the random phase approximation, by considering the formation of a unidirectional charge density wave in an electronic nematic state. The associated quantum critical point is investigated within the Hertz-Millis approach. Non-Fermi liquid behaviors are discovered both at the quantum phase transition and in the smectic ordered phase. The theory we studied here provides a simple description for the so-called ""fluctuating stripe"" phase in cuprates. Similar to its classical counterpart, the phase transition between the nematic and smectic phases are described by a ""gauge-like"" theory as required by the rotational invariance in close analogy with the McMillan-deGennes theory of the smectic-nematic phase transition in classical liquid crystals. However, unlike the classical McMillandeGennes theory, in which the coupling between the ""gauge-like"" nematic fluctuations and the ""matter-like"" smectic fields is relevant, in the sense of renormalization group, this coupling is irrelevant at the quantum phase transition. This property enables the study of low energy fluctuations and the fate of fermions near this quantum critical point. In Chapter 4, quantum liquid crystal phases with a broken time-reversal symmetry are investigated. We start by studying the general scenario of timereversal symmetry breaking phases in the absence of magnetic ordering in systems with long-lived low-energy fermionic quasiparticle excitations in two dimensions. Using a Berry phase approach, we classified possible time-reversal symmetry breaking phases by the accompanying spatial symmetry breaking patterns. Two of the simplest situations are referred to as the type I state, which breaks simultaneously the space-inversion symmetry and the time-reversal symmetry, and the type I I state, in which the chiral symmetry is broken in addition to the breaking of the time-reversal symmetry. Although the starting point is general and has little relation with the quantum liquid crystal phases, both type I and type II states defined above are realized by (generalized) Pomeranchuk instabilities. In fact , a type I I state is usually a nematic state which also breaks the time-reversal symmetry. Interestingly, the type II states also shows spontaneously generated Hall effect even in the absence of a magnetic field, which is known as the spontaneous anomalous Hall effect. In Chapter 5, we investigate the stability of a quadratic band-crossing point in two-dimensional fermionic systems that provide an explicit example, within well controlled approximations, for the nematic ordering discussed in Chapter 2 and spontaneous anomalous Hall effect discussed in Chapter 4. At the non-interacting level, we show that a quadratic band-crossing point exists and is topologically stable when the Berry flux of this crossing point is ±27r and the point symmetry group at this point has either fourfold or sixfold rotational symmetries. Strikingly, we find that this would-be topologically stable quadratic band-crossing is marginally unstable against short-range interactions: a quadratic band-crossing point in two dimensions is unstable against shortrange repulsion, no matter how weak! Four ordered phases are found in this system, the quantum anomalous Hall state, the quantum spin Hall phase, the nematic phase, and the nematic-spin-nematic phase."