We identify a general mechanism for the finite-time thermalization of macroscopic observables, such as coarse-grained charge densities, in terms of elementary forms of the quantum dynamics of initial states: (1) aperiodicity, which provides a computable measure of (2) a dynamical partially ergodic exploration of the Hilbert space. Specifically, this mechanism predicts the equilibration of all (concentrated) macroscopic observables, in almost all states in an initial ensemble and almost all times within finite and longer intervals, given only the observable-independent information that the return probability of the ensemble of initial states is small over a finite time range. As a special case, it also accesses standard results on equilibration over infinitely long times in terms of (stronger versions of) the effective dimension of initial state delocalization in the energy eigenbasis. Our results incorporate macroscopic thermalization into the domain of operational quantum statistical mechanics, recently developed to provide finitely computable criteria for microscopic thermalization. We discuss an overall characterization of this approach as establishing connections between (1) the decay of a (theoretically or experimentally) computable probe indicating memorylessness, (2) a fundamental invariant mechanism in terms of the alignment of observables or states in the Hilbert space, and (3) predicting different natural forms of (classical and) quantum thermalization, most of which rigorously recover conventional eigenstate-based descriptions of infinite-time thermalization as a special case but provide stronger accessible predictions over finite observation times in the thermodynamic limit.
We identify a general mechanism for the finite-time thermalization of macroscopic observables, such as coarse-grained charge densities, in terms of elementary forms of the quantum dynamics of initial states: (1) aperiodicity, which provides a computable measure of (2) a dynamical partially ergodic exploration of the Hilbert space. Specifically, this mechanism predicts the equilibration of all (concentrated) macroscopic observables, in almost all states in an initial ensemble and almost all times within finite and longer intervals, given only the observable-independent information that the return probability of the ensemble of initial states is small over a finite time range. As a special case, it also accesses standard results on equilibration over infinitely long times in terms of (stronger versions of) the effective dimension of initial state delocalization in the energy eigenbasis. Our results incorporate macroscopic thermalization into the domain of operational quantum statistical mechanics, recently developed to provide finitely computable criteria for microscopic thermalization. We discuss an overall characterization of this approach as establishing connections between (1) the decay of a (theoretically or experimentally) computable probe indicating memorylessness, (2) a fundamental invariant mechanism in terms of the alignment of observables or states in the Hilbert space, and (3) predicting different natural forms of (classical and) quantum thermalization, most of which rigorously recover conventional eigenstate-based descriptions of infinite-time thermalization as a special case but provide stronger accessible predictions over finite observation times in the thermodynamic limit.
We develop a rigorous system-agnostic method to predict quantum thermalization in an overwhelming fraction of accessible pure states in a many-body system, entirely in terms of certain out-of-time-ordered correlators of few-body observables. In contrast to previous rigorous results on thermalization with semiclassical counterparts, our method is not limited to statistical averages of observables, such as time averages in ergodicity or state averages in mixing. Moreover, consistent with such approaches, we retain the advantage of not requiring a detailed knowledge of energy eigenstate structure or thermodynamically large times, which can become intractable for systems with more than a handful of particles. Our approach is centered on a geometric result that connects thermalization to the alignment of high dimensional subspaces in a Hilbert space, which is determined by the saturation of "controllably nonlocal" out-of-time-ordered correlators. We discuss the possibility of predicting quantum thermalization in almost all states at almost all times from finite-time observations of a single such correlator per observable. This formalism reduces the problem of establishing pure state quantum thermalization at finite times in almost all complex many-body states to a theoretically or experimentally accessible study of few-body correlators, even in thermodynamically large systems.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
Eigenstate thermalization has played a prominent role as a determiner of the validity of quantum statistical mechanics since von Neumann’s early works on quantum ergodicity. However, its connection to the dynamical process of quantum thermalization relies sensitively on nondegeneracy properties of the energy spectrum, as well as detailed features of individual eigenstates that are effective only over correspondingly large timescales, rendering it generically inaccessible given practical timescales and finite experimental resources. Here, we introduce the notion of energy-band thermalization to address these limitations, by coarse-graining over energy level spacings with a finite energy resolution. We show that energy-band thermalization implies the thermalization of an observable in almost all states (in any orthonormal basis) over accessible timescales without relying on microscopic properties of the energy eigenvalues or eigenstates, and conversely, can be efficiently accessed in experiments via the dynamics of a single mixed state (for a given observable) with only polynomially many resources in the system size. This allows us to directly determine thermalization, including in the presence of conserved charges, from this state: Most strikingly, if an observable thermalizes in this initial state over a finite range of times, then it must thermalize in almost all physical initial states over all longer timescales. As applications, we derive a finite-time Mazur-Suzuki inequality for quantum transport with approximately conserved charges, and establish the thermalization of local observables over finite timescales in almost all accessible states in (generally inhomogeneous) dual-unitary quantum circuits. We also propose measurement protocols for general many-qubit systems. This work initiates a rigorous treatment of quantum thermalization in terms of experimentally accessible quantities.
Recent advances in quantum simulation have enabled the discovery of novel forms of universality in quantum many-body dynamics. In this Review, we discuss deep thermalization and Hilbert space ergodicity--two recently discovered phenomena characterized by the emergence of distributions of quantum states that are "maximally random" in a precise sense. They offer a new perspective on how irreversible statistical mechanics arises from reversible unitary quantum dynamics, going beyond conventional theories of quantum thermalization and equilibration. We review a unifying framework, rooted in quantum information theory and principles of maximum entropy, that explains the different forms of ergodicity which arise under various physical constraints. We discuss open questions and active research directions, including generalizations beyond ensembles of pure quantum states, phase transitions in deep thermalization tied to deeper forms of ergodicity-breaking, connections to broader topics in quantum thermalization and ergodicity, and applications in quantum information science, such as for benchmarking or tomography.
Using the ergodicity principle for the expectation values of several types of observables, we investigate the thermalization process in isolated fermionic systems.These are described by the two-body random ensemble, which is a paradigmatic model to study quantum chaos and especially the dynamical transition from integrability to chaos.By means of exact diagonalizations we analyze the relevance of the eigenstate thermalization hypothesis as well as the influence of other factors, such as the energy and structure of the initial state, or the dimension of the Hilbert space.We also obtain analytical expressions linking the degree of thermalization for a given observable with the so-called number of principal components for transition strengths originating at a given energy, with the dimensions of the whole Hilbert space and microcanonical energy shell, and with the correlations generated by the observable.As the strength of the residual interaction is increased, an order-to-chaos transition takes place, and we show that the onset of Wigner spectral fluctuations, which is the standard signature of chaos, is not sufficient to guarantee thermalization in finite systems.When all the signatures of chaos are fulfilled, including the quasicomplete delocalization of eigenfunctions, the eigenstate thermalization hypothesis is the mechanism responsible for the thermalization of certain types of observables, such as (linear combinations of) occupancies and strength function operators.Our results also suggest that fully chaotic systems will thermalize relative to most observables in the thermodynamic limit.
Quantum thermalization explains how an isolated many-body system naturally evolves towards a thermal state, rendering information about the initial conditions inaccessible to local measurements. This is precisely the mechanism utilized in quantum error correction, where information is protected by design through a nonlocal encoding. In this work, we leverage this connection to port the rigorous framework of (approximate) quantum error correction to the study of quantum thermalization. Treating typical late-time states as codewords, we characterize the error-correcting properties of generic thermalizing dynamics. We numerically uncover a universal relationship between the encoding rate, distance, and thermal entropy density of the emergent code. At infinite temperature, this universal curve saturates the quantum Singleton bound, achieving the same optimal limit as Haar-random codes. At finite temperature, we introduce a code family based on the Scrooge ensemble, the natural thermal analogue of the Haar ensemble, and prove it saturates the entropic quantum Singleton bound, establishing this family as optimal within entropic constraints. Our extracted universal curve independently saturates this same bound, revealing that finite-temperature thermalization is itself optimal. Finally, we show how conserved quantities limit the error-correcting behavior of thermalization: codewords with differing energies, or other conserved charges, leak only classical information, and correctability persists until the difference reaches the scale of thermal fluctuations. Our results reveal a universal optimal coding structure in thermalizing dynamics, while introducing new optimal codes that achieve fundamental limits of approximate quantum error correction.