Using the ergodicity principle for the expectation values of several types of observables, we investigate the thermalization process in isolated fermionic systems. These are described by the two-body random ensemble, which is a paradigmatic model to study quantum chaos and especially the dynamical transition from integrability to chaos. By means of exact diagonalizations we analyze the relevance of the eigenstate thermalization hypothesis as well as the influence of other factors, such as the energy and structure of the initial state, or the dimension of the Hilbert space. We also obtain analytical expressions linking the degree of thermalization for a given observable with the so-called number of principal components for transition strengths originating at a given energy, with the dimensions of the whole Hilbert space and microcanonical energy shell, and with the correlations generated by the observable. As the strength of the residual interaction is increased, an order-to-chaos transition takes place, and we show that the onset of Wigner spectral fluctuations, which is the standard signature of chaos, is not sufficient to guarantee thermalization in finite systems. When all the signatures of chaos are fulfilled, including the quasicomplete delocalization of eigenfunctions, the eigenstate thermalization hypothesis is the mechanism responsible for the thermalization of certain types of observables, such as (linear combinations of) occupancies and strength function operators. Our results also suggest that fully chaotic systems will thermalize relative to most observables in the thermodynamic limit.Using the ergodicity principle for the expectation values of several types of observables, we investigate the thermalization process in isolated fermionic systems. These are described by the two-body random ensemble, which is a paradigmatic model to study quantum chaos and especially the dynamical transition from integrability to chaos. By means of exact diagonalizations we analyze the relevance of the eigenstate thermalization hypothesis as well as the influence of other factors, such as the energy and structure of the initial state, or the dimension of the Hilbert space. We also obtain analytical expressions linking the degree of thermalization for a given observable with the so-called number of principal components for transition strengths originating at a given energy, with the dimensions of the whole Hilbert space and microcanonical energy shell, and with the correlations generated by the observable. As the strength of the residual interaction is increased, an order-to-chaos transition takes place, and we show that the onset of Wigner spectral fluctuations, which is the standard signature of chaos, is not sufficient to guarantee thermalization in finite systems. When all the signatures of chaos are fulfilled, including the quasicomplete delocalization of eigenfunctions, the eigenstate thermalization hypothesis is the mechanism responsible for the thermalization of certain types of observables, such as (linear combinations of) occupancies and strength function operators. Our results also suggest that fully chaotic systems will thermalize relative to most observables in the thermodynamic limit.

Jan 1, 200824 citations

Thermalization in a closed quantum system from randomized dynamics

Nikolay V. Gnezdilov, Andrei I. Pavlov

The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.

cond-mat.stat-mechCross-listedarXiv:2601.00056Jan 2, 20260 citations

On thermalization in random free fermions: Statistical origins and energy-dependent ETH structure

Xiao-Kan Guo, Zhiqiang Huang

We analyze thermalization and eigenstate thermalization in the random free fermion model, a quadratic Hamiltonian with a Gaussian Orthogonal Ensemble hopping matrix, by an exact random-matrix calculation. For a single-particle observable $A$ we compute the ensemble average and fluctuations of $\operatorname{Tr}(Aρ(t))$ : we derive the relaxation envelope $g^2(t/τ_λ)$ with $τ_λ= \hbar/(2η\sqrt{N})$ and its oscillatory $|t|^{-3}$ tail, both properties of the semicircular limiting density, and we show that the variance of the fluctuations is $O(1/N)$ , so that the relaxation profile self-averages at fixed scaled time. Incorporating particle-number conservation, we prove a factorization theorem for the energy-shell statistics of the many-body eigenstates: the energy-independent ETH structure follows from the statistical independence of the eigenvector matrix and the spectrum, and at fixed realization the energy constraint enters only through a covariance subtraction of relative order $1/N$ . A controlled eigenvector--eigenvalue correlation deformation $H(\varepsilon)=H_0+\varepsilon H_1$ then generates, at first order in $\varepsilon$ , the energy dependence of the diagonal energy-resolved slope and of the off-diagonal spectral function, a single-particle diagnostic of the ETH structure in the allowed particle-hole sector. Correlation-function fluctuations and the single-particle spectral form factor finally identify the subleading $O(1/N)$ late-time fingerprints of two-level spectral correlations. The model thus separates eigenbasis chaos from spectral chaos and identifies the statistical origin of energy-independent versus energy-dependent ETH.We analyze thermalization and eigenstate thermalization in the random free fermion model, a quadratic Hamiltonian with a Gaussian Orthogonal Ensemble hopping matrix, by an exact random-matrix calculation. For a single-particle observable $A$ we compute the ensemble average and fluctuations of $\operatorname{Tr}(Aρ(t))$: we derive the relaxation envelope $g^2(t/τ_λ)$ with $τ_λ= \hbar/(2η\sqrt{N})$ and its oscillatory $|t|^{-3}$ tail, both properties of the semicircular limiting density, and we show that the variance of the fluctuations is $O(1/N)$, so that the relaxation profile self-averages at fixed scaled time. Incorporating particle-number conservation, we prove a factorization theorem for the energy-shell statistics of the many-body eigenstates: the energy-independent ETH structure follows from the statistical independence of the eigenvector matrix and the spectrum, and at fixed realization the energy constraint enters only through a covariance subtraction of relative order $1/N$. A controlled eigenvector--eigenvalue correlation deformation $H(\varepsilon)=H_0+\varepsilon H_1$ then generates, at first order in $\varepsilon$, the energy dependence of the diagonal energy-resolved slope and of the off-diagonal spectral function, a single-particle diagnostic of the ETH structure in the allowed particle-hole sector. Correlation-function fluctuations and the single-particle spectral form factor finally identify the subleading $O(1/N)$ late-time fingerprints of two-level spectral correlations. The model thus separates eigenbasis chaos from spectral chaos and identifies the statistical origin of energy-independent versus energy-dependent ETH.

arXiv:2610.01414Oct 1, 20260 citations

Eigenstate Thermalization and Spectral Imprints of the Hamiltonian in Local Observables

Shivam Mishra, C Jisha, Ravi Prakash

The Eigenstate Thermalization Hypothesis explains thermalization in isolated quantum systems through the statistical properties of observables in the energy eigenbasis. We investigate the crossover from integrability to chaos in the spin- $1/2$ XXZ chain, establishing a direct correspondence between the spectral correlations of the Hamiltonian and local observables expressed in the energy eigenbasis as a signature of ergodicity breaking. By introducing a local perturbation that drives the system from integrability to chaos, we track the standard ETH indicators and the eigenstate entanglement entropy. We introduce a submatrix-based framework for analyzing local observables in the energy eigenbasis. By extracting real-symmetric blocks along the diagonal of the local observables represented in eigenbasis, we show that these submatrices exhibit both the short-range and long-range spectral features of the Hamiltonian. Remarkably, this correspondence persists even in a partially ergodic regime, indicating that the emergence of chaos is already encoded locally within the observables' matrix structure and that small blocks are sufficient to capture the underlying spectral correlations.The Eigenstate Thermalization Hypothesis explains thermalization in isolated quantum systems through the statistical properties of observables in the energy eigenbasis. We investigate the crossover from integrability to chaos in the spin-$1/2$ XXZ chain, establishing a direct correspondence between the spectral correlations of the Hamiltonian and local observables expressed in the energy eigenbasis as a signature of ergodicity breaking. By introducing a local perturbation that drives the system from integrability to chaos, we track the standard ETH indicators and the eigenstate entanglement entropy. We introduce a submatrix-based framework for analyzing local observables in the energy eigenbasis. By extracting real-symmetric blocks along the diagonal of the local observables represented in eigenbasis, we show that these submatrices exhibit both the short-range and long-range spectral features of the Hamiltonian. Remarkably, this correspondence persists even in a partially ergodic regime, indicating that the emergence of chaos is already encoded locally within the observables' matrix structure and that small blocks are sufficient to capture the underlying spectral correlations.

quant-pharXiv:2601.09340Jan 15, 20260 citations

Effects of the interplay between initial state and Hamiltonian on the thermalization of isolated quantum many-body systems

Eduardo Jonathan Torres-Herrera, Léa Ferreira dos Santos

We explore the role of the initial state on the onset of thermalization in isolated quantum many-body systems after a quench. The initial state is an eigenstate of an initial Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ and it evolves according to a different final Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$. If the initial state has a chaotic structure with respect to ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, i.e., if it fills the energy shell ergodically, thermalization is certain to occur. This happens when ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ is a full random matrix, because its states projected onto ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$ are fully delocalized. The results for the observables then agree with those obtained with thermal states at infinite temperature. However, finite real systems with few-body interactions, as the ones considered here, are deprived of fully extended eigenstates, even when described by a nonintegrable Hamiltonian. We examine how the initial state delocalizes as it gets closer to the middle of the spectrum of ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, causing the observables to approach thermal averages, be the models integrable or chaotic. Our numerical studies are based on initial states with energies that cover the entire lower half of the spectrum of one-dimensional Heisenberg spin-1/2 systems.We explore the role of the initial state on the onset of thermalization in isolated quantum many-body systems after a quench. The initial state is an eigenstate of an initial Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ and it evolves according to a different final Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$. If the initial state has a chaotic structure with respect to ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, i.e., if it fills the energy shell ergodically, thermalization is certain to occur. This happens when ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ is a full random matrix, because its states projected onto ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$ are fully delocalized. The results for the observables then agree with those obtained with thermal states at infinite temperature. However, finite real systems with few-body interactions, as the ones considered here, are deprived of fully extended eigenstates, even when described by a nonintegrable Hamiltonian. We examine how the initial state delocalizes as it gets closer to the middle of the spectrum of ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, causing the observables to approach thermal averages, be the models integrable or chaotic. Our numerical studies are based on initial states with energies that cover the entire lower half of the spectrum of one-dimensional Heisenberg spin-1/2 systems.

arXiv:1305.6937Physical Review EOct 11, 201349 citations

From quantum chaos and eigenstate thermalization to statistical mechanics and thermodynamics

Luca D’Alessio, Yariv Kafri, Anatoli Polkovnikov +1 more

This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, the fluctuation–dissipation relation, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. In some cases, it is possible to extend their regimes of applicability beyond the standard thermal equilibrium domain. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We present results from numerical experiments and analytical studies of quantum quenches at integrability. We introduce the concept of the generalized Gibbs ensemble and discuss its connection with ideas of prethermalization in weakly interacting systems.This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, the fluctuation–dissipation relation, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. In some cases, it is possible to extend their regimes of applicability beyond the standard thermal equilibrium domain. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We present results from numerical experiments and analytical studies of quantum quenches at integrability. We introduce the concept of the generalized Gibbs ensemble and discuss its connection with ideas of prethermalization in weakly interacting systems.

arXiv:1509.06411Advances In PhysicsMay 3, 20162,413 citations

A

we compute the ensemble average and fluctuations of

\operatorname{Tr}(Aρ(t))

: we derive the relaxation envelope

g^2(t/τ_λ)

with

τ_λ= \hbar/(2η\sqrt{N})

and its oscillatory

|t|^{-3}

tail, both properties of the semicircular limiting density, and we show that the variance of the fluctuations is

O(1/N)

, so that the relaxation profile self-averages at fixed scaled time. Incorporating particle-number conservation, we prove a factorization theorem for the energy-shell statistics of the many-body eigenstates: the energy-independent ETH structure follows from the statistical independence of the eigenvector matrix and the spectrum, and at fixed realization the energy constraint enters only through a covariance subtraction of relative order

1/N

. A controlled eigenvector--eigenvalue correlation deformation

H(\varepsilon)=H_0+\varepsilon H_1

then generates, at first order in

\varepsilon

, the energy dependence of the diagonal energy-resolved slope and of the off-diagonal spectral function, a single-particle diagnostic of the ETH structure in the allowed particle-hole sector. Correlation-function fluctuations and the single-particle spectral form factor finally identify the subleading

O(1/N)

late-time fingerprints of two-level spectral correlations. The model thus separates eigenbasis chaos from spectral chaos and identifies the statistical origin of energy-independent versus energy-dependent ETH.

1/2

XXZ chain, establishing a direct correspondence between the spectral correlations of the Hamiltonian and local observables expressed in the energy eigenbasis as a signature of ergodicity breaking. By introducing a local perturbation that drives the system from integrability to chaos, we track the standard ETH indicators and the eigenstate entanglement entropy. We introduce a submatrix-based framework for analyzing local observables in the energy eigenbasis. By extracting real-symmetric blocks along the diagonal of the local observables represented in eigenbasis, we show that these submatrices exhibit both the short-range and long-range spectral features of the Hamiltonian. Remarkably, this correspondence persists even in a partially ergodic regime, indicating that the emergence of chaos is already encoded locally within the observables' matrix structure and that small blocks are sufficient to capture the underlying spectral correlations.