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arXiv:2601.09340

Eigenstate Thermalization and Spectral Imprints of the Hamiltonian in Local Observables

Shivam Mishra, C Jisha, Ravi Prakash

quant-phcond-mat.stat-mechnlin.CDSubmitted Jan 14, 2026• Announced Jan 15, 2026• 0 citations
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Abstract

The Eigenstate Thermalization Hypothesis explains thermalization in isolated quantum systems through the statistical properties of observables in the energy eigenbasis. We investigate the crossover from integrability to chaos in the spin-$1/2$ XXZ chain, establishing a direct correspondence between the spectral correlations of the Hamiltonian and local observables expressed in the energy eigenbasis as a signature of ergodicity breaking. By introducing a local perturbation that drives the system from integrability to chaos, we track the standard ETH indicators and the eigenstate entanglement entropy. We introduce a submatrix-based framework for analyzing local observables in the energy eigenbasis. By extracting real-symmetric blocks along the diagonal of the local observables represented in eigenbasis, we show that these submatrices exhibit both the short-range and long-range spectral features of the Hamiltonian. Remarkably, this correspondence persists even in a partially ergodic regime, indicating that the emergence of chaos is already encoded locally within the observables' matrix structure and that small blocks are sufficient to capture the underlying spectral correlations.

Comments
14 pages, 13 figures

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The Eigenstate Thermalization Hypothesis explains thermalization in isolated quantum systems through the statistical properties of observables in the energy eigenbasis. We investigate the crossover from integrability to chaos in the spin-1/21/21/2 XXZ chain, establishing a direct correspondence between the spectral correlations of the Hamiltonian and local observables expressed in the energy eigenbasis as a signature of ergodicity breaking. By introducing a local perturbation that drives the system from integrability to chaos, we track the standard ETH indicators and the eigenstate entanglement entropy. We introduce a submatrix-based framework for analyzing local observables in the energy eigenbasis. By extracting real-symmetric blocks along the diagonal of the local observables represented in eigenbasis, we show that these submatrices exhibit both the short-range and long-range spectral features of the Hamiltonian. Remarkably, this correspondence persists even in a partially ergodic regime, indicating that the emergence of chaos is already encoded locally within the observables' matrix structure and that small blocks are sufficient to capture the underlying spectral correlations.
The eigenstate thermalization hypothesis (ETH) is a successful theory that establishes the criteria for ergodicity and thermalization in isolated quantum many-body systems. In this work, we investigate the thermalization properties of a spin-1/21/21/2 XXZ chain with linearly inhomogeneous interactions. We demonstrate that introduction of the inhomogeneous interactions leads to an onset of quantum chaos and thermalization, which, however, becomes inhibited for sufficiently strong inhomogeneity. To exhibit ETH, and to display its breakdown upon varying the strength of interactions, we probe statistics of energy levels and properties of matrix elements of local observables in eigenstates of the inhomogeneous XXZ spin chain. Moreover, we investigate the dynamics of the entanglement entropy and the survival probability which further evidence the thermalization and its breakdown in the considered model. We outline a way to experimentally realize the XXZ chain with linearly inhomogeneous interactions in systems of ultracold atoms. Our results highlight a mechanism of emergence of ETH due to insertion of inhomogeneities in an otherwise integrable system and illustrate the arrest of quantum dynamics in the presence of strong interactions.
The eigenstate thermalization hypothesis (ETH) is a successful theory that establishes the criteria for ergodicity and thermalization in isolated quantum many-body systems. In this work, we investigate the thermalization properties of spin-$ 1/2 $ XXZ chain with linearly-inhomogeneous interactions. We demonstrate that introduction of the inhomogeneous interactions leads to an onset of quantum chaos and thermalization, which, however, becomes inhibited for sufficiently strong inhomogeneity. To exhibit ETH, and to display its breakdown upon varying the strength of interactions, we probe statistics of energy levels and properties of matrix elements of local observables in eigenstates of the inhomogeneous XXZ spin chain. Moreover, we investigate the dynamics of the entanglement entropy and the survival probability which further evidence the thermalization and its breakdown in the considered model. We outline a way to experimentally realize the XXZ chain with linearly-inhomogeneous interactions in systems of ultracold atoms. Our results highlight a mechanism of emergence of ETH due to insertion of inhomogeneities in an otherwise integrable system and illustrate the arrest of quantum dynamics in presence of strong interactions.
Using numerical exact diagonalization, we study matrix elements of a local spin operator in the eigenbasis of two different nonintegrable quantum spin chains. Our emphasis is on the question to what extent local operators can be represented as random matrices and, in particular, to what extent matrix elements can be considered as uncorrelated. As a main result, we show that the eigenvalue distribution of band submatrices at a fixed energy density is a sensitive probe of the correlations between matrix elements. We find that, on the scales where the matrix elements are in a good agreement with all standard indicators of the eigenstate thermalization hypothesis, the eigenvalue distribution still exhibits clear signatures of the original operator, implying correlations between matrix elements. Moreover, we demonstrate that at much smaller energy scales, the eigenvalue distribution approximately assumes the universal semicircle shape, indicating transition to the random-matrix behavior, and in particular that matrix elements become uncorrelated.
We investigate the extent to which the eigenstate thermalization hypothesis (ETH) is valid or violated in the nonintegrable and the integrable spin-1/2 XXZ chains. We perform the energy-resolved analysis of statistical properties of matrix elements of observables in the energy eigenstate basis. The Hilbert space is divided into energy shells of constant width, and a block submatrix is constructed whose columns and rows correspond to the eigenstates in the respective energy shells. In each submatrix, we measure the second moment of off-diagonal elements in a column. The columnar second moments are distributed with a finite variance for finite-sized systems. We show that the relative variance of the columnar second moments decreases as the system size increases in the non-integrable system. The self-averaging behavior indicates that the energy eigenstates are statistically equivalent to each other, which is consistent with the ETH. In contrast, the relative variance does not decrease with the system size in the integrable system. The persisting eigenstate-to-eigenstate fluctuation implies that the matrix elements cannot be characterized with the energy parameters only. Our result explains the origin for the breakdown of the fluctuation dissipation theorem in the integrable system. The eigenstate-to-eigenstate fluctuations sheds a new light on the meaning of the ETH.
The eigenstate thermalization hypothesis explains the emergence of the thermodynamic equilibrium in isolated quantum many-body systems by assuming a particular structure of the observable's matrix elements in the energy eigenbasis. Schematically, it postulates that off-diagonal matrix elements are random numbers and the observables can be described by random matrix theory (RMT). To what extent a RMT description applies, more precisely at which energy scale matrix elements of physical operators become truly uncorrelated, is, however, not fully understood. We study this issue by introducing a novel numerical approach to probe correlations between matrix elements for Hilbert-space dimensions beyond those accessible by exact diagonalization. Our analysis is based on the evaluation of higher moments of operator submatrices, defined within energy windows of varying width. Considering nonintegrable quantum spin chains, we observe that matrix elements remain correlated even for narrow energy windows corresponding to timescales of the order of thermalization time of the respective observables. We also demonstrate that such residual correlations between matrix elements are reflected in the dynamics of out-of-time-ordered correlation functions.
In classical systems, chaos is clearly defined via the behavior of trajectories. In quantum systems with a classical analogue one finds that the transition from regular to chaotic dynamics is signified by a change in the spectral statistics. This has been found to remain true for quantum systems with no classical analogue, including many-body systems. Furthermore, quantum chaotic systems explore all the allowed configurations in the Hilbert space, i.e. they are ergodic, while integrable systems, and systems in the many-body localized phase, are restricted to a certain subspace of the available phase space, and hence strongly break ergodicity. In this dissertation, we study the intermediate behavior between ergodicity and localization, i.e. the weak breaking of ergodicity. The model examined is the PXP spin chain model, where spins are allowed to flip only under certain kinetic constraints. We start by reproducing some already established results. First, we explore the eigenstate thermalization hypothesis (ETH) for this model and demonstrate the existence of a small number of states, throughout the PXP spectrum, that violate the ETH. Then we study the level-spacing statistics of the model, a well-known quantum chaos diagnostic, which turns out to be close to semi-Poisson and approach Wigner--Dyson statistics for large system sizes. Moreover, we examine various aspects of the model that have not been studied before. For example, the eigenvector component statistics, another quantum chaos diagnostic, for the PXP model turn out to be non-Gaussian. Finally, we perform a quench, in order to study how the energy spreads throughout the system, and observe ballistic fronts.