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arXiv:2503.07729 · SciPost Physics

Bypassing eigenstate thermalization with experimentally accessible quantum dynamics

Amit Vikram

Published Jul 31, 2026• 0 citations
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Abstract

Eigenstate thermalization has played a prominent role as a determiner of the validity of quantum statistical mechanics since von Neumann’s early works on quantum ergodicity. However, its connection to the dynamical process of quantum thermalization relies sensitively on nondegeneracy properties of the energy spectrum, as well as detailed features of individual eigenstates that are effective only over correspondingly large timescales, rendering it generically inaccessible given practical timescales and finite experimental resources. Here, we introduce the notion of energy-band thermalization to address these limitations, by coarse-graining over energy level spacings with a finite energy resolution. We show that energy-band thermalization implies the thermalization of an observable in almost all states (in any orthonormal basis) over accessible timescales without relying on microscopic properties of the energy eigenvalues or eigenstates, and conversely, can be efficiently accessed in experiments via the dynamics of a single mixed state (for a given observable) with only polynomially many resources in the system size. This allows us to directly determine thermalization, including in the presence of conserved charges, from this state: Most strikingly, if an observable thermalizes in this initial state over a finite range of times, then it must thermalize in almost all physical initial states over all longer timescales. As applications, we derive a finite-time Mazur-Suzuki inequality for quantum transport with approximately conserved charges, and establish the thermalization of local observables over finite timescales in almost all accessible states in (generally inhomogeneous) dual-unitary quantum circuits. We also propose measurement protocols for general many-qubit systems. This work initiates a rigorous treatment of quantum thermalization in terms of experimentally accessible quantities.

DOI
10.21468/scipostphys.21.1.029

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Eigenstate thermalization has played a prominent role as a determiner of the validity of quantum statistical mechanics since von Neumann’s early works on quantum ergodicity. However, its connection to the dynamical process of quantum thermalization relies sensitively on nondegeneracy properties of the energy spectrum, as well as detailed features of individual eigenstates that are effective only over correspondingly large timescales, rendering it generically inaccessible given practical timescales and finite experimental resources. Here, we introduce the notion of energy-band thermalization to address these limitations, by coarse-graining over energy level spacings with a finite energy resolution. We show that energy-band thermalization implies the thermalization of an observable in almost all states (in any orthonormal basis) over accessible timescales without relying on microscopic properties of the energy eigenvalues or eigenstates, and conversely, can be efficiently accessed in experiments via the dynamics of a single mixed state (for a given observable) with only polynomially many resources in the system size. This allows us to directly determine thermalization, including in the presence of conserved charges, from this state: Most strikingly, if an observable thermalizes in this initial state over a finite range of times, then it must thermalize in almost all physical initial states over all longer timescales. As applications, we derive a finite-time Mazur-Suzuki inequality for quantum transport with approximately conserved charges, and establish the thermalization of local observables over finite timescales in almost all accessible states in (generally inhomogeneous) dual-unitary quantum circuits. We also propose measurement protocols for general many-qubit systems. This work initiates a rigorous treatment of quantum thermalization in terms of experimentally accessible quantities.
The Eigenstate Thermalization Hypothesis (ETH) has played a key role in recent advances in the high energy and condensed matter communities. It explains how an isolated quantum system in a far-from-equilibrium initial state can evolve to a state that is indistinguishable from thermal equilibrium, with observables relaxing to almost time-independent results that can be described using traditional statistical mechanics ensembles. In this work we probe the limits of ETH, pushing it outside its prototypical applications in several directions. We design a qutrit lattice system with conserved quasilocal charge, in which we verify a form of generalized eigenstate thermalization. We also observe signatures of thermalization in states well outside microcanonical windows of both charge and energy, which we dub `generic ETH.'
We develop a rigorous system-agnostic method to predict quantum thermalization in an overwhelming fraction of accessible pure states in a many-body system, entirely in terms of certain out-of-time-ordered correlators of few-body observables. In contrast to previous rigorous results on thermalization with semiclassical counterparts, our method is not limited to statistical averages of observables, such as time averages in ergodicity or state averages in mixing. Moreover, consistent with such approaches, we retain the advantage of not requiring a detailed knowledge of energy eigenstate structure or thermodynamically large times, which can become intractable for systems with more than a handful of particles. Our approach is centered on a geometric result that connects thermalization to the alignment of high dimensional subspaces in a Hilbert space, which is determined by the saturation of "controllably nonlocal" out-of-time-ordered correlators. We discuss the possibility of predicting quantum thermalization in almost all states at almost all times from finite-time observations of a single such correlator per observable. This formalism reduces the problem of establishing pure state quantum thermalization at finite times in almost all complex many-body states to a theoretically or experimentally accessible study of few-body correlators, even in thermodynamically large systems.
We identify a general mechanism for the finite-time thermalization of macroscopic observables, such as coarse-grained charge densities, in terms of elementary forms of the quantum dynamics of initial states: (1) aperiodicity, which provides a computable measure of (2) a dynamical partially ergodic exploration of the Hilbert space. Specifically, this mechanism predicts the equilibration of all (concentrated) macroscopic observables, in almost all states in an initial ensemble and almost all times within finite and longer intervals, given only the observable-independent information that the return probability of the ensemble of initial states is small over a finite time range. As a special case, it also accesses standard results on equilibration over infinitely long times in terms of (stronger versions of) the effective dimension of initial state delocalization in the energy eigenbasis. Our results incorporate macroscopic thermalization into the domain of operational quantum statistical mechanics, recently developed to provide finitely computable criteria for microscopic thermalization. We discuss an overall characterization of this approach as establishing connections between (1) the decay of a (theoretically or experimentally) computable probe indicating memorylessness, (2) a fundamental invariant mechanism in terms of the alignment of observables or states in the Hilbert space, and (3) predicting different natural forms of (classical and) quantum thermalization, most of which rigorously recover conventional eigenstate-based descriptions of infinite-time thermalization as a special case but provide stronger accessible predictions over finite observation times in the thermodynamic limit.
Proving thermalization from the unitary evolution of closed quantum systems is one of the oldest questions that is still only partially resolved. Efforts led to various versions of the eigenstate thermalization hypothesis (ETH), which implies thermalization under certain conditions. Whether the ETH holds in specific systems is however difficult to verify from the microscopic description of the system. In this work, we focus on thermalization under local Hamiltonians of low-entanglement initial states, which are operationally accessible in many natural physical settings, including schemes for testing thermalization in experiments and quantum simulators. We prove thermalization of these states under precise conditions that have operational significance. More specifically, motivated by arguments of unavoidable finite resolution, we define a random energy smoothing on local Hamiltonians that leads to local thermalization when the initial state has low entanglement. Finally we show that this transformation affects neither the Gibbs state locally nor, under generic smoothness conditions on the spectrum, the short-time dynamics.
The eigenstate thermalization hypothesis conjectures that for a thermodynamically large system in one of its energy eigenstates, the reduced density matrix describing any finite subsystem is determined solely by a set of relevant conserved quantities. In a chaotic quantum system, only the energy is expected to play that role and hence eigenstates appear locally thermal. Integrable systems, on the other hand, possess an extensive number of such conserved quantities and therefore the reduced density matrix requires specification of all the corresponding parameters (generalized Gibbs ensemble). However, here we show by unbiased statistical sampling of the individual eigenstates with a given finite energy density that the local description of an overwhelming majority of these states of even such an integrable system is actually Gibbs-like, i.e., requires only the energy density of the eigenstate. Rare eigenstates that cannot be represented by the Gibbs ensemble can also be sampled efficiently by our method and their local properties are then shown to be described by appropriately truncated generalized Gibbs ensembles. We further show that the presence of these rare eigenstates differentiates the model from the chaotic case and leads to the system being described by a generalized Gibbs ensemble at long time under a unitary dynamics following a sudden quench, even when the initial state is a typical (Gibbs-like) eigenstate of the prequench Hamiltonian.
Proving thermalization from the unitary evolution of a closed quantum system is one of the oldest questions that is still nowadays only partially resolved. Several efforts have led to various formulations of what is called the eigenstate thermalization hypothesis, which leads to thermalization under certain conditions on the initial states. These conditions, however, are sensitive to the precise formulation of the hypothesis. In this work, we focus on the important case of low entanglement initial states, which are operationally accessible in many natural physical settings, including experimental schemes for testing thermalization and for quantum simulation. We prove thermalization of these states under precise conditions that have operational significance. More specifically, motivated by arguments of unavoidable finite resolution, we define a random energy smoothing on local Hamiltonians that leads to local thermalization when the initial state has low entanglement. Finally we show that such a transformation affects neither the Gibbs state locally nor, under generic smoothness conditions on the spectrum, the short-time dynamics.