Regarded as one of the most fundamental concepts of classical mechanics and thermodynamics, work has received well-grounded definitions within the quantum framework since the 1970s, having being successfully applied to many contexts. Recent developments in the concept have taken place in the emergent field of quantum thermodynamics, where work is frequently characterized as a stochastic variable. Notwithstanding this remarkable progress, it is still debatable whether some sensible notion of work can be posed for a strictly quantum instance involving a few-particle system prepared in a pure state and abandoned to its closed autonomous dynamics. By treating work as a quantum mechanical observable with a well-defined classical limit, here we show that this scenario can be satisfactorily materialized. We prove, by explicit examples, that one can indeed assign eigensystems to work operators. This paves the way for frameworks involving quantum superposition and nonlocal steering of work. We also show that two-point measurement protocols can be inappropriate to describe work (and other two-time physical quantities), especially in the semiclassical regime. However subtle it may be, our quantum mechanical notion of work is experimentally testable and requires an updating of our intuition regarding the concept of two-time elements of reality. In this context, we derive a work-energy uncertainty relation, and we illustrate how energy conservation emerges as an element of physical reality.
Regarded as one of the most fundamental concepts of classical mechanics and thermodynamics, work has received well-grounded definitions within the quantum framework since the 1970s, having being successfully applied to many contexts. Recent developments in the concept have taken place in the emergent field of quantum thermodynamics, where work is frequently characterized as a stochastic variable. Notwithstanding this remarkable progress, it is still debatable whether some sensible notion of work can be posed for a strictly quantum instance involving a few-particle system prepared in a pure state and abandoned to its closed autonomous dynamics. By treating work as a quantum mechanical observable with a well-defined classical limit, here we show that this scenario can be satisfactorily materialized. We prove, by explicit examples, that one can indeed assign eigensystems to work operators. This paves the way for frameworks involving quantum superposition and nonlocal steering of work. We also show that two-point measurement protocols can be inappropriate to describe work (and other two-time physical quantities), especially in the semiclassical regime. However subtle it may be, our quantum mechanical notion of work is experimentally testable and requires an updating of our intuition regarding the concept of two-time elements of reality. In this context, we derive a work-energy uncertainty relation, and we illustrate how energy conservation emerges as an element of physical reality.
Of indisputable relevance for nonequilibrium thermodynamics, fluctuations theorems have been generalized to the framework of quantum thermodynamics, with the notion of work playing a key role in such contexts. The typical approach consists of treating work as a stochastic variable and the acting system as an eminently classical device with a deterministic dynamics. Inspired by technological advances in the field of quantum machines, here we look for corrections to work fluctuations theorems when the acting system is allowed to enter the quantum domain. This entails including the acting system in the dynamics and letting it share a nonclassical state with the system acted upon. Moreover, favoring a mechanical perspective to this program, we employ a concept of work observable. For simplicity, we choose as theoretical platform the autonomous dynamics of a two-particle system with an elastic coupling. For some specific processes, we derive several fluctuation theorems within both the quantum and classical statistical arenas. In the quantum results, we find that, along with entanglement and quantum coherence, aspects of inertia also play a significant role since they regulate the route to mechanical equilibrium.
Technological advances over the past few decades have made it possible to address quantum systems down to individual quanta of energy. Artificial atoms are now routinely fabricated and manipulated using solid-state technology. Exciting new applications are now within grasp, such as quantum heat engines, which have been theorised to achieve energy efficiencies not possible for their classical counterparts. Energy fluctuations are an inherent part of these devices and a detailed understanding of them is required. However, the proper theoretical framework under which such fluctuations are to be understood is still debated. In this thesis, we study energy fluctuations in open quantum systems at the level of individual runs of an experimental protocol. This work has been carried out in two parts. In the first part, we focus on calorimetric measurements – a promising new experimental protocol to continuously measure energy fluctuations of a qubit interacting with a thermal environment. Applying the protocol to more complex systems is not straightforward. Using a simple two-level approximation, we show that for some experimental parameters this protocol can be extended to a driven harmonic oscillator. Another aspect of the calorimetric protocol is that it can induce non-Markovian effects which affect how work and heat are defined. We quantify the degree of non-Markovianity induced by this measurement protocol, when applied to a qubit, based on a previously developed theoretical model. Importantly, we show that non-Markovianity does not necessarily decrease monotonically with the environment size. The attempt to extend the calorimetric protocol to general systems has led to the second part of this thesis. The calorimetric detection is a particular case of a continuously monitored system. However, other schemes exist that lead to different definitions of work and heat. Reconciling these approaches is not straightforward, as evidenced by the many work definitions present in the literature. The difficulty is centred at the fact that, in the orthodox interpretation of quantum mechanics, energy is not always a well-defined quantity. Here, based on the Bohmian interpretation of quantum mechanics, we put forward a general framework to remove this problem in a clear conceptual manner. In particular, we show that the classical definition of work for closed systems can be straightforwardly generalised to the quantum case. For an open system, we used the Bohmian conditional wave function which provides a stochastic state evolution for the open system. We show that this approach can lead to new insights regarding the role of entanglement in energy fluctuations and has the potential to provide a general and observer-independent framework of energy fluctuations in open quantum systems. The results presented in this thesis give a small contribution to the developing field of quantum thermodynamics.
Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.
Quantum fluctuations are fundamental to quantum technologies, affecting quantum computing, sensing, cryptography, and thermodynamics. A paradigmatic example is quantum work, which, for a thermally isolated driven system, is identified with the variation of its energy. Although quantum mechanics provides precise rules for measuring energy and other observables at individual instants of time, it does not provide a standard framework for characterizing the statistics of their variations between two times. This ambiguity has led to competing protocols that can assign different work distributions--and, more generally, different fluctuation statistics--to the same physical process, with consequences for both foundational physics and quantum technologies. In this work, we propose four fundamental criteria that any consistent protocol for measuring energy variations must satisfy, grounded in conservation laws, state independence of the measurement apparatus, the no-signaling principle, and constraints on physical reality. We prove that these criteria uniquely select the two-time quantum observable protocol. We then show that this conclusion extends beyond work and energy to the variation of arbitrary physical observables, including charge, particle number, and momentum. This result has the potential to establish the foundations for measurements of quantum processes, possibly resolving ambiguities in quantum fluctuation measurements. Moreover, it enables the extension of quantum information concepts, such as entanglement and Bell's inequalities, to processes rather than instantaneous observables.
A definition of quantum mechanical work is introduced in this dissertation, preserving the mathematical structure of the Classical Mechanics concept of work without, however, in any way invoking the notion of trajectory. By use of Gaussian states and the Caldirola-Kanai model, a case study is conducted through which the proposed quantum work is compared with another Quantum Thermodynamics well-known definition, both in quantum and semiclassical regimes, showing promising results. Finally the new definition is investigated in comparison with a classical-statistical approach for superposition and mixed states.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.