Of indisputable relevance for nonequilibrium thermodynamics, fluctuations theorems have been generalized to the framework of quantum thermodynamics, with the notion of work playing a key role in such contexts. The typical approach consists of treating work as a stochastic variable and the acting system as an eminently classical device with a deterministic dynamics. Inspired by technological advances in the field of quantum machines, here we look for corrections to work fluctuations theorems when the acting system is allowed to enter the quantum domain. This entails including the acting system in the dynamics and letting it share a nonclassical state with the system acted upon. Moreover, favoring a mechanical perspective to this program, we employ a concept of work observable. For simplicity, we choose as theoretical platform the autonomous dynamics of a two-particle system with an elastic coupling. For some specific processes, we derive several fluctuation theorems within both the quantum and classical statistical arenas. In the quantum results, we find that, along with entanglement and quantum coherence, aspects of inertia also play a significant role since they regulate the route to mechanical equilibrium.
Of indisputable relevance for nonequilibrium thermodynamics, fluctuations theorems have been generalized to the framework of quantum thermodynamics, with the notion of work playing a key role in such contexts. The typical approach consists of treating work as a stochastic variable and the acting system as an eminently classical device with a deterministic dynamics. Inspired by technological advances in the field of quantum machines, here we look for corrections to work fluctuations theorems when the acting system is allowed to enter the quantum domain. This entails including the acting system in the dynamics and letting it share a nonclassical state with the system acted upon. Moreover, favoring a mechanical perspective to this program, we employ a concept of work observable. For simplicity, we choose as theoretical platform the autonomous dynamics of a two-particle system with an elastic coupling. For some specific processes, we derive several fluctuation theorems within both the quantum and classical statistical arenas. In the quantum results, we find that, along with entanglement and quantum coherence, aspects of inertia also play a significant role since they regulate the route to mechanical equilibrium.
Fluctuation theorems for work provide universal constraints on nonequilibrium fluctuations, yet their quantum generalizations often rely on externally prescribed classical driving protocols. While for classical systems, fluctuation theorems have been extended to autonomous work, where the dynamics of the work source is subject to the backaction of the system, their generalization to the quantum regime is constrained by the uncertainty principle. Here, we extend fluctuation theorems for autonomous work from the classical regime to the quantum regime. By performing successive projective measurements over the work source and the system, we derive Jarzynski-type and Crooks-type fluctuation theorems for autonomous inclusive work from initial mixed thermal states. These relations are analogous to fluctuation theorems for autonomous work in the classical regime and explicitly incorporate the fluctuations of the work source. However, quantum noncommutativity prevents a consistent reduction to the nonautonomous counterparts, even in the limit of a large work source and correspondingly negligible backaction. By contrast, under the exclusive work definition, the nonautonomous limit is recovered when the measured observable of the work source commutes with its bare Hamiltonian and the backaction of the system on the work source is negligible. Our results are illustrated with the Dicke model, where a single-mode radiation field and an ensemble of two-level atoms act as the system of interest and the work source, respectively.
Regarded as one of the most fundamental concepts of classical mechanics and thermodynamics, work has received well-grounded definitions within the quantum framework since the 1970s, having being successfully applied to many contexts. Recent developments in the concept have taken place in the emergent field of quantum thermodynamics, where work is frequently characterized as a stochastic variable. Notwithstanding this remarkable progress, it is still debatable whether some sensible notion of work can be posed for a strictly quantum instance involving a few-particle system prepared in a pure state and abandoned to its closed autonomous dynamics. By treating work as a quantum mechanical observable with a well-defined classical limit, here we show that this scenario can be satisfactorily materialized. We prove, by explicit examples, that one can indeed assign eigensystems to work operators. This paves the way for frameworks involving quantum superposition and nonlocal steering of work. We also show that two-point measurement protocols can be inappropriate to describe work (and other two-time physical quantities), especially in the semiclassical regime. However subtle it may be, our quantum mechanical notion of work is experimentally testable and requires an updating of our intuition regarding the concept of two-time elements of reality. In this context, we derive a work-energy uncertainty relation, and we illustrate how energy conservation emerges as an element of physical reality.
Abstract Quantum thermodynamics allows for the interconversion of quantum coherence and mechanical work. Quantum coherence is thus a potential physical resource for quantum machines. However, formulating a general nonequilibrium thermodynamics of quantum coherence has turned out to be challenging. In particular, precise conditions under which coherence is beneficial to or, on the contrary, detrimental for work extraction from a system have remained elusive. We here develop a generic dynamic-Bayesian-network approach to the far-from-equilibrium thermodynamics of coherence. We concretely derive generalized fluctuation relations and a maximum-work theorem that fully account for quantum coherence at all times, for both closed and open dynamics. We obtain criteria for successful coherence-to-work conversion, and identify a nonequilibrium regime where maximum work extraction is increased by quantum coherence for fast processes beyond linear response.
This article traces the development of fluctuation theory and its deep connection to irreversibility, from equilibrium to near-equilibrium, and finally to far-from-equilibrium systems. Classical fluctuation theorems, which capture the statistical behaviour of thermodynamic systems far from equilibrium, are now well established. Their quantum counterparts, however, remain an active area of research. In this review, we highlight recent advances by linking quantum fluctuation theorems with linear response theory, offering new insights into the nature of quantum fluctuations and irreversibility in the near-equilibrium regime. Particular emphasis is placed on dissipated work in quantum systems as a pathway to observing non-classical effects in quantum thermodynamics. Understanding quantum fluctuations is not only essential for clarifying the foundations of irreversibility but also crucial for the development of novel quantum technologies, including quantum computers, sensors, and metrological devices.
Thermodynamics typically concerns the physical behaviour of macroscopic systems comprised of many particles. However, recent theoretical progress has extended the theory to both the classical-stochastic and quantum regimes, where systems are comprised of just a small number of particles. In this thesis I investigate a range of situations in which new thermodynamic phenomena emerge due to the reduced size of the systems involved. One central assumption in macroscopic thermodynamics is the weak coupling approximation, which posits that the equilibrium properties of a system are not influenced by the interactions with its surrounding environment. However, for microscopic systems this assumption can break down, and I derive new fluctuation relations that provide a refined form of the second law of thermodynamics in this strong-coupling regime, taking into account corrections stemming from these interactions. In this work I provide a characterisation of stochastic heat and entropy production for small scale classical systems that are defined regardless of the strength of interaction. I then show that these definitions lead to a consistent thermodynamic framework valid beyond the usual weak-coupling regime. The thesis also concerns the effect of interactions on the equilibrium properties of strongly-coupled quantum systems, and I investigate how these interactions can influence the resulting temperature fluctuations in this regime. Using tools from quantum estimation theory, I derive an uncertainty relation between energy and temperature valid at all coupling strengths and system sizes. The relation reveals how quantum energy coherences contribute to statistical fluctuations in the estimated temperature of small- scale systems. Finally, I investigate how quantum fluctuations influence the statistics of work extracted from slowly-driven quantum systems. I prove that, unlike in classical systems, the work dissipated by a general quantum system is no longer proportional to its statistical fluctuations. This result reveals new subtleties involved in designing optimal quantum thermodynamic processes.
Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward out-of-equilibrium quantum process and in a corresponding backward one. In particular, the initial states of the two processes are thermal states and thus incoherent in the energy basis. Here we aim to investigate the role of initial quantum coherence in work fluctuation theorems, by considering a quasiprobability distribution of work. To do this, we formulate and examine the implications of a detailed fluctuation theorem, which reproduces the Tasaki-Crooks fluctuation theorem in the absence of initial quantum coherence.