A definition of quantum mechanical work is introduced in this dissertation, preserving the mathematical structure of the Classical Mechanics concept of work without, however, in any way invoking the notion of trajectory. By use of Gaussian states and the Caldirola-Kanai model, a case study is conducted through which the proposed quantum work is compared with another Quantum Thermodynamics well-known definition, both in quantum and semiclassical regimes, showing promising results. Finally the new definition is investigated in comparison with a classical-statistical approach for superposition and mixed states.
A definition of quantum mechanical work is introduced in this dissertation, preserving the mathematical structure of the Classical Mechanics concept of work without, however, in any way invoking the notion of trajectory. By use of Gaussian states and the Caldirola-Kanai model, a case study is conducted through which the proposed quantum work is compared with another Quantum Thermodynamics well-known definition, both in quantum and semiclassical regimes, showing promising results. Finally the new definition is investigated in comparison with a classical-statistical approach for superposition and mixed states.
Regarded as one of the most fundamental concepts of classical mechanics and thermodynamics, work has received well-grounded definitions within the quantum framework since the 1970s, having being successfully applied to many contexts. Recent developments in the concept have taken place in the emergent field of quantum thermodynamics, where work is frequently characterized as a stochastic variable. Notwithstanding this remarkable progress, it is still debatable whether some sensible notion of work can be posed for a strictly quantum instance involving a few-particle system prepared in a pure state and abandoned to its closed autonomous dynamics. By treating work as a quantum mechanical observable with a well-defined classical limit, here we show that this scenario can be satisfactorily materialized. We prove, by explicit examples, that one can indeed assign eigensystems to work operators. This paves the way for frameworks involving quantum superposition and nonlocal steering of work. We also show that two-point measurement protocols can be inappropriate to describe work (and other two-time physical quantities), especially in the semiclassical regime. However subtle it may be, our quantum mechanical notion of work is experimentally testable and requires an updating of our intuition regarding the concept of two-time elements of reality. In this context, we derive a work-energy uncertainty relation, and we illustrate how energy conservation emerges as an element of physical reality.
Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.
Work belongs to the most basic notions in thermodynamics but it is not well understood in quantum systems, especially in open quantum systems. By introducing a novel concept of the work functional along an individual Feynman path, we invent a new approach to study thermodynamics in the quantum regime. Using the work functional, we derive a path integral expression for the work statistics. By performing the ℏ expansion, we analytically prove the quantum-classical correspondence of the work statistics. In addition, we obtain the quantum correction to the classical fluctuating work. We can also apply this approach to an open quantum system in the strong coupling regime described by the quantum Brownian motion model. This approach provides an effective way to calculate the work in open quantum systems by utilizing various path integral techniques. As an example, we calculate the work statistics for a dragged harmonic oscillator in both isolated and open quantum systems.
In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines, in an analogous way to the role played, for macroscopic machines, by the energy stored in the idealisation of a lifted weight. Despite several attempts to resolve this issue by putting forward specific models, these are far from realistically capturing the transitions that a quantum machine is expected to perform. In this work, we adopt a novel strategy by considering arbitrary kinds of systems that one can attach to a quantum thermal machine and defining work quantifiers . These are functions that measure the value of a transition and generalise the concept of work beyond those models familiar from phenomenological thermodynamics. We do so by imposing simple operational axioms that any reasonable work quantifier must fulfil and by deriving from them stringent mathematical condition with a clear physical interpretation. Our approach allows us to derive much of the structure of the theory of thermodynamics without taking the definition of work as a primitive. We can derive, for any work quantifier , a quantitative second law in the sense of bounding the work that can be performed using some non-equilibrium resource by the work that is needed to create it. We also discuss in detail the role of reversibility and correlations in connection with the second law. Furthermore, we recover the usual identification of work with energy in degrees of freedom with vanishing entropy as a particular case of our formalism. Our mathematical results can be formulated abstractly and are general enough to carry over to other resource theories than quantum thermodynamics.
This doctoral dissertation on the foundations of quantum theory isolates and then formalizes a physically relevant concept that I have called "Epistemic Constraint." Here, epistemic constraints are the definite, intersubjectively agreeable, ordinary-language conditions under which experiments are described. The usual formulation of the quantum measurement problem, which I call the Schrodingerian measurement problem, has the structure of an anomaly: if we take quantum theory at face value, we expect no definite values, and yet we see definite values in experiments. The responses to this problem have been either to solve it or to dissolve it. These responses, which have taken the form of interpretation, modification, or reconstruction of quantum mechanics, seek either to derive (conceptually or mathematically) epistemic constraints from within quantum mechanics or suitable modifications of it, as is the case with certain interpretations and modifications, or to posit the epistemic constraint, or parts of it, as a primitive assumption with the goal of deriving quantum mechanics, as is the case in some reconstruction programs. In contrast to the Schrodingerian measurement problem, which had the structure of an anomaly, this dissertation develops the Bohrian Program, which (for lack of a better comparison) has a structure similar to the problem historically associated with Euclid's fifth postulate. It seeks to keep epistemic constraints as primitive in an onto-epistemic sense. It then seeks new physical conclusions from the joint consideration of quantum mechanics and epistemic constraints, without seeking to derive one from the other. Among other results, this leads to a notion of the probability of instantiability of the Born Rule that specifies when to apply the Born Rule and when to apply a unitary transformation to a quantum state.