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arXiv:quant-ph/0108042 · Journal of Physics A Mathematical and General

Coherent states for the hydrogen atom: discrete and continuous spectra

S A Pol'shin

Published Dec 5, 2001• 3 citations
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Abstract

We construct the systems of generalized coherent states for the discrete and continuous spectra of the hydrogen atom. These systems are expressed in elementary functions and are invariant under the SO (3, 2) (discrete spectrum) and SO (4, 1) (continuous spectrum) subgroups of the dynamical symmetry group SO (4, 2) of the hydrogen atom. Both systems of coherent states are particular cases of the kernel of integral operator which intertwines irreducible representations of the SO (4, 2) group.

DOI
10.1088/0305-4470/34/49/323

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Theoretical and mathematical physics•Jan 1, 2021•1 citation
We construct the systems of generalized coherent states for the discrete and continuous spectra of the hydrogen atom. These systems are expressed in elementary functions and are invariant under the SO (3, 2) (discrete spectrum) and SO (4, 1) (continuous spectrum) subgroups of the dynamical symmetry group SO (4, 2) of the hydrogen atom. Both systems of coherent states are particular cases of the kernel of integral operator which intertwines irreducible representations of the SO (4, 2) group.
We construct the systems of generalised coherent states for the discrete and continuous spectra of the hydrogen atom. These systems are expressed in terms of elementary functions and are invariant under the SO(3,2)SO(3, 2)SO(3,2) (discrete spectrum) and SO(4,1)SO(4, 1)SO(4,1) (continuous spectrum) subgroups of the dynamical symmetry group SO(4,2)SO(4, 2)SO(4,2) of the hydrogen atom. Both systems of coherent states are particular cases of the kernel of integral operator which interwines irreducible representations of the SO(4,2)SO(4, 2)SO(4,2) group.
A new approach is developed for solving spectral problems for operators with continuous spectrum, which consists in the integral transform of the problem by using coherent Schwartz distributions. The constructed family of coherent distributions is a complete analogue of the family of ordinary coherent states. More precisely, it satisfies all Gazeau–Klauder axioms satisfied by the usual coherent states. But in contrast to the coherent states belonging to the point spectrum of the annihilation operator (or operators), the coherent distributions belong to the continuous spectrum of some Hermitian operators. Therefore, the coherent distributions work better than the coherent states as the kernel of the integral representation of generalized eigenfunctions of operators with continuous spectrum. In this work, this approach is demonstrated with an example of solving a basic problem of quantum mechanics, i.e., the problem of the continuous part of the spectrum of the Hamiltonian of the hydrogen atom.
The aim of this chapter is to present a construction of a set of coherent states for the hydrogen atom proposed by Villegas-Blas (The Laplacian on the n-sphere, the hydrogen atom and the Bargmann space representation. Ph.D. thesis, Mathematics Department, University of Virginia, 1996, [251]), Thomas and Villegas-Blas (Commun Math Phys 187:623–645, 1997, [244]). We show that in a semiclassical sense they concentrate essentially around the Kepler orbits (in configuration space) of the classical motion. A suitable unitary transformation (the Fock operator) maps the pure point subspace of the hydrogen atom Hamitonian onto the Hilbert space L2(S3)L^2({\mathbb S}^3)L2(S3) for the S3\mathbb S^3S3 sphere. We study the coherent states for the S3\mathbb S^3S3 sphere (as introduced by Uribe (J Funct Anal 59:535–556, 1984, [247]) and show that the action of the group SO(4) is irreducible in the space generated by the spherical harmonics of a given degree. Note that coherent states for the hydrogen atom have been extensively studied by J. Klauder and his school. We have chosen not to present them here and refer the interested reader to Klauder and Skagerstam (Coherent states, Worlds Scientific Publishing, Singapore, 1985, [167]).