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arXiv:quant-ph/0006050 · Journal of Physics A Mathematical and General

Coherent states for the hydrogen atom

S. A. Pol'shin

Published Sep 13, 2000• 8 citations
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Abstract

We construct a system of coherent states for the hydrogen atom that is expressed in terms of elementary functions. Unlike the previous attempts in this direction, this system possesses properties equivalent to most of those for the harmonic oscillator, with modifications due to the character of the problem.
DOI
10.1088/0305-4470/33/38/102

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The long-standing problem of finding coherent states for the (bound state portion of the) hydrogen atom is positively resolved. The states in question: (i) are normalized and parameterized continuously, (ii) admit a resolution of unity with a positive measure, and (iii) enjoy the property that the temporal evolution of any coherent state by the hydrogen atom Hamiltonian remains a coherent state for all time. Harmonic-oscillator coherent states In modern terms, the distinguished set of states Schrodinger introduced for the harmonic oscillator 1 are now commonly known as coherent states 2 and are given, for all z 2 I C, by jzi j e (za y \\Gammaz a) j0i = e \\Gamma 1 2 jzj 2 1 X n=0 z n p n! jni; (1) where [a; a y ] = 1 as usual. Here jni; n = 0; 1; 2; : : :, denote normalized eigenstates of the number operator N , N jni = njni, which may be identified with the eigenstates of the harmonic oscillator Hamiltonian H 0 = !N = !a y a (¯h = 1). As such it follows that ...
We construct the systems of generalised coherent states for the discrete and continuous spectra of the hydrogen atom. These systems are expressed in terms of elementary functions and are invariant under the SO(3,2)SO(3, 2)SO(3,2) (discrete spectrum) and SO(4,1)SO(4, 1)SO(4,1) (continuous spectrum) subgroups of the dynamical symmetry group SO(4,2)SO(4, 2)SO(4,2) of the hydrogen atom. Both systems of coherent states are particular cases of the kernel of integral operator which interwines irreducible representations of the SO(4,2)SO(4, 2)SO(4,2) group.
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