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arXiv:nucl-th/9311006 · Physical Review A

Possibility that Schrödinger’s conjecture for the hydrogen-atom coherent states is not attainable

Ivaylo Zlatev f, Wei-Min Zhang, D.H. Feng

Published Sep 1, 1994• 21 citations
arXivHTMLPDF

Abstract

We construct the most general SO(4,2) hydrogen-atom coherent states which are the counterpart of Schr\"odinger's harmonic-oscillator coherent states. We show that these states cannot be localized and cannot follow the classical orbits. Thus, Schr\"odinger's conjecture for the hydrogen-atom coherent states is unattainable.

DOI
10.1103/physreva.50.r1973

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We construct the most general SO(4,2) hydrogen-atom coherent states which are the counterpart of Schr"odinger's harmonic-oscillator coherent states. We show that these states cannot be localized and cannot follow the classical orbits. Thus, Schr"odinger's conjecture for the hydrogen-atom coherent states is unattainable.
The long-standing problem of finding coherent states for the (bound state portion of the) hydrogen atom is positively resolved. The states in question: (i) are normalized and parameterized continuously, (ii) admit a resolution of unity with a positive measure, and (iii) enjoy the property that the temporal evolution of any coherent state by the hydrogen atom Hamiltonian remains a coherent state for all time. Harmonic-oscillator coherent states In modern terms, the distinguished set of states Schrodinger introduced for the harmonic oscillator 1 are now commonly known as coherent states 2 and are given, for all z 2 I C, by jzi j e (za y \\Gammaz a) j0i = e \\Gamma 1 2 jzj 2 1 X n=0 z n p n! jni; (1) where [a; a y ] = 1 as usual. Here jni; n = 0; 1; 2; : : :, denote normalized eigenstates of the number operator N , N jni = njni, which may be identified with the eigenstates of the harmonic oscillator Hamiltonian H 0 = !N = !a y a (¯h = 1). As such it follows that ...
Klauder's recent generalization of the harmonic oscillator coherent states [J. Phys A 29, L293 (1996)], is applicable only in nondegenerate systems, requiring some additional structure if applied to systems with degeneracies. The author suggests how this structure could be added, and applies the complete method to the hydrogen atom problem. To illustrate how a certain degree of freedom in the construction may be exercised, states are constructed, which are initially localized and evolve semiclassically, and whose long time evolution exhibits ``fractional revivals.''
Coherent states in the harmonic oscillator have long been thought of as a bridge from quantum mechanics to classical mechanics. Many of their important properties (most notably those involving time evolution) are only valid in the harmonic oscillator and are at best approximations elsewhere. This thesis is an investigation into several means of generalizing coherent states for other systems and examines the resultant states for some systems. One system of interest is the harmonic oscillator with centripetal barrier for which coherent states of several disparate definitions coincide. Also studied is this spherical rotator, a system which is particularly amenable to defining annihilation operator coherent states. A third system under investigation is the hydrogen atom. This system serves as an arena for the development of an extension to a generalization due to Klauder [J. Phys. A. 29(12):L293-L298. 1996]. Klauder's construction is only applicable to systems without energy degeneracies and must be extended for application where degeneracies are present. The author provides a means for this extension and applies the complete construction to the hydrogen atom problem. As a demonstration of how this construction may be adapted, the author constructs Rydberg wave packets which are initially localized and exhibit full and fractional revivals in the long time evolution.
The aim of this chapter is to present a construction of a set of coherent states for the hydrogen atom proposed by Villegas-Blas (The Laplacian on the n-sphere, the hydrogen atom and the Bargmann space representation. Ph.D. thesis, Mathematics Department, University of Virginia, 1996, [251]), Thomas and Villegas-Blas (Commun Math Phys 187:623–645, 1997, [244]). We show that in a semiclassical sense they concentrate essentially around the Kepler orbits (in configuration space) of the classical motion. A suitable unitary transformation (the Fock operator) maps the pure point subspace of the hydrogen atom Hamitonian onto the Hilbert space L2(S3)L^2({\mathbb S}^3)L2(S3) for the S3\mathbb S^3S3 sphere. We study the coherent states for the S3\mathbb S^3S3 sphere (as introduced by Uribe (J Funct Anal 59:535–556, 1984, [247]) and show that the action of the group SO(4) is irreducible in the space generated by the spherical harmonics of a given degree. Note that coherent states for the hydrogen atom have been extensively studied by J. Klauder and his school. We have chosen not to present them here and refer the interested reader to Klauder and Skagerstam (Coherent states, Worlds Scientific Publishing, Singapore, 1985, [167]).