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Theoretical and mathematical physics

The Coherent States of the Hydrogen Atom

Didier Robert, Monique Combescure

Published Jan 1, 2021• 1 citation
Publisher

Abstract

The aim of this chapter is to present a construction of a set of coherent states for the hydrogen atom proposed by Villegas-Blas (The Laplacian on the n-sphere, the hydrogen atom and the Bargmann space representation. Ph.D. thesis, Mathematics Department, University of Virginia, 1996, [251]), Thomas and Villegas-Blas (Commun Math Phys 187:623–645, 1997, [244]). We show that in a semiclassical sense they concentrate essentially around the Kepler orbits (in configuration space) of the classical motion. A suitable unitary transformation (the Fock operator) maps the pure point subspace of the hydrogen atom Hamitonian onto the Hilbert space \(L^2({\mathbb S}^3)\) for the \(\mathbb S^3\) sphere. We study the coherent states for the \(\mathbb S^3\) sphere (as introduced by Uribe (J Funct Anal 59:535–556, 1984, [247]) and show that the action of the group SO(4) is irreducible in the space generated by the spherical harmonics of a given degree. Note that coherent states for the hydrogen atom have been extensively studied by J. Klauder and his school. We have chosen not to present them here and refer the interested reader to Klauder and Skagerstam (Coherent states, Worlds Scientific Publishing, Singapore, 1985, [167]).

DOI
10.1007/978-3-030-70845-0_9

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Coherent states: a contemporary panorama

S. Twareque Ali, Jean-Pierre Antoine, Fabio Bagarello +1 more

Coherent states (CS) of the harmonic oscillator (also called canonical CS) were introduced in 1926 by Schrödinger in answer to a remark by Lorentz on the classical interpretation of the wave function. They were rediscovered in the early 1960s, first (somewhat implicitly) by Klauder in the context of a novel representation of quantum states, then by Glauber and Sudarshan for the description of coherence in lasers. Since then, CS have grown into an extremely rich domain that pervades almost every corner of physics and have also led to the development of several flourishing topics in mathematics. Along the way, a number of review articles have appeared in the literature, devoted to CS, notably the 1985 reprint volume of Klauder and Skagerstam [1], the 1990 review paper by Zhang et al [2], the 1993 Oak Ridge Conference [3] and the 1995 review paper by Ali et al [4]. Textbooks also have been published, among which one might mention the ground breaking text of Perelomov [5] focusing on the group-theoretical aspects, that of Ali et al [6] 1 analyzing systematically the mathematical structure beyond the group-theoretical approach and also the relation to wavelet analysis, that of Dodonov and Man'ko [7] mostly devoted to quantum optics, that of Gazeau [8] more oriented towards the physical, probabilistic and quantization aspects, and finally the very recent one by Combescure and Robert [9]. In retrospect, one can see that the development of CS has gone through a two-phase transition. First, the (simultaneous) discovery in 1972 by Gilmore and Perelomov that CS were rooted in group theory, then the realization that CS can be defined in a purely algebraic way, as an eigenvalue problem or by a series expansion (Malkin and Man'ko 1969, Barut and Girardello 1971, Gazeau and Klauder 1999; references to the original articles may be found in the textbooks quoted above). Both facts resulted in an explosive expansion of the CS literature. We thought, therefore, that the time was ripe to devote a special issue of Journal of Physics A: Mathematical and Theoretical to CS. However, because of limitations of space and time, it would have been impossible to get a fully representative cross-section of papers, covering all the different facets of the subject. Consequently, we have selected 37 articles, including some by a few of the originators of the field. We thank all the authors for submitting their up-to-date thoughts on this fascinating subject. The contents of this special issue are subdivided into five categories: (1) review papers; (2) physics-oriented CS; (3) physics and quantum information; (4) mathematics, general topics; and (5) mathematics, particular problems. (1) Review papers We start with five review papers. The first paper, by Klauder, surveys the many possible applications of affine variables, both in classical and quantum physics. The second, by Sanders, proposes a grand tour of entangled CS, which are present in many fields, such as quantum optics, quantum information processing, etc. The next paper, by Rowe, surveys the field of vector CS and the attendant group representation problems (including induced representations). Then Oriti et al describe a particular class of CS relevant to (loop) quantum gravity. Finally, Combescure and Robert present a comprehensive review of fermionic CS, including all mathematical details. (2) Physics-oriented CS The six contributions in this section deal with specific physical problems: (i) Dajka–Luczka study Gazeau–Klauder cat states associated with a nonlinear Kerr oscillator, instead of the usual canonical CS leading to Schrödinger cat states; (ii) Angelova et al discuss squeezed CS associated with a 1D Morse potential, used in molecular physics; (iii) Bagrov et al study CS in a magnetic solenoid field and prove their completeness; (iv) Blasone–Jizba treat Nambu–Goldstone dynamics in spontaneously broken symmetries, using CS functional integrals; (v) Calixto et al describe accelerated relativistic particles in the context of spontaneous breakdown of conformal SU(2,2) symmetry, using SU(2,2) CS; and (vi) Mortazavi–Tavassoly study f -deformed charge CS and their physical properties (nonclassical features, sub-Poissonian statistical behavior, etc). (3) Physics and quantum information The second group of physically related CS contains four contributions with a distinct quantum information theoretic flavor. First, Thilagam describes the dynamical behavior of entanglement of a pair of qubits (excitons), using a CS basis. Next, Lavoie–de Guise study SU(3) intelligent states (i.e., minimal uncertainty states), of interest in the quantum information community. Then Muñoz constructs discrete CS for n qubits. Finally, Wagner–Kendon explore the continuous variable Deutsch–Jozsa algorithm known in quantum computing in a discrete formulation. (4) Mathematics, general topics In this subgroup, there are eight papers dealing with general properties of CS, independently of any particular system or application. A whole series discusses the interaction between CS and various mathematical objects: pseudodifferential operators and Weyl calculus (Unterberger); induced representations of the affine group and intertwining operators (Elmabrok–Hutnik); measure-free CS and reproducing kernels (Horzela–Szafraniec); extremal POV measures (Heinosaari–Pellonpää); Hilbert W*-modules (Bhattacharyya–Roy); Toeplitz operators (Hutníková–Hutník); and operator localization and homogeneous structure of nilpotent Lie groups (Kisil). In addition, Balazs et al consider multipliers for continuous frames, including CS or wavelet frames. (5) Mathematics, particular problems The second group of mathematically oriented papers contains 14 contributions, devoted to CS in particular systems. We start with a paper by Gilmore, which explores the (sometimes chaotic) evolution of atomic CS under a time-periodic driving field, using sphere maps S 2 → S 2 . Next, we include a paper on CS on the 2-sphere in a magnetic field (Hall–Mitchell); a paper on CS for a quantum particle on a Möbius strip (Cirilo–Lombardo); a discussion of quantization on the circle (Chadzitaskos et al ); SUSY CS for Pöschl–Teller potentials (Bergeron et al ); generalized Bargmann functions and von Neumann lattices (Vourdas et al ); partial reconstruction for a finite CS system, using the Fock–Bargmann representation (Calixto et al ); phase operators for SU(3) irreps, thus for finite quantum systems (de Guise); semiclassical CS in periodic potentials (Carles–Sparber); complexified CS with non-Hermitian Hamiltonians (Graefe–Schubert); minimal uncertainty states in the context of (semisimple) group representation theory (Oszmaniec); localization operators in the time-frequency domain, i.e., in Gabor analysis (Muzhikyan–Avanesyan); and, finally, two papers about fermionic CS (Daoud–Kibler and Trifonov). This brief description illustrates perfectly the extreme versatility of the CS concept. As already stressed, coherent states constitute nowadays a flourishing research topic, with applications to a wide spectrum of domains. Indeed, CS are everywhere in physics: condensed matter physics, atomic physics, nuclear and particle physics, quantum optics, dynamics—both quantum and classical potentials—quantum gravity, quantization and quantum information theory. On the other hand, CS have grown into a fully-fledged domain in mathematics, incorporating many tools such as group representations, POV measures, frames, holomorphic functions, orthogonal polynomials and so on. Interestingly enough, the majority of contributions to this special issue (22 out of 37) are mathematically minded, demonstrating the widespread interest CS have generated in various areas of mathematics. A third field related to CS (but almost not represented in the present collection) is signal processing. Indeed both Gabor analysis and wavelet analysis derive in the first place from CS theory, namely, CS associated to the Weyl–Heisenberg and the ax + b group, respectively. Here too, a tremendous development has taken place in recent years, another testimony to the richness of the notion of CS. We leave it to the jury of public opinion to judge whether the call for a special issue of the journal, devoted to coherent states, has been justified. References [1] Klauder J R and Skagerstam B S 1985 Coherent States—Applications in Physics and Mathematical Physics (Singapore: World Scientific) [2] Zhang W-M, Feng D H and Gilmore R 1990 Coherent states: theory and some applications Rev. Mod. Phys. 62 867–927 [3] Feng D H, Klauder J R and Strayer M (ed) 1994 Coherent States: Past, Present and Future (Singapore: World Scientific) [4] Ali S T, Antoine J-P, Gazeau J-P and Mueller U A 1995 Coherent states and their generalizations: a mathematical overview Rev. Math. Phys. 7 1013–104 [5] Perelomov A M 1986 Generalized Coherent States and Their Applications (New York: Springer) [6] Ali S T, Antoine J-P and Gazeau J-P 2000 Coherent States, Wavelets and Their Generalizations (New York: Springer) [7] Dodonov V V and Man'ko V I (ed) 2003 Theory of Nonclassical States of Light (London: Taylor & Francis) [8] Gazeau J-P 2009 Coherent States in Quantum Physics (Berlin: Wiley) [9] Combescure M and Robert D 2012 Coherent States and Applications in Mathematical Physics (New York: Springer) 1 A second edition of that volume is in preparation.

Journal of Physics A Mathematical and Theoretical•May 30, 2012•9 citations

Introduction to Coherent States

Didier Robert, Monique Combescure

In this Chapter we study the Weyl–Heisenberg group in the Schrödinger representation in arbitrary dimension n. One shows that it operates in the Hilbert space of quantum states (and on quantum operators) as a phase-space translation. Then applying it to a Schwartz class state of arbitrary profile we get a set of generalized coherent states. When we apply the Weyl–Heisenberg translation operator to the ground state of the n-dimensional Harmonic Oscillator, one gets the standard coherent states introduced by Schrödinger [233] (Naturwissenshaften 14:664–666, 1926) in the early days of quantum mechanics (1926). Later the coherent states have been extensively studied by Glauber [118, 119] (Phys. Rev. 131:2766–2788, 1963; Phys. Rev. 130:2529–2539, 1963) for the purpose of quantum optics and it seems that their name comes back to this work. The standard coherent states have been generalized by Perelomov [208] (Generalised Coherent States and Their Applications, 1986) to more general Lie groups than the Weyl–Heisenberg group. We also introduce the usual creation and annihilation operators in dimension n which are very convenient for the study of coherent states. We show that coherent states constitute a non-orthogonal over-complete system which yields a resolution of the identity operator in the Hilbert space and which allows a computation of the Hilbert–Schmidt norm and of the trace of respectively Hilbert–Schmidt class and trace-class operators. We study their time-evolution for the quantum Harmonic Oscillator hamiltonian and show that a time evolved coherent state located around phase-space point z is up to a phase a coherent state located around the phase-space point \(z_t\), where \(z_t\) is the phase-space point of the classical flow governed by the Harmonic Oscillator. This property was described by Schrödinger as the non-spreading of the time evolution of coherent states under the quantum Harmonic Oscillator dynamics. We also show how to go from the Schrödinger to the Fock–Bargmann representation using the standard coherent states.

Theoretical and mathematical physics•Jan 1, 2021•0 citations

Temporally stable coherent states in energy-degenerate systems: The hydrogen atom

M. G. A. Crawford

Klauder's recent generalization of the harmonic oscillator coherent states [J. Phys A 29, L293 (1996)], is applicable only in nondegenerate systems, requiring some additional structure if applied to systems with degeneracies. The author suggests how this structure could be added, and applies the complete method to the hydrogen atom problem. To illustrate how a certain degree of freedom in the construction may be exercised, states are constructed, which are initially localized and evolve semiclassically, and whose long time evolution exhibits ``fractional revivals.''

arXiv:quant-ph/0101092•Physical Review A•Jun 9, 2000•25 citations

The quantum states for Hydrogen atom: spherical harmonics and the orbitals geometrical representation

D. R. Constantin, Liliana Preda, AGNETA A. MOCANU +3 more

Our work utilizes the quantum model of the hydrogen atom which is based on the Schrödinger equation with Coulomb potential. Specifically, we concentrate on the angular components of the wave eigenfunctions derived from this model. We consider the quantum states with n ≤ 4. In order to visualize the orbital shapes of these states, we built in the spherical coordinates system their 3D geometric representations. Furthermore, we use the corresponding spherical harmonics, to calculate the θ nodal values that describe the configurations of these orbital states.

INCAS BULLETIN•Mar 11, 2024•2 citations

The Bargmann representation for the quantum mechanics on a sphere

Kowalski, K L, Rembielinski, J

The Bargmann representation is constructed corresponding to the coherent states for a particle on a sphere introduced in: K. Kowalski and J. Rembielinski, J. Phys. A: Math. Gen. 33, 6035 (2000). The connection is discussed between the introduced formalism and the standard approach based on the Hilbert space of square integrable functions on a sphere S^2.

•Nov 16, 2000•20 citations

Coherent states on spheres

Brian C. Hall, Jeffrey J. Mitchell

We describe a family of coherent states and an associated resolution of the identity for a quantum particle whose classical configuration space is the d-dimensional sphere Sd. The coherent states are labeled by points in the associated phase space T*(Sd). These coherent states are not of Perelomov type but rather are constructed as the eigenvectors of suitably defined annihilation operators. We describe as well the Segal–Bargmann representation for the system, the associated unitary Segal–Bargmann transform, and a natural inversion formula. Although many of these results are in principle special cases of the results of Hall and Stenzel, we give here a substantially different description based on ideas of Thiemann and of Kowalski and Rembieliński. All of these results can be generalized to a system whose configuration space is an arbitrary compact symmetric space. We focus on the sphere case in order to carry out the calculations in a self-contained and explicit way.

arXiv:quant-ph/0109086•Journal of Mathematical Physics•Mar 1, 2002•63 citations
The aim of this chapter is to present a construction of a set of coherent states for the hydrogen atom proposed by Villegas-Blas (The Laplacian on the n-sphere, the hydrogen atom and the Bargmann space representation. Ph.D. thesis, Mathematics Department, University of Virginia, 1996, [251]), Thomas and Villegas-Blas (Commun Math Phys 187:623–645, 1997, [244]). We show that in a semiclassical sense they concentrate essentially around the Kepler orbits (in configuration space) of the classical motion. A suitable unitary transformation (the Fock operator) maps the pure point subspace of the hydrogen atom Hamitonian onto the Hilbert space (L^2({\mathbb S}^3)) for the (\mathbb S^3) sphere. We study the coherent states for the (\mathbb S^3) sphere (as introduced by Uribe (J Funct Anal 59:535–556, 1984, [247]) and show that the action of the group SO(4) is irreducible in the space generated by the spherical harmonics of a given degree. Note that coherent states for the hydrogen atom have been extensively studied by J. Klauder and his school. We have chosen not to present them here and refer the interested reader to Klauder and Skagerstam (Coherent states, Worlds Scientific Publishing, Singapore, 1985, [167]).
Coherent states (CS) of the harmonic oscillator (also called canonical CS) were introduced in 1926 by Schrödinger in answer to a remark by Lorentz on the classical interpretation of the wave function. They were rediscovered in the early 1960s, first (somewhat implicitly) by Klauder in the context of a novel representation of quantum states, then by Glauber and Sudarshan for the description of coherence in lasers. Since then, CS have grown into an extremely rich domain that pervades almost every corner of physics and have also led to the development of several flourishing topics in mathematics. Along the way, a number of review articles have appeared in the literature, devoted to CS, notably the 1985 reprint volume of Klauder and Skagerstam [1], the 1990 review paper by Zhang et al [2], the 1993 Oak Ridge Conference [3] and the 1995 review paper by Ali et al [4]. Textbooks also have been published, among which one might mention the ground breaking text of Perelomov [5] focusing on the group-theoretical aspects, that of Ali et al [6] 1 analyzing systematically the mathematical structure beyond the group-theoretical approach and also the relation to wavelet analysis, that of Dodonov and Man'ko [7] mostly devoted to quantum optics, that of Gazeau [8] more oriented towards the physical, probabilistic and quantization aspects, and finally the very recent one by Combescure and Robert [9]. In retrospect, one can see that the development of CS has gone through a two-phase transition. First, the (simultaneous) discovery in 1972 by Gilmore and Perelomov that CS were rooted in group theory, then the realization that CS can be defined in a purely algebraic way, as an eigenvalue problem or by a series expansion (Malkin and Man'ko 1969, Barut and Girardello 1971, Gazeau and Klauder 1999; references to the original articles may be found in the textbooks quoted above). Both facts resulted in an explosive expansion of the CS literature. We thought, therefore, that the time was ripe to devote a special issue of Journal of Physics A: Mathematical and Theoretical to CS. However, because of limitations of space and time, it would have been impossible to get a fully representative cross-section of papers, covering all the different facets of the subject. Consequently, we have selected 37 articles, including some by a few of the originators of the field. We thank all the authors for submitting their up-to-date thoughts on this fascinating subject. The contents of this special issue are subdivided into five categories: (1) review papers; (2) physics-oriented CS; (3) physics and quantum information; (4) mathematics, general topics; and (5) mathematics, particular problems. (1) Review papers We start with five review papers. The first paper, by Klauder, surveys the many possible applications of affine variables, both in classical and quantum physics. The second, by Sanders, proposes a grand tour of entangled CS, which are present in many fields, such as quantum optics, quantum information processing, etc. The next paper, by Rowe, surveys the field of vector CS and the attendant group representation problems (including induced representations). Then Oriti et al describe a particular class of CS relevant to (loop) quantum gravity. Finally, Combescure and Robert present a comprehensive review of fermionic CS, including all mathematical details. (2) Physics-oriented CS The six contributions in this section deal with specific physical problems: (i) Dajka–Luczka study Gazeau–Klauder cat states associated with a nonlinear Kerr oscillator, instead of the usual canonical CS leading to Schrödinger cat states; (ii) Angelova et al discuss squeezed CS associated with a 1D Morse potential, used in molecular physics; (iii) Bagrov et al study CS in a magnetic solenoid field and prove their completeness; (iv) Blasone–Jizba treat Nambu–Goldstone dynamics in spontaneously broken symmetries, using CS functional integrals; (v) Calixto et al describe accelerated relativistic particles in the context of spontaneous breakdown of conformal SU(2,2) symmetry, using SU(2,2) CS; and (vi) Mortazavi–Tavassoly study f -deformed charge CS and their physical properties (nonclassical features, sub-Poissonian statistical behavior, etc). (3) Physics and quantum information The second group of physically related CS contains four contributions with a distinct quantum information theoretic flavor. First, Thilagam describes the dynamical behavior of entanglement of a pair of qubits (excitons), using a CS basis. Next, Lavoie–de Guise study SU(3) intelligent states (i.e., minimal uncertainty states), of interest in the quantum information community. Then Muñoz constructs discrete CS for n qubits. Finally, Wagner–Kendon explore the continuous variable Deutsch–Jozsa algorithm known in quantum computing in a discrete formulation. (4) Mathematics, general topics In this subgroup, there are eight papers dealing with general properties of CS, independently of any particular system or application. A whole series discusses the interaction between CS and various mathematical objects: pseudodifferential operators and Weyl calculus (Unterberger); induced representations of the affine group and intertwining operators (Elmabrok–Hutnik); measure-free CS and reproducing kernels (Horzela–Szafraniec); extremal POV measures (Heinosaari–Pellonpää); Hilbert W*-modules (Bhattacharyya–Roy); Toeplitz operators (Hutníková–Hutník); and operator localization and homogeneous structure of nilpotent Lie groups (Kisil). In addition, Balazs et al consider multipliers for continuous frames, including CS or wavelet frames. (5) Mathematics, particular problems The second group of mathematically oriented papers contains 14 contributions, devoted to CS in particular systems. We start with a paper by Gilmore, which explores the (sometimes chaotic) evolution of atomic CS under a time-periodic driving field, using sphere maps S 2 → S 2 . Next, we include a paper on CS on the 2-sphere in a magnetic field (Hall–Mitchell); a paper on CS for a quantum particle on a Möbius strip (Cirilo–Lombardo); a discussion of quantization on the circle (Chadzitaskos et al ); SUSY CS for Pöschl–Teller potentials (Bergeron et al ); generalized Bargmann functions and von Neumann lattices (Vourdas et al ); partial reconstruction for a finite CS system, using the Fock–Bargmann representation (Calixto et al ); phase operators for SU(3) irreps, thus for finite quantum systems (de Guise); semiclassical CS in periodic potentials (Carles–Sparber); complexified CS with non-Hermitian Hamiltonians (Graefe–Schubert); minimal uncertainty states in the context of (semisimple) group representation theory (Oszmaniec); localization operators in the time-frequency domain, i.e., in Gabor analysis (Muzhikyan–Avanesyan); and, finally, two papers about fermionic CS (Daoud–Kibler and Trifonov). This brief description illustrates perfectly the extreme versatility of the CS concept. As already stressed, coherent states constitute nowadays a flourishing research topic, with applications to a wide spectrum of domains. Indeed, CS are everywhere in physics: condensed matter physics, atomic physics, nuclear and particle physics, quantum optics, dynamics—both quantum and classical potentials—quantum gravity, quantization and quantum information theory. On the other hand, CS have grown into a fully-fledged domain in mathematics, incorporating many tools such as group representations, POV measures, frames, holomorphic functions, orthogonal polynomials and so on. Interestingly enough, the majority of contributions to this special issue (22 out of 37) are mathematically minded, demonstrating the widespread interest CS have generated in various areas of mathematics. A third field related to CS (but almost not represented in the present collection) is signal processing. Indeed both Gabor analysis and wavelet analysis derive in the first place from CS theory, namely, CS associated to the Weyl–Heisenberg and the ax + b group, respectively. Here too, a tremendous development has taken place in recent years, another testimony to the richness of the notion of CS. We leave it to the jury of public opinion to judge whether the call for a special issue of the journal, devoted to coherent states, has been justified. References [1] Klauder J R and Skagerstam B S 1985 Coherent States—Applications in Physics and Mathematical Physics (Singapore: World Scientific) [2] Zhang W-M, Feng D H and Gilmore R 1990 Coherent states: theory and some applications Rev. Mod. Phys. 62 867–927 [3] Feng D H, Klauder J R and Strayer M (ed) 1994 Coherent States: Past, Present and Future (Singapore: World Scientific) [4] Ali S T, Antoine J-P, Gazeau J-P and Mueller U A 1995 Coherent states and their generalizations: a mathematical overview Rev. Math. Phys. 7 1013–104 [5] Perelomov A M 1986 Generalized Coherent States and Their Applications (New York: Springer) [6] Ali S T, Antoine J-P and Gazeau J-P 2000 Coherent States, Wavelets and Their Generalizations (New York: Springer) [7] Dodonov V V and Man'ko V I (ed) 2003 Theory of Nonclassical States of Light (London: Taylor & Francis) [8] Gazeau J-P 2009 Coherent States in Quantum Physics (Berlin: Wiley) [9] Combescure M and Robert D 2012 Coherent States and Applications in Mathematical Physics (New York: Springer) 1 A second edition of that volume is in preparation.
In this Chapter we study the Weyl–Heisenberg group in the Schrödinger representation in arbitrary dimension n. One shows that it operates in the Hilbert space of quantum states (and on quantum operators) as a phase-space translation. Then applying it to a Schwartz class state of arbitrary profile we get a set of generalized coherent states. When we apply the Weyl–Heisenberg translation operator to the ground state of the n-dimensional Harmonic Oscillator, one gets the standard coherent states introduced by Schrödinger [233] (Naturwissenshaften 14:664–666, 1926) in the early days of quantum mechanics (1926). Later the coherent states have been extensively studied by Glauber [118, 119] (Phys. Rev. 131:2766–2788, 1963; Phys. Rev. 130:2529–2539, 1963) for the purpose of quantum optics and it seems that their name comes back to this work. The standard coherent states have been generalized by Perelomov [208] (Generalised Coherent States and Their Applications, 1986) to more general Lie groups than the Weyl–Heisenberg group. We also introduce the usual creation and annihilation operators in dimension n which are very convenient for the study of coherent states. We show that coherent states constitute a non-orthogonal over-complete system which yields a resolution of the identity operator in the Hilbert space and which allows a computation of the Hilbert–Schmidt norm and of the trace of respectively Hilbert–Schmidt class and trace-class operators. We study their time-evolution for the quantum Harmonic Oscillator hamiltonian and show that a time evolved coherent state located around phase-space point z is up to a phase a coherent state located around the phase-space point ztz_tzt​, where ztz_tzt​ is the phase-space point of the classical flow governed by the Harmonic Oscillator. This property was described by Schrödinger as the non-spreading of the time evolution of coherent states under the quantum Harmonic Oscillator dynamics. We also show how to go from the Schrödinger to the Fock–Bargmann representation using the standard coherent states.
Klauder's recent generalization of the harmonic oscillator coherent states [J. Phys A 29, L293 (1996)], is applicable only in nondegenerate systems, requiring some additional structure if applied to systems with degeneracies. The author suggests how this structure could be added, and applies the complete method to the hydrogen atom problem. To illustrate how a certain degree of freedom in the construction may be exercised, states are constructed, which are initially localized and evolve semiclassically, and whose long time evolution exhibits ``fractional revivals.''
Our work utilizes the quantum model of the hydrogen atom which is based on the Schrödinger equation with Coulomb potential. Specifically, we concentrate on the angular components of the wave eigenfunctions derived from this model. We consider the quantum states with n ≤ 4. In order to visualize the orbital shapes of these states, we built in the spherical coordinates system their 3D geometric representations. Furthermore, we use the corresponding spherical harmonics, to calculate the θ nodal values that describe the configurations of these orbital states.
We describe a family of coherent states and an associated resolution of the identity for a quantum particle whose classical configuration space is the d-dimensional sphere Sd. The coherent states are labeled by points in the associated phase space T*(Sd). These coherent states are not of Perelomov type but rather are constructed as the eigenvectors of suitably defined annihilation operators. We describe as well the Segal–Bargmann representation for the system, the associated unitary Segal–Bargmann transform, and a natural inversion formula. Although many of these results are in principle special cases of the results of Hall and Stenzel, we give here a substantially different description based on ideas of Thiemann and of Kowalski and Rembieliński. All of these results can be generalized to a system whose configuration space is an arbitrary compact symmetric space. We focus on the sphere case in order to carry out the calculations in a self-contained and explicit way.