We consider many-body quantum systems that exhibit quantum chaos, in the sense that the observables of interest act on energy eigenstates like banded random matrices. We study the time-dependent expectation values of these observables, assuming that the system is in a definite (but arbitrary) pure quantum state. We induce a probability distribution for the expectation values by treating the zero of time as a uniformly distributed random variable. We show explicitly that if an observable has a nonequilibrium expectation value at some particular moment, then it is overwhelmingly likely to move towards equilibrium, both forwards and backwards in time. For deviations from equilibrium that are not much larger than a typical quantum or thermal fluctuation, we find that the time dependence of the move towards equilibrium is given by the Kubo correlation function, in agreement with Onsager’s postulate. These results are independent of the details of the system’s quantum state.We consider many-body quantum systems that exhibit quantum chaos, in the sense that the observables of interest act on energy eigenstates like banded random matrices. We study the time-dependent expectation values of these observables, assuming that the system is in a definite (but arbitrary) pure quantum state. We induce a probability distribution for the expectation values by treating the zero of time as a uniformly distributed random variable. We show explicitly that if an observable has a nonequilibrium expectation value at some particular moment, then it is overwhelmingly likely to move towards equilibrium, both forwards and backwards in time. For deviations from equilibrium that are not much larger than a typical quantum or thermal fluctuation, we find that the time dependence of the move towards equilibrium is given by the Kubo correlation function, in agreement with Onsager’s postulate. These results are independent of the details of the system’s quantum state.

Jan 1, 1998231 citations

Thermal fluctuations in quantized chaotic systems

Mark Srednicki

We consider a quantum system with N degrees of freedom which is classically chaotic. When N is large, and both and the quantum energy uncertainty are small, quantum chaos theory can be used to demonstrate the following results: (i) given a generic observable A, the infinite time average of the quantum expectation value is independent of all aspects of the initial state other than the total energy, and equal to an appropriate thermal average of A; (ii) the time variations of are too small to represent thermal fluctuations; (iii) however, the time variations of can be consistently interpreted as thermal fluctuations, even though these same time variations would be called quantum fluctuations when N is small.We consider a quantum system with N degrees of freedom which is classically chaotic. When N is large, and both and the quantum energy uncertainty are small, quantum chaos theory can be used to demonstrate the following results: (i) given a generic observable A, the infinite time average of the quantum expectation value is independent of all aspects of the initial state other than the total energy, and equal to an appropriate thermal average of A; (ii) the time variations of are too small to represent thermal fluctuations; (iii) however, the time variations of can be consistently interpreted as thermal fluctuations, even though these same time variations would be called quantum fluctuations when N is small.

arXiv:chao-dyn/9511001Journal of Physics A Mathematical and GeneralFeb 21, 1996220 citations

Thermal fluctuations in quantized chaotic systems

Mark Srednicki

We consider a quantum system with N degrees of freedom which is classically chaotic. When N is large, and both ¯h and the quantum energy uncertainty ∆E are small, quantum chaos theory can be used to demonstrate the following results: (1) given a generic observable A, the infinite time average A of the quantum expectation value 〈A(t) 〉 is independent of all aspects of the initial state other than the total energy, and equal to an appropriate thermal average of A; (2) the time variations of 〈A(t)〉−A are too small to represent thermal fluctuations; (3) however, the time variations of 〈A 2 (t) 〉 − 〈A(t) 〉 2 can be consistently interpreted as thermal fluctuations, even though these same time variations would be called quantum fluctuations when N is small. Typeset using REVTEXWe consider a quantum system with N degrees of freedom which is classically chaotic. When N is large, and both ¯h and the quantum energy uncertainty ∆E are small, quantum chaos theory can be used to demonstrate the following results: (1) given a generic observable A, the infinite time average A of the quantum expectation value 〈A(t) 〉 is independent of all aspects of the initial state other than the total energy, and equal to an appropriate thermal average of A; (2) the time variations of 〈A(t)〉−A are too small to represent thermal fluctuations; (3) however, the time variations of 〈A 2 (t) 〉 − 〈A(t) 〉 2 can be consistently interpreted as thermal fluctuations, even though these same time variations would be called quantum fluctuations when N is small. Typeset using REVTEX

Jan 1, 199692 citations

Chaos and quantum thermalization

Mark Srednicki

We show that a bounded, isolated quantum system of many particles in a specific initial state will approach thermal equilibrium if the energy eigenfunctions which are superposed to form that state obey Berry's conjecture. Berry's conjecture is expected to hold only if the corresponding classical system is chaotic, and essentially states that the energy eigenfunctions behave as if they were Gaussian random variables. We review the existing evidence, and show that previously neglected effects substantially strengthen the case for Berry's conjecture. We study a rarefied hard-sphere gas as an explicit example of a many-body system which is known to be classically chaotic, and show that an energy eigenstate which obeys Berry's conjecture predicts a Maxwell-Boltzmann, Bose-Einstein, or Fermi-Dirac distribution for the momentum of each constituent particle, depending on whether the wave functions are taken to be nonsymmetric, completely symmetric, or completely antisymmetric functions of the positions of the particles. We call this phenomenon eigenstate thermalization. We show that a generic initial state will approach thermal equilibrium at least as fast as O(\ensuremath{\Elzxh}/\ensuremath{\Delta})${\mathit{t}}^{\mathrm{\ensuremath{-}}1}$, where \ensuremath{\Delta} is the uncertainty in the total energy of the gas. This result holds for an individual initial state; in contrast to the classical theory, no averaging over an ensemble of initial states is needed. We argue that these results constitute a sound foundation for quantum statistical mechanics.We show that a bounded, isolated quantum system of many particles in a specific initial state will approach thermal equilibrium if the energy eigenfunctions which are superposed to form that state obey Berry's conjecture. Berry's conjecture is expected to hold only if the corresponding classical system is chaotic, and essentially states that the energy eigenfunctions behave as if they were Gaussian random variables. We review the existing evidence, and show that previously neglected effects substantially strengthen the case for Berry's conjecture. We study a rarefied hard-sphere gas as an explicit example of a many-body system which is known to be classically chaotic, and show that an energy eigenstate which obeys Berry's conjecture predicts a Maxwell-Boltzmann, Bose-Einstein, or Fermi-Dirac distribution for the momentum of each constituent particle, depending on whether the wave functions are taken to be nonsymmetric, completely symmetric, or completely antisymmetric functions of the positions of the particles. We call this phenomenon eigenstate thermalization. We show that a generic initial state will approach thermal equilibrium at least as fast as O(\ensuremath{\Elzxh}/\ensuremath{\Delta})${\mathit{t}}^{\mathrm{\ensuremath{-}}1}$, where \ensuremath{\Delta} is the uncertainty in the total energy of the gas. This result holds for an individual initial state; in contrast to the classical theory, no averaging over an ensemble of initial states is needed. We argue that these results constitute a sound foundation for quantum statistical mechanics.

arXiv:cond-mat/9403051Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topicsAug 1, 19943,166 citations

Does Quantum Chaos Explain Quantum Statistical Mechanics?

Mark Srednicki

If a many-body quantum system approaches thermal equilibrium from a generic initial state, then the expectation value $\langleψ(t)|A_i|ψ(t)\rangle$ , where $|ψ(t)\rangle$ is the system's state vector and $A_i$ is an experimentally accessible observable, should approach a constant value which is independent of the initial state, and equal to a thermal average of $A_i$ at an appropriate temperature. We show that this is the case for all simple observables whenever the system is classically chaotic.If a many-body quantum system approaches thermal equilibrium from a generic initial state, then the expectation value $\langleψ(t)|A_i|ψ(t)\rangle$, where $|ψ(t)\rangle$ is the system's state vector and $A_i$ is an experimentally accessible observable, should approach a constant value which is independent of the initial state, and equal to a thermal average of $A_i$ at an appropriate temperature. We show that this is the case for all simple observables whenever the system is classically chaotic.

arXiv:cond-mat/9410046Oct 14, 19945 citations

Method to discriminate between localized and chaotic quantum systems

Youssef Aziz Alaoui, B. Laburthe-Tolra

We study whether a generic isolated quantum system initially set out of equilibrium can be considered as localized close to its initial state. Our approach considers the time evolution in the Krylov basis, which maps the system's dynamics onto that of a particle moving in a one-dimensional lattice where both the energy in the lattice sites and the tunneling from one lattice site to the next are inhomogeneous. By tying the dynamical propagation in the Krylov basis to that in the basis of microstates, we infer qualitative criteria that allow distinguishing systems that remain localized close to their initial state from systems that undergo quantum thermalization. These criteria are system-dependent and involve the expectation values and standard deviations of both the coupling strengths between Krylov states and their energy. We verify their validity by inspecting two cases: Anderson localization as a function of dimension and the out-of-equilibrium dynamics of a many-body dipolar spin system. We finally investigate the Wigner surmise and the eigenstate thermalization hypothesis that have both been proposed to characterize quantum chaotic systems. We show that when the average value of the nondiagonal terms in the Lanczos matrix is large compared to their fluctuations and to the fluctuations of the energy expectation values, which typically corresponds to delocalized quantum systems according to our criteria, there can be level repulsion of eigenenergies (also known as spectral rigidity), similar to that of the Wigner-Dyson statistics of energy levels; and we also demonstrate that in the same regime, the expectation values of typical local observables only weakly vary as a function of eigenstates, an important condition for the eigenstate thermalization hypothesis. Our demonstration assumes that, in the chaotic regime, the observable is sufficiently diagonal in the basis of Krylov states. Published by the American Physical Society 2024We study whether a generic isolated quantum system initially set out of equilibrium can be considered as localized close to its initial state. Our approach considers the time evolution in the Krylov basis, which maps the system's dynamics onto that of a particle moving in a one-dimensional lattice where both the energy in the lattice sites and the tunneling from one lattice site to the next are inhomogeneous. By tying the dynamical propagation in the Krylov basis to that in the basis of microstates, we infer qualitative criteria that allow distinguishing systems that remain localized close to their initial state from systems that undergo quantum thermalization. These criteria are system-dependent and involve the expectation values and standard deviations of both the coupling strengths between Krylov states and their energy. We verify their validity by inspecting two cases: Anderson localization as a function of dimension and the out-of-equilibrium dynamics of a many-body dipolar spin system. We finally investigate the Wigner surmise and the eigenstate thermalization hypothesis that have both been proposed to characterize quantum chaotic systems. We show that when the average value of the nondiagonal terms in the Lanczos matrix is large compared to their fluctuations and to the fluctuations of the energy expectation values, which typically corresponds to delocalized quantum systems according to our criteria, there can be level repulsion of eigenenergies (also known as spectral rigidity), similar to that of the Wigner-Dyson statistics of energy levels; and we also demonstrate that in the same regime, the expectation values of typical local observables only weakly vary as a function of eigenstates, an important condition for the eigenstate thermalization hypothesis. Our demonstration assumes that, in the chaotic regime, the observable is sufficiently diagonal in the basis of Krylov states. Published by the American Physical Society 2024

arXiv:2307.10706Physical Review ResearchOct 17, 20243 citations

If a many-body quantum system approaches thermal equilibrium from a generic initial state, then the expectation value

\langleψ(t)|A_i|ψ(t)\rangle

, where

|ψ(t)\rangle

is the system's state vector and

A_i

is an experimentally accessible observable, should approach a constant value which is independent of the initial state, and equal to a thermal average of

A_i

at an appropriate temperature. We show that this is the case for all simple observables whenever the system is classically chaotic.