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arXiv:cond-mat/9403051 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Chaos and quantum thermalization

Mark Srednicki

Published Aug 1, 1994• 3,166 citations
arXivHTMLPDF

Abstract

We show that a bounded, isolated quantum system of many particles in a specific initial state will approach thermal equilibrium if the energy eigenfunctions which are superposed to form that state obey Berry's conjecture. Berry's conjecture is expected to hold only if the corresponding classical system is chaotic, and essentially states that the energy eigenfunctions behave as if they were Gaussian random variables. We review the existing evidence, and show that previously neglected effects substantially strengthen the case for Berry's conjecture. We study a rarefied hard-sphere gas as an explicit example of a many-body system which is known to be classically chaotic, and show that an energy eigenstate which obeys Berry's conjecture predicts a Maxwell-Boltzmann, Bose-Einstein, or Fermi-Dirac distribution for the momentum of each constituent particle, depending on whether the wave functions are taken to be nonsymmetric, completely symmetric, or completely antisymmetric functions of the positions of the particles. We call this phenomenon eigenstate thermalization. We show that a generic initial state will approach thermal equilibrium at least as fast as O(\ensuremath{\Elzxh}/\ensuremath{\Delta})${\mathit{t}}^{\mathrm{\ensuremath{-}}1}$, where \ensuremath{\Delta} is the uncertainty in the total energy of the gas. This result holds for an individual initial state; in contrast to the classical theory, no averaging over an ensemble of initial states is needed. We argue that these results constitute a sound foundation for quantum statistical mechanics.

DOI
10.1103/physreve.50.888

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We show that a bounded, isolated quantum system of many particles in a specific initial state will approach thermal equilibrium if the energy eigenfunctions which are superposed to form that state obey Berry's conjecture. Berry's conjecture is expected to hold only if the corresponding classical system is chaotic, and essentially states that the energy eigenfunctions behave as if they were Gaussian random variables. We review the existing evidence, and show that previously neglected effects substantially strengthen the case for Berry's conjecture. We study a rarefied hard-sphere gas as an explicit example of a many-body system which is known to be classically chaotic, and show that an energy eigenstate which obeys Berry's conjecture predicts a Maxwell-Boltzmann, Bose-Einstein, or Fermi-Dirac distribution for the momentum of each constituent particle, depending on whether the wave functions are taken to be nonsymmetric, completely symmetric, or completely antisymmetric functions of the positions of the particles. We call this phenomenon eigenstate thermalization. We show that a generic initial state will approach thermal equilibrium at least as fast as O(\ensuremath{\Elzxh}/\ensuremath{\Delta})t\ensuremath−1{\mathit{t}}^{\mathrm{\ensuremath{-}}1}t\ensuremath−1, where \ensuremath{\Delta} is the uncertainty in the total energy of the gas. This result holds for an individual initial state; in contrast to the classical theory, no averaging over an ensemble of initial states is needed. We argue that these results constitute a sound foundation for quantum statistical mechanics.
A profound quest of statistical mechanics is the origin of irreversibility - the arrow of time. New stimulants have been provided, thanks to unprecedented degree of control reached in experiments with isolated quantum systems and rapid theoretical developments of manybody localization in disordered interacting systems. The proposal of (many-body) eigenstate thermalization (ET) for these systems reinforces the common belief that either interaction or extrinsic randomness is required for thermalization. Here, we unveil a quantum thermalization mechanism challenging this belief. We find that, provided one-body quantum chaos is present, as a pure many-body state evolves the arrow of time can emerge, even without interaction or randomness. In times much larger than the Ehrenfest time that signals the breakdown of quantum-classical correspondence, quantum chaotic motion leads to thermal [Fermi-Dirac (FD) or Bose-Einstein (BE)] distributions and thermodynamics in individual eigenstates. Our findings lay dynamical foundation of statistical mechanics and thermodynamics of isolated quantum systems.
The eigenstate thermalization hypothesis (ETH), which asserts that every eigenstate of a many-body quantum system is indistinguishable from a thermal ensemble, plays a pivotal role in understanding thermalization of isolated quantum systems. Yet, no evidence has been obtained as to whether the ETH holds for all few-body operators in a chaotic system; such few-body operators include key quantities in statistical mechanics, such as the total magnetization, the momentum distributions, and their low-order thermal and quantum fluctuations. Here, we formulate a conjecture that for a generic nonintegrable system the ETH holds simultaneously for all mmm-body operators with m<α∗Nm < α_{\ast} Nm<α∗​N in the thermodynamic limit for some nonzero constant α∗>0α_{\ast} > 0α∗​>0. We first show the existence of such nontrivial constants for idealized (pseudo) random-matrix descriptions of many-body eigenstates. We then verify the conjecture for generic spin, Bose, and Fermi systems with local and few-body interactions by large-scale numerical calculations. Our results imply that generic systems satisfy the ETH simultaneously for all few-body operators, including their thermal and quantum fluctuations.
This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, the fluctuation–dissipation relation, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. In some cases, it is possible to extend their regimes of applicability beyond the standard thermal equilibrium domain. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We present results from numerical experiments and analytical studies of quantum quenches at integrability. We introduce the concept of the generalized Gibbs ensemble and discuss its connection with ideas of prethermalization in weakly interacting systems.
Abstract We investigate thermalization of a closed chaotic many-body quantum system by combining the Hartree–Fock approach with the Bohigas–Giannoni–Schmit conjecture. The conjecture implies that locally, the residual interaction causes the statistics of eigenvalues and eigenfunctions of the full Hamiltonian to agree with random-matrix predictions. The agreement is confined to an interval Δ (the correlation width). The results are used to calculate Tr ( A ρ ( t ) ) . Here ρ ( t ) is the time-dependent density matrix of the system, and A represents an observable. In the semiclassical regime, the average ⟨ Tr ( A ρ ( t ) ) ⟩ decays on the time scale ℏ / Δ toward an asymptotic value. If the energy spread of the system is of order Δ, that value is given by Tr ( A ρ eq ) where ρ eq is the density matrix of statistical equilibrium. The correlation width Δ is the central parameter of our approach. We argue that Δ occurs generically in chaotic quantum systems and plays the same central role.
The emergence of statistical mechanics for isolated classical systems comes about through chaotic dynamics and ergodicity. Here we review how similar questions can be answered in quantum systems. The crucial point is that individual energy eigenstates behave in many ways like a statistical ensemble. A more detailed statement of this is named the eigenstate thermalization hypothesis (ETH). The reasons for why it works in so many cases are rooted in the early work of Wigner on random matrix theory and our understanding of quantum chaos. The ETH has now been studied extensively by both analytic and numerical means, and applied to a number of physical situations ranging from black hole physics to condensed matter systems. It has recently become the focus of a number of experiments in highly isolated systems. Current theoretical work also focuses on where the ETH breaks down leading to new interesting phenomena. This review of the ETH takes a somewhat intuitive approach as to why it works and how this informs our understanding of many body quantum states.
Using the ergodicity principle for the expectation values of several types of observables, we investigate the thermalization process in isolated fermionic systems.These are described by the two-body random ensemble, which is a paradigmatic model to study quantum chaos and especially the dynamical transition from integrability to chaos.By means of exact diagonalizations we analyze the relevance of the eigenstate thermalization hypothesis as well as the influence of other factors, such as the energy and structure of the initial state, or the dimension of the Hilbert space.We also obtain analytical expressions linking the degree of thermalization for a given observable with the so-called number of principal components for transition strengths originating at a given energy, with the dimensions of the whole Hilbert space and microcanonical energy shell, and with the correlations generated by the observable.As the strength of the residual interaction is increased, an order-to-chaos transition takes place, and we show that the onset of Wigner spectral fluctuations, which is the standard signature of chaos, is not sufficient to guarantee thermalization in finite systems.When all the signatures of chaos are fulfilled, including the quasicomplete delocalization of eigenfunctions, the eigenstate thermalization hypothesis is the mechanism responsible for the thermalization of certain types of observables, such as (linear combinations of) occupancies and strength function operators.Our results also suggest that fully chaotic systems will thermalize relative to most observables in the thermodynamic limit.