Since the early days of quantum mechanics, tunneling has been recognized as one of the hallmarks of the wave character of microscopic physics. The possibility of a quantum particle to penetrate an energetic barrier represents certainly one of the most spectacular implications of quantum theory and has led to various applications in nuclear, atomic, and molecular physics as well as in mesoscopic science. Typical scenarios in which tunneling manifests are the escape route of a quantum particle from a quasibounded region, the transition between two or more symmetry-related, but classically disconnected wells (which we shall focus on in the following), as well as scattering or transport through potential barriers. The spectrum of scenarios becomes even richer when the concept of tunneling is generalized to any kind of classically forbidden transitions in phase space, that is, to transitions that are not necessarily inhibited by static potential barriers but by some other constraints of the underlying classical dynamics (such as integrals of motion). Such “dynamical tunneling” processes arise frequently in molecular systems [1] and were realized with cold atoms propagating in periodically modulated optical lattices [2-4]. Moreover, the electromagnetic analog of dynamical tunneling was also obtained with microwaves in billiards [5].
Since the early days of quantum mechanics, tunneling has been recognized as one of the hallmarks of the wave character of microscopic physics. The possibility of a quantum particle to penetrate an energetic barrier represents certainly one of the most spectacular implications of quantum theory and has led to various applications in nuclear, atomic, and molecular physics as well as in mesoscopic science. Typical scenarios in which tunneling manifests are the escape route of a quantum particle from a quasibounded region, the transition between two or more symmetry-related, but classically disconnected wells (which we shall focus on in the following), as well as scattering or transport through potential barriers. The spectrum of scenarios becomes even richer when the concept of tunneling is generalized to any kind of classically forbidden transitions in phase space, that is, to transitions that are not necessarily inhibited by static potential barriers but by some other constraints of the underlying classical dynamics (such as integrals of motion). Such “dynamical tunneling” processes arise frequently in molecular systems [1] and were realized with cold atoms propagating in periodically modulated optical lattices [2-4]. Moreover, the electromagnetic analog of dynamical tunneling was also obtained with microwaves in billiards [5].
In generic Hamiltonian systems that are neither completely integrable nor fully chaotic, phase space consists of a mixture of regular and chaotic components. In classical dynamics, transitions between different invariant sets in phase space are strictly forbidden, and these sets act as dynamical barriers to one another. In quantum mechanics, in contrast, wave effects allow transitions through such dynamical barriers. This process, known as dynamical tunneling, refers to penetration through dynamical barriers in phase space and was first recognized in the early 1980s. Since then, various aspects of dynamical tunneling have been elucidated, significantly advancing our understanding of such a novel quantum phenomenon. In this article, we provide an overview of several phenomenological perspectives of dynamical tunneling, including chaos-assisted and resonance-assisted tunneling, and also introduce approaches based on classical mechanics extended into the complex domain. In particular, we seek to clarify what is meant by the common claim that "chaos leads to an enhancement of the tunneling probability", which is often made when dynamical tunneling is dressed. We discuss what regime this refers to and, if such an enhancement occurs, what its likely origin is.
The study of quantum tunneling dates back to the early days of quantum mechanics, and has been a major topic of investigation in both theory and experiment. In recent years, there has been significant effort to understand tunneling phenomena for systems that exhibit chaos in their classical counterpart [13,15,18,29,42]. In particular, tunneling was predicted for mixed systems where chaotic and stable regions are intermingled [14]. The tunneling in this case is between two stable regions (referred to as nonlinear resonances, or islands of stability) in the classical phase space. The classical transport between these islands is forbidden by “dynamical barriers” in phase space. In contrast, quantum tunneling can couple the two islands so that a wave packet oscillates coherently between the two symmetry-related regions. This phenomenon is called dynamical tunneling because it occurs in phase space, without a fixed potential barrier. In the case of a mixed phase space, the presence of the chaotic region can enhance the rate of dynamical tunneling, a phenomenon known as chaos-assisted tunneling [53]. In this chapter, we review our experimental observation of chaosassisted tunneling with ultracold cesium atoms [48-51]. We first give a brief overview of some basic concepts and of earlier work in order to provide a context for our results.
In the usual quantum tunneling, a low-energy quantum particle penetrates across a physical barrier of higher potential energy, by traversing a classically forbidden region, and finally escapes into another region. In an analogous scenario, a classical particle inside a closed regular region in the phase space is dynamically bound from escaping to other regions of the phase space. Here, the physical potential barrier is replaced by dynamical barriers which separate different regions of the phase space. However, in the quantum regime, the system can overcome such dynamical barriers and escape through them, giving rise to dynamical tunneling. In chaotic Hamiltonian systems, dynamical tunneling refers to quantum tunneling between states whose classical limits correspond to symmetry-related regular regions separated by a chaotic zone between which any classical transport is prohibited. Here, an experimental realization of dynamical tunneling in spin systems is reported using nuclear magnetic resonance (NMR) architecture. In particular, dynamical tunneling in quantum kicked tops of spin-1 and spin-3/2 systems using two- and three-qubit NMR registers is investigated. By extracting time-dependent expectation values of the angular momentum operator components, size-dependent tunneling behavior for various initial states is systematically investigated. Further, by monitoring the adverse effects of dephasing noise on the tunneling oscillations, we assert the importance of quantum coherence in enabling dynamical tunneling.
Tunneling as a quantum mechanical effect takes place in a classically forbidden region between two regions of classically allowed motion. While the term “dynamical tunneling” typically refers to tunneling of quantum states across dynamical barriers in classical phase space [1], the original problem simply intended tunneling across a potential barrier. Both types of tunneling are addressed in this chapter, with major focus on situations in which external forces make the studied systems intrinsically time-dependent and allow for a dynamical control of tunneling through potential barriers or across band gaps which are dynamically explored by the system.
Tunneling is a supreme quantum effect. Every introductory text [1] on quantum mechanics gives the paradigm example of a particle tunneling through a one-dimensional potential barrier despite having a total energy less than the barrier height. Indeed, the reader typically works through a number of exercises, all involving one-dimensional potential barriers of one form or another modeling several key physical phenomena ranging from atom transfer reactions to the decay of α-particles [2]. However, one seldom encounters coupled multidimenisonal tunneling in such texts since an analytical solution of the Schro¨dinger equation in such cases is not possible. Interestingly, the richness and complexity of the tunneling phenomenon manifest themselves in full glory in the case of multidimensional systems [3]. Thus, for instance, the usual one-dimensional expectation of increasing tunneling splittings as one approaches the barrier top from below is not necessarily true as soon as one couples another bound degree of freedom to the tunneling coordinate. In the context of molecular reaction dynamics, multidimensional tunneling can result in strong mode-specificity and fluctuations in the reaction rates [4]. In fact, a proper description of tunneling of electrons and hydrogen atoms is absolutely essential [5,6] even in molecular systems as large as enzymes and proteins. Although one usually assumes tunneling effects to be significant in molecules involving light atom transfers, it is worth pointing out that neglecting the tunneling of even a heavy atom like carbon is the difference between a reaction occurring or not occurring. In particular, one can underestimate rates by nearly hundred orders of magnitude [7]. Interestingly, and perhaps paradoxically, several penetrating insights into the nature and mechanism of multidimensional barrier tunneling have been obtained from a phase-space perspective [8,9]. The contributions by Creagh, Shudo and Ikeda, and Takahashi in the present volume provide a detailed account of the latest advances in the phasespace-based understanding of multidimensional barrier tunneling.
Scanning tunneling microscopy is introduced as an analytic tool for characterizing nanostructures and dynamics on the nanoscale. To analyze the underlying tunneling phenomenon, the Schrödinger equation is solved for a particle confined between finite potential energy steps. For a single potential energy well, the proper solutions to the Schrödinger equation are similar to those of a particle in an infinite box, except for the emerging “tails” of the stationary wave functions in the “classically forbidden” regions of the external confining potentials. For a symmetric double well potential, wave function penetration of the stationary solutions manifests in their even distribution among the wells. An attempt to localize the particle in one of them would lead to periodic oscillations between the wells, as if the particle can “tunnel” under the separating energy barrier. The wave function penetration and tunneling phenomena are discussed also in relation to energy band formation in periodic lattices.