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Cambridge University Press eBooks

Phase Transitions

Aron J. Beekman, Louk Rademaker, Jasper van Wezel

Published Sep 3, 2026• 0 citations
Publisher

Abstract

This chapter focuses on phase transitions, either with or without a change in symmetry. The generic Ginzburg–Landau description of phase transitions in terms of an emergent energy functional for the order parameter is introduced, and the role of spatial variations and spatial fluctuations is highlighted. The universality of this description and its applicability across domains of physics is emphasised.

DOI
10.1017/9781009575782.008

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Cambridge University Press eBooks•Mar 6, 2014•1 citation
This chapter focuses on phase transitions, either with or without a change in symmetry. The generic Ginzburg–Landau description of phase transitions in terms of an emergent energy functional for the order parameter is introduced, and the role of spatial variations and spatial fluctuations is highlighted. The universality of this description and its applicability across domains of physics is emphasised.
In the previous chapter, we developed the Landau theory of phase transitions, emphasizing how macroscopic order parameters and symmetry considerations determine the general form of the free energy near criticality. There, spatial variations of the order parameter were neglected, corresponding to the mean-field approximation . However, as we have seen, close to the critical temperature T c the correlation length ξ diverges, and fluctuations occur over arbitrarily large scales. In this regime, the assumption of spatial uniformity breaks down, and a local field description becomes necessary.
The Landau Paradigm The usual paradigm to describe phase transitions is that of Landau. It is based on an expansion of a free energy functional or an action in terms of an order parameter. Close to the phase transition the order parameter is small, and only terms dictated by symmetry are allowed in this expansion. Associated with this paradigm are many important ideas, such as that of broken symmetry and Goldstone modes. The extension of this paradigm to include quantum phase transitions certainly brought new ideas and progress, as we have seen in this book: the inextricability between the dynamics and static properties, the modified hyperscaling relation with the notion of an effective dimensionality, the role of the uncertainty principle linking energy and temporal fluctuations and so on. The underlying principle here is always that of symmetry. However, as we will see in this chapter, this paradigm is not sufficient to describe certain classes of phenomena that do not involve symmetry changes but are nonetheless still associated with diverging lengths, singularities and critical exponents: features that are clearly related to critical phenomena and phase transitions. We have already met similar behaviour when studying density-driven or Lifshitz transitions. We will see in this chapter that these transitions are much more common and interesting that initially thought. The keyword here is topology, which contains principles and constraints that protect quasi-particle excitations and are still more powerful than those of symmetry. Topological Quantum Phase Transitions We will refer to topological quantum phase transitions (TQPT) as those that separate two phases where at least one of them is topologically non-trivial, as characterised by some topological parameter like a winding number or a Berry phase. In some cases these transitions either give rise to singularities in a thermodynamic quantity or are accompanied by a diverging length. However, differently from Landau-type phase transitions they are not necessarily associated with a symmetry change. Also there is no identifiable order parameter to distinguish between the different phases. Topological quantities are not useful to play the role of an order parameter. They are in general discontinuous at topological transitions and this does not necessarily reflect the nature of the transition. On the other hand, we will show that the renormalisation group is a useful tool to describe TQPT.
Abstract Interacting many-particle systems may undergo phase transitions and exhibit critical phenomena in the limit of infinite system size, while the precursors of these phenomena are studied in the theory of finite-size scaling. After surveying the basic notions of phases, phase diagrams, and phase transitions, this chapter focuses on critical behaviour at a second-order phase transition. The Landau-Ginzburg theory and the concept of scaling prepare readers for an elementary introduction to the concepts of the renormalization group, followed by an introduction into the field of quantum phase transitions where quantum fluctuations take over the role of thermal fluctuations.
In this chapter, the author shows the theory of phase transition using some systems of interacting spins. Note that various systems of different nature can be mapped into spin systems and solved using the spin language. However, the mean-field theory gives some artifacts at low dimensions and cannot determine with precision the critical exponents which characterize the nature of a phase transition. A transition from one phase to another may take place when an external parameter varies. Such a parameter can be the temperature or an external applied magnetic field. Renormalization group analysis shows that the universality class depends only on a few very general parameters such as the space dimension, the symmetry of the order parameter and the nature of the interaction. The Landau–Ginzburg theory is an extension of the mean-field theory which includes a great part of fluctuations so far neglected near the transition.
Recently, a generalized Landau paradigm has been proposed, in which a broad class of "unconventional" phase transitions lying beyond the original symmetry-breaking framework of Landau are understood as the symmetry-breaking transitions of generalized symmetries. In particular, in (1+1)D, such "topological" or "deconfined" transitions can be mapped to the symmetry-breaking transitions of non-invertible symmetries. How to extract the universal dynamical properties of the transitions from this understanding? In this paper, we follow the Ginzburg-Landau philosophy and develop a field-theoretic description of such critical points in terms of the fluctuations of local order parameters, now of non-invertible symmetries. The Symmetry Topological Field Theory formalism plays a central role in our analysis, allowing us to identify the algebra of local order parameters from the Lagrangian algebra of a (2+1)D topological order. We illustrate the key ideas and the full steps of this generalized Ginzburg-Landau procedure using the transitions between gapped phases with a simple non-invertible symmetry --- the Rep(S3S_3S3​) symmetry.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.