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Phase Transitions, Critical Phenomena, and Finite-Size Scaling

Hans-Peter Eckle

Published Jul 25, 2019• 0 citations
Publisher

Abstract

Abstract Interacting many-particle systems may undergo phase transitions and exhibit critical phenomena in the limit of infinite system size, while the precursors of these phenomena are studied in the theory of finite-size scaling. After surveying the basic notions of phases, phase diagrams, and phase transitions, this chapter focuses on critical behaviour at a second-order phase transition. The Landau-Ginzburg theory and the concept of scaling prepare readers for an elementary introduction to the concepts of the renormalization group, followed by an introduction into the field of quantum phase transitions where quantum fluctuations take over the role of thermal fluctuations.

DOI
10.1093/oso/9780199678839.003.0005

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Abstract Interacting many-particle systems may undergo phase transitions and exhibit critical phenomena in the limit of infinite system size, while the precursors of these phenomena are studied in the theory of finite-size scaling. After surveying the basic notions of phases, phase diagrams, and phase transitions, this chapter focuses on critical behaviour at a second-order phase transition. The Landau-Ginzburg theory and the concept of scaling prepare readers for an elementary introduction to the concepts of the renormalization group, followed by an introduction into the field of quantum phase transitions where quantum fluctuations take over the role of thermal fluctuations.
The chapter is an introduction to basic equilibrium aspects of phase transitions. It starts by reviewing thermodynamics and the thermodynamic description of phase transitions. Next, lattice models, such as the paradigmatic Ising model, are introduced as simple physical models that permit a mechano-statistical study of phase transitions from a more microscopic point of view. It is shown that the Ising model can quite faithfully describe many different systems after suitable interpretation of the lattice variables. Special emphasis is placed on the mean-field concept and the mean-field approximations. The deformable Ising model is then studied as an example that illustrates the interplay of different degrees of freedom. Subsequently, the Landau theory of phase transitions is introduced for continuous and first-order transitions, as well as critical and tricritical behaviour are analysed. Finally, scaling theories and the notion of universality within the framework of the renormalization group are briefly discussed.
In this chapter, the author shows the theory of phase transition using some systems of interacting spins. Note that various systems of different nature can be mapped into spin systems and solved using the spin language. However, the mean-field theory gives some artifacts at low dimensions and cannot determine with precision the critical exponents which characterize the nature of a phase transition. A transition from one phase to another may take place when an external parameter varies. Such a parameter can be the temperature or an external applied magnetic field. Renormalization group analysis shows that the universality class depends only on a few very general parameters such as the space dimension, the symmetry of the order parameter and the nature of the interaction. The Landau–Ginzburg theory is an extension of the mean-field theory which includes a great part of fluctuations so far neglected near the transition.
Quantum Phase Transitions Quantum phase transitions, in contrast to temperature-driven critical phenomena, occur due to a competition between different parameters describing the basic interactions of the system. Their specific feature is the quantum character of the critical fluctuations. This implies, through the uncertainty principle, that energy fluctuations and time are coupled. Then at zero temperature time plays a crucial and fundamental role, the static properties being entangled with the dynamics (Continentino, 1994a; Sondhi et al ., 1997; Sachdev, 1999). In this book we are mainly interested in quantum phase transitions that occur in electronic many-body systems and how scaling concepts can be useful to understand their properties close to these transitions (Continentino, 1994a). Even though a similar approach has been used in the case of interacting bosons (Fisher et al ., 1989) the fermionic problem has its own idiosyncrasies and difficulties. For example, there is no natural order parameter associated with the localisation transition in the electronic case, while bosons at zero temperature are either localised or superfluid so that the superfluid order parameter can be used to distinguish between both phases. If the results of the study of quantum phase transitions were restricted to zero temperature, this would be an interesting but purely academic area of research. What is really exciting about this subject is the effect of quantum critical points (QCP) in the finite temperature phase diagram of actual physical systems, even far away from the QCP (Freitas, 2015). As we will show, there is a special line in this phase diagram, the quantum critical trajectory , where the temperature dependence of the thermodynamic and transport properties is governed by the quantum critical exponents, i.e. those associated with the QCP. This and the observed crossover effects induced by temperature in the non-critical side of the phase diagram of a material with a QCP are sufficient to make the study of quantum phase transitions an inevitable subject. We start this chapter by introducing the scaling theory of quantum critical phenomena, since scaling concepts are used throughout this book.
These lecture notes provide an overview of the renormalization group (RG) as a successful framework to understand critical phenomena above the upper critical dimension ducd_{\rm uc}duc​. After an introduction to the scaling picture of continuous phase transitions, we discuss the apparent failure of the Gaussian fixed point to capture scaling for Landau mean-field theory, which should hold in the thermodynamic limit above ducd_{\rm uc}duc​. We recount how Fisher's dangerous-irrelevant-variable formalism applied to thermodynamic functions partially repairs the situation but at the expense of hyperscaling and finite-size scaling, both of which were, until recently, believed not to apply above ducd_{\rm uc}duc​. We recall limitations of various attempts to match the RG with analytical and numerical results for Ising systems. We explain how the extension of dangerous irrelevancy to the correlation sector is key to marrying the above concepts into a comprehensive RG scaling picture that renders hyperscaling and finite-size scaling valid in all dimensions. We collect what we believe is the current status of the theory, including some new insights and results. This paper is in grateful memory of Michael Fisher who introduced many of the concepts discussed and who, half a century later, contributed to their advancement.
Abstract This paper presents an in-depth analysis of the anatomy of both thermodynamics and statistical mechanics, together with the relationships between their constituent parts. Based on this analysis, using the renormalization group and finite-size scaling, we give a definition of a large but finite system and argue that phase transitions are represented correctly, as incipient singularities in such systems. We describe the role of the thermodynamic limit. And we explore the implications of this picture of critical phenomena for the questions of reduction and emergence.
These lecture notes provide an overview of the renormalization group (RG) as a successful framework to understand critical phenomena above the upper critical dimension d_{uc} d u c . After an introduction to the scaling picture of continuous phase transitions, we discuss the apparent failure of the Gaussian fixed point to capture scaling for Landau mean-field theory, which should hold in the thermodynamic limit above d_{uc} d u c . We recount how Fisher’s dangerous-irrelevant-variable formalism applied to thermodynamic functions partially repairs the situation but at the expense of hyperscaling and finite-size scaling, both of which were, until recently, believed not to apply above d_{uc} d u c . We recall limitations of various attempts to match the RG with analytical and numerical results for Ising systems. We explain how the extension of dangerous irrelevancy to the correlation sector is key to marrying the above concepts into a comprehensive RG scaling picture that renders hyperscaling and finite-size scaling valid in all dimensions. We collect what we believe is the current status of the theory, including some new insights and results. This paper is in grateful memory of Michael Fisher who introduced many of the concepts discussed and who, half a century later, contributed to their advancement.