These lectures describe the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, these general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Then the Landau theory of phase transitions is presented. The form of free energy in the Landau theory is motivated by an explicit mean field calculation for the Ising model. This is followed by a discussion of spatial correlations and the breakdown of the mean field theory due to increase of spatial fluctuations near the critical point. This calculation also brings out the role of dimension of the system for the critical behaviour. The basic ideas of Renormalization Group (RG) are then introduced and illustrated by a simple RG calculation for the one-dimensional Ising model. Real-space RG calculations are then applied to the two-dimensional Ising model on the triangular lattice, which, in fact, brings forth several key features of the RG technique. A discussion of more general aspects of the RG formalism, such as scaling for spatial correlation functions, relevant and irrelevant couplings, universality, upper critical dimension, etc. are introduced.
These lectures describe the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, these general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Then the Landau theory of phase transitions is presented. The form of free energy in the Landau theory is motivated by an explicit mean field calculation for the Ising model. This is followed by a discussion of spatial correlations and the breakdown of the mean field theory due to increase of spatial fluctuations near the critical point. This calculation also brings out the role of dimension of the system for the critical behaviour. The basic ideas of Renormalization Group (RG) are then introduced and illustrated by a simple RG calculation for the one-dimensional Ising model. Real-space RG calculations are then applied to the two-dimensional Ising model on the triangular lattice, which, in fact, brings forth several key features of the RG technique. A discussion of more general aspects of the RG formalism, such as scaling for spatial correlation functions, relevant and irrelevant couplings, universality, upper critical dimension, etc. are introduced.
This chapter describes the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, the general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Phase transitions occur in macroscopic systems when one or more external parameters like temperature, pressure, electrical field, magnetic field, etc are varied. The chapter demonstrates the utility of the alternative formulations of thermodynamics and statistical mechanics in the context of phase transitions and shows how their use clarifies and unifies the theory of phase transitions. It deals with the basic thermodynamic description of a single component fluid. To understand different phases and associated transitions, one studies how the couplings flow in the parameter space under repeated Renormalization Group (RG) transformations. The flows around the fixed point are easily studied by linearizing the RG equations around the fixed points and determining the eigenvalues and eigenvectors of the linearized RG transformations.
The chapter is an introduction to basic equilibrium aspects of phase transitions. It starts by reviewing thermodynamics and the thermodynamic description of phase transitions. Next, lattice models, such as the paradigmatic Ising model, are introduced as simple physical models that permit a mechano-statistical study of phase transitions from a more microscopic point of view. It is shown that the Ising model can quite faithfully describe many different systems after suitable interpretation of the lattice variables. Special emphasis is placed on the mean-field concept and the mean-field approximations. The deformable Ising model is then studied as an example that illustrates the interplay of different degrees of freedom. Subsequently, the Landau theory of phase transitions is introduced for continuous and first-order transitions, as well as critical and tricritical behaviour are analysed. Finally, scaling theories and the notion of universality within the framework of the renormalization group are briefly discussed.
The sophistication of modern tools used in the study of statistical mechanics and field theory is often an obstacle to the easy understanding of new important current results reported in journals. The main purpose of this book is to introduce the reader to the methods of the fluctuation (field) theory of phase transitions and critical phenomena so as to provide a good source for research. The introductory contents are concerned with ideas of description, thermodynamic stability theory related to phase transitions, major experimental facts, basic models and their relationships. Special attention is paid to the mean field approximation and to the Landau expansion for simple and complex models of critical and multicritical phenomena. An instructive representation of the modern perturbation theory and the method of the renormalization group is developed for field models of phase transitions. The essential influence of the fluctuations on the critical behaviour is established together with the theory of correlation functions, Gaussian approximation, the Ginzburg criterion, [symbol]- and 1/n- expansions as practical realizations of the renormalization group ideas. Applications of the theory to concrete aspects of condensed matter physics are considered: quantum effects, Bose condensation, crystal anisotropy, superconductors and liquid crystals, effects of disorder of type randomly distributed quenched impurities and random fields. This volume can be used as an advanced University course book for students with a basic knowledge of statistical physics and quantum mechanics. It could be considered as a complementary text to a standard University course on statistical physics
Abstract The successful calculation of critical exponents for continuous phase transitions is one of the main achievements of theoretical physics over the last quarter-century. This was achieved through the use of scaling and field-theoretic techniques which have since become standard equipment in many areas of physics, especially quantum field theory. This book provides a thorough introduction to these techniques. Continuous phase transitions are introduced, then the necessary statistical mechanics is summarized, followed by standard models, some exact solutions and techniques for numerical simulations. The real-space renormalization group and mean-field theory are then explained and illustrated. The final chapters cover the Landau-Ginzburg model, from physical motivation, through diagrammatic perturbation theory and renormalization to the renormalization group and the calculation of critical exponents above and below the critical temperature.
This book provides an elementary introduction to the notions of continuum limit and universality in statistical systems with a large number of degrees of freedom. The existence of a continuum limit requires the appearance of correlations at large distance, a situation that is encountered in second order phase transitions, near the critical temperature. In this context, the book emphasizes the role of gaussian distributions and their relations with the mean field approximation and Landau′s theory of critical phenomena. The book shows that quasi-gaussian or mean-field approximations cannot describe correctly phase transitions in three space dimensions. The book assigns this difficulty to the coupling of very different physical length scales, even though the systems we will consider have only local, that is, short range, interactions. To analyze the unusual situation, a new concept is required: the renormalization group, whose fixed points allow understanding the universality of physical properties at large distance, beyond mean-field theory. In the continuum limit, critical phenomena can be described by quantum field theories. In this framework, the renormalization group is directly related to the renormalization process; that is, the necessity to cancel the infinities that arise in straightforward formulations of the theory. The book discusses the renormalization group in the context of various relevant field theories. This leads to proofs of universality and to efficient tools for calculating universal quantities in a perturbative framework. Finally, the book constructs a general functional renormalization group, which can be used when perturbative methods are inadequate.
The renormalization-group (RG) method discussed in this chapter has assumed a pivotal role in the modern theory of critical phenomena. It attempts to relate the partition function of a given system to that of a “similar system” with decreased degrees of freedom through a process referred to as renormalization. Exactly how these degrees of freedom are removed from the system, what we mean by a “similar” system, and how successive systems are coupled to one another are essentially the questions we take up in the introductory treatment given in this chapter. The RG method is a topic with large scope and found widely disseminated in an extensive physics literature on the topic; however, it is seldom found in engineering journals. Our purpose here is to try and make sense of some basic ideas with the RG approach so that it is more accessible to this wider community. For this we often rely upon some prior exposes of the subject in more specialized settings [1, 2, 3, 5]. In its complete sense, the RG method has only been made to work, at least analytically, for a few simple statistical-mechanical models. But aside from these numerical results, many important and quite general insights about critical phenomena can be developed from studying this approach to the problem, especially the central role played by length scale as a factor in describing the phenomenology. These ideas have significantly enhanced our understanding of ideas like scale invariance, universality classes, relevant scaling fields (as opposed to irrelevant ones), Hamiltonian renormalization, and so on; these and related concepts lie at the center of modern discourse on the subject. The essential concepts of the approach can be well illustrated using the Ising system since, with this model, lattice spins are fixed in space, which makes the analytical work quite transparent. This approach, called real space renormalization, is the RG method studied in this chapter.