This chapter describes the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, the general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Phase transitions occur in macroscopic systems when one or more external parameters like temperature, pressure, electrical field, magnetic field, etc are varied. The chapter demonstrates the utility of the alternative formulations of thermodynamics and statistical mechanics in the context of phase transitions and shows how their use clarifies and unifies the theory of phase transitions. It deals with the basic thermodynamic description of a single component fluid. To understand different phases and associated transitions, one studies how the couplings flow in the parameter space under repeated Renormalization Group (RG) transformations. The flows around the fixed point are easily studied by linearizing the RG equations around the fixed points and determining the eigenvalues and eigenvectors of the linearized RG transformations.
This chapter describes the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, the general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Phase transitions occur in macroscopic systems when one or more external parameters like temperature, pressure, electrical field, magnetic field, etc are varied. The chapter demonstrates the utility of the alternative formulations of thermodynamics and statistical mechanics in the context of phase transitions and shows how their use clarifies and unifies the theory of phase transitions. It deals with the basic thermodynamic description of a single component fluid. To understand different phases and associated transitions, one studies how the couplings flow in the parameter space under repeated Renormalization Group (RG) transformations. The flows around the fixed point are easily studied by linearizing the RG equations around the fixed points and determining the eigenvalues and eigenvectors of the linearized RG transformations.
Introduction In this chapter we provide a comprehensive and unified treatment of the physical concepts and quantities relevant to phase transitions and critical phenomena. Some of these concepts and quantities have already been discussed in the particular contexts of magnetism (Chapter 7), or liquid crystals (Chapter 9, We conclude the chapter with a brief reference to the application of renormalisation group ideas to critical phenomena. The resulting reconciliation of the predictions of classical theories with experiments and exact or quasi-exact solutions of model systems is a major triumph of twentieth-century physics. Phases and phase transitions Thermodynamics habitually deals with equilibrium systems that are uniform on the macroscopic scale – i.e., where the structure, density and composition are the same throughout the bulk of the system, which is many times greater than a single atom or molecule. Because the system is in equilibrium, intensive thermodynamic variables such as the temperature or chemical potential are also spatially uniform. Such a system is said to consist of a single phase – it is a one-phase system. Phases are what used to be called the states of matter. Solids, liquids, gases and plasmas are four commonly occurring phases – they correspond to the four elements of Aristotelian physics: earth, water, air and fire, respectively. There are, however, many other, less easily identified phases, some of which we have already encountered in this book, such as the ferromagnetic, antiferromagnetic, nematic or superconducting phases. On varying the temperature, pressure and chemical potential(s) of a system, properties such as its structure, density, composition, compressibility, specific heat, etc., in general change smoothly. Yet under certain conditions the changes may be abrupt – some of these properties may exhibit discontinuities, or even divergences, at a phase transition . Phase transitions are among the most spectacular phenomena of nature. Consider, for instance, the phase sequence of water on heating: from ice, an opaque, slippery, rock-like solid; to colourless, incompressible, liquid water, which nevertheless easily flows under gravity; to water vapour, an invisible and very low-density (greenhouse!) gas, hence of ill-defined volume.
Abstract Chapter 16 explores the statistical mechanics of discrete lattice models and their use in describing critical phenomena. The chapter begins with a review of phase diagrams, coexistence curves, crititical points, and the behavior of certain thermodynamic quantities in the neighborhood of a critical point. The notion of universality classes is introduced. To set up the class of lattice models, magnetic systems are described; simplifications are made to these models to yield the so-called Ising model. Solution of this model is demonstrated within the mean-field theory approximation, which is shown to yield a qualitative description of critical behavior. Exact solutions are derived in one and two dimensions, and predictions of critical exponents from them are obtained. Following this, the renormalization group is introduced, and approaches for understanding critical behavior and universality from renormalization group transformations are discussed. The chapter concludes with a discussion of the use of discrete models in areas ranging from molecular crystals to tissue morphogenesis
In this chapter, the author shows the theory of phase transition using some systems of interacting spins. Note that various systems of different nature can be mapped into spin systems and solved using the spin language. However, the mean-field theory gives some artifacts at low dimensions and cannot determine with precision the critical exponents which characterize the nature of a phase transition. A transition from one phase to another may take place when an external parameter varies. Such a parameter can be the temperature or an external applied magnetic field. Renormalization group analysis shows that the universality class depends only on a few very general parameters such as the space dimension, the symmetry of the order parameter and the nature of the interaction. The Landau–Ginzburg theory is an extension of the mean-field theory which includes a great part of fluctuations so far neglected near the transition.
The chapter is an introduction to basic equilibrium aspects of phase transitions. It starts by reviewing thermodynamics and the thermodynamic description of phase transitions. Next, lattice models, such as the paradigmatic Ising model, are introduced as simple physical models that permit a mechano-statistical study of phase transitions from a more microscopic point of view. It is shown that the Ising model can quite faithfully describe many different systems after suitable interpretation of the lattice variables. Special emphasis is placed on the mean-field concept and the mean-field approximations. The deformable Ising model is then studied as an example that illustrates the interplay of different degrees of freedom. Subsequently, the Landau theory of phase transitions is introduced for continuous and first-order transitions, as well as critical and tricritical behaviour are analysed. Finally, scaling theories and the notion of universality within the framework of the renormalization group are briefly discussed.
Abstract Chapter 6 describes how the perturbative renormalization group (RG) of quantum field theory has made it possible to derive universal properties of continuous macroscopic phase transitions. The RG initially emerged as a consequence of the necessity to cancel infinities that appear in the perturbative expansion (the renormalization procedure) and the possibility of defining the parameters of the renormalized theory at different momentum scales. Although the field theory RG is now understood to be an asymptotic form, it has made it possible to confirm the Wilson–Fisher fixed point and led to an understanding of universality for a large class of critical phenomena. In the framework of dimensional continuation, zeros of RG beta functions, which correspond to Wilson–Fisher’s fixed points, have made it possible to recover Wilson–Fisher’s epsilon expansion, proving scaling relations and calculating critical exponents. Series summation methods have then been used to generate precise values of exponents.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.