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Entropy Production in Quantum Heat Engines with Squeezed Reservoirs

Pavol Berger, Natalia Zizka, Andrej Molnar

Published Jun 15, 2026• 0 citations
Publisher

Abstract

Squeezed thermal reservoirs have been proposed as a route to boosting the efficiency and power of quantum heat engines beyond the standard Carnot bound, since squeezing injects an effective negative entropy that can, in principle, be converted into extra work. What remains poorly quantified is the entropy-production cost that driving a working qubit against a squeezed bath actually incurs once finite-time operation and reservoir decoherence are taken into account. We simulate a quantum Otto-cycle heat engine built from a two-level working system coupled alternately to a hot reservoir at temperature 4.2 K, squeezed with squeezing parameter r ranging from 0 to 1.2, and an unsqueezed cold reservoir at 0.8 K, integrating the Lindblad master equation across 42 combinations of squeezing parameter and cycle duration between 0.05 and 2.0 (in units of the inverse qubit gap). At r = 0, mean entropy production per cycle was 0.223 k_B, consistent with standard finite-time Otto-cycle behaviour, but rose to 0.361 k_B at r = 1.2, a 62% increase, even as extractable work per cycle increased by 41%, from 0.184 to 0.259 (in units of the qubit gap). The ratio of work output to entropy production, an effective thermodynamic figure of merit, was therefore not monotonic in squeezing: it peaked at r = 0.6, where work per unit entropy produced reached 0.98, 15% above the unsqueezed value of 0.85, before declining at higher squeezing as entropy production began to outpace the marginal work gain. Power output at the maximum-power cycle duration increased with squeezing across the full range tested, from 0.31 (gap units) at r = 0 to 0.52 at r = 1.2, a 68% gain, but efficiency at maximum power fell from 0.41 to 0.33 over the same range, a trade-off traced out in detail in Table 1. A decomposition of total entropy production attributed 58-71% to hot-bath coupling across all squeezing values, with the squeezed-bath contribution alone rising from undefined at r = 0 to 34% of hot-bath entropy production at r = 1.2, while coherence generated during the unitary strokes accounted for a comparatively stable 12-18% regardless of squeezing strength. These results indicate that reservoir squeezing in quantum heat engines delivers a genuine power and work advantage but at a non-negligible and squeezing-dependent entropy cost, with an intermediate squeezing level offering the best entropy-normalized performance rather than the strongest squeezing tested, a finding directly relevant to the design of squeezed-bath quantum thermal devices operating under realistic decoherence.

DOI
10.5281/zenodo.22698604

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Squeezed thermal reservoirs have been proposed as a route to boosting the efficiency and power of quantum heat engines beyond the standard Carnot bound, since squeezing injects an effective negative entropy that can, in principle, be converted into extra work. What remains poorly quantified is the entropy-production cost that driving a working qubit against a squeezed bath actually incurs once finite-time operation and reservoir decoherence are taken into account. We simulate a quantum Otto-cycle heat engine built from a two-level working system coupled alternately to a hot reservoir at temperature 4.2 K, squeezed with squeezing parameter r ranging from 0 to 1.2, and an unsqueezed cold reservoir at 0.8 K, integrating the Lindblad master equation across 42 combinations of squeezing parameter and cycle duration between 0.05 and 2.0 (in units of the inverse qubit gap). At r = 0, mean entropy production per cycle was 0.223 k_B, consistent with standard finite-time Otto-cycle behaviour, but rose to 0.361 k_B at r = 1.2, a 62% increase, even as extractable work per cycle increased by 41%, from 0.184 to 0.259 (in units of the qubit gap). The ratio of work output to entropy production, an effective thermodynamic figure of merit, was therefore not monotonic in squeezing: it peaked at r = 0.6, where work per unit entropy produced reached 0.98, 15% above the unsqueezed value of 0.85, before declining at higher squeezing as entropy production began to outpace the marginal work gain. Power output at the maximum-power cycle duration increased with squeezing across the full range tested, from 0.31 (gap units) at r = 0 to 0.52 at r = 1.2, a 68% gain, but efficiency at maximum power fell from 0.41 to 0.33 over the same range, a trade-off traced out in detail in Table 1. A decomposition of total entropy production attributed 58-71% to hot-bath coupling across all squeezing values, with the squeezed-bath contribution alone rising from undefined at r = 0 to 34% of hot-bath entropy production at r = 1.2, while coherence generated during the unitary strokes accounted for a comparatively stable 12-18% regardless of squeezing strength. These results indicate that reservoir squeezing in quantum heat engines delivers a genuine power and work advantage but at a non-negligible and squeezing-dependent entropy cost, with an intermediate squeezing level offering the best entropy-normalized performance rather than the strongest squeezing tested, a finding directly relevant to the design of squeezed-bath quantum thermal devices operating under realistic decoherence.
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cycle, which are dependent on the time duration along each process. With these, we derive the analytical expressions for the thermodynamic quantities of the two-level heat engine, such as total work, thermodynamic efficiency, entropy production, and work fluctuations, in which effects of coherence, squeezing, inner friction and finite-time heat exchange are included. We then numerically determine the thermodynamic quantities and the fluctuations using the parameters employed in the experimental implementation. Our results clarify the role of coherence and squeezing in the performance and fluctuations in the quantum Otto engines.
Abstract We work on a comprehensive theoretical investigation of a three-level quantum heat engine operating with engineered squeezed thermal reservoirs. Unlike conventional quantum heat engines that use thermal reservoirs, we demonstrate that squeezed reservoirs can significantly enhance the engine's performance by increasing both efficiency and output power. Using a rigorous open-quantum-system approach, we derive the full Lindblad master equation for a three-level system interacting with hot and cold squeezed thermal baths. Through a detailed analysis of the steady-state thermodynamics, we obtain explicit expressions for heat currents, work output, and efficiency. Our results reveal that moderate squeezing parameters (r≈0.5r \approx 0.5r≈0.5) combined with optimal squeezing phase (ϕ=π/2\phi = \pi/2ϕ=π/2) enhance the engine efficiency by up to 40\% compared to the classical Carnot limit for the same temperature ratio. The power output shows a non-monotonic behavior with squeezing, exhibiting an optimal squeezing parameter that maximizes performance. We identify three distinct operational regimes: (i) heat engine regime, (ii) refrigerator regime, and (iii) heat pump regime, which can be tuned by adjusting the squeezing phase. The efficiency at maximum power follows a universal scaling ηMP≈ηCarnot/2+Δη(r)\eta_{MP} \approx \eta_{Carnot}/2 + \Delta\eta(r)ηMP​≈ηCarnot​/2+Δη(r), where Δη(r)\Delta\eta(r)Δη(r) represents the squeezing-induced enhancement. Our findings provide fundamental insights into the role of non-thermal reservoirs in quantum thermodynamics and offer practical guidelines for designing high-performance quantum heat engines using squeezed light and engineered baths.
We consider the finite-time performance of a quantum Otto engine working between a hot squeezed and a cold thermal bath at inverse temperatures ${\ensuremath{\beta}}_{h}$ and ${\ensuremath{\beta}}_{c}(>{\ensuremath{\beta}}_{h})$ with $({k}_{B}\ensuremath{\equiv}1)\ensuremath{\beta}=1/T$. We derive the analytical expressions for work, efficiency, power, and power fluctuations, in which the squeezing parameter is involved. By optimizing the power output with respect to two frequencies, we derive the efficiency at maximum power as ${\ensuremath{\eta}}_{mp}={({\ensuremath{\eta}}_{C}^{\mathrm{gen}})}^{2}/[{\ensuremath{\eta}}_{C}^{\mathrm{gen}}\ensuremath{-}(1\ensuremath{-}{\ensuremath{\eta}}_{C}^{\mathrm{gen}})ln(1\ensuremath{-}{\ensuremath{\eta}}_{C}^{\mathrm{gen}})]$, where the generalized Carnot efficiency ${\ensuremath{\eta}}_{C}^{\mathrm{gen}}$ in the high-temperature or small squeezing limit simplifies to an analytic function of squeezing parameter $\ensuremath{\gamma}$: ${\ensuremath{\eta}}_{C}^{\mathrm{gen}}=1\ensuremath{-}{\ensuremath{\beta}}_{h}/[{\ensuremath{\beta}}_{c}cosh(2\ensuremath{\gamma})]$. Within the context of irreversible thermodynamics, we demonstrate that the expression of efficiency at maximum power satisfies a general form derived from nonlinear steady state heat engines. We show that, the power fluctuations are considerably increased, although the engine efficiency is enhanced by squeezing.
We analyze the performance of a quantum Otto cycle, employing a time-dependent harmonic oscillator as the working fluid undergoing sudden expansion and compression strokes during the adiabatic stages, coupled to a squeezed reservoir. First, we show that the maximum efficiency that our engine can achieve is 1/2 only, which is in contrast with earlier studies claiming unit efficiency under the effect of a squeezed reservoir. Then, in the high-temperature limit, we obtain analytic expressions for the upper bound on the efficiency as well as on the coefficient of performance of the Otto cycle. The obtained bounds are independent of the parameters of the system and depend on the reservoir parameters only. Additionally, with a hot squeezed thermal bath, we obtain an analytic expression for the efficiency at maximum work which satisfies the derived upper bound. Further, in the presence of squeezing in the cold reservoir, we specify an operational regime for the Otto refrigerator otherwise forbidden in the standard case. Finally, we find the cost of creating a squeezed state from the thermal state and show that in order to harvest the benefits of squeezing, it is sufficient to squeeze only one mode of the reservoir in resonance with the transition frequency of the working fluid. Further, we show that when the cost of squeezing is included in the definition of the operational efficiency of the engine, the advantages of squeezing fade away. Still, being purely quantum mechanical fuel in nature, squeezed reservoirs are beneficial in their own way by providing us with more compact energy storage medium or offering effectively high-temperature baths without being actually too hot.
We characterize the entropy production and the maximal extractable work from a squeezed thermal reservoir. The nonequilibrium quantum nature of the reservoir induces an entropy transfer with a coherent contribution while modifying its thermal part, allowing work extraction from a single reservoir, as well as great improvements in power and efficiency for quantum heat engines, which are characterized. Introducing a modified quantum Otto cycle, we predict the appearance of operational regimes forbidden in the standard case, such as refrigeration and work extraction at the same time, accompanied by efficiencies equal to unity.
Abstract Recent theoretical and experimental studies in quantum heat engines show that, in the quasi-static regime, it is possible to have higher efficiency than the limit imposed by Carnot, provided that engineered reservoirs are used. The quasi-static regime, however, is a strong limitation to the operation of heat engines, since an infinitely long time is required to complete a cycle. In this paper we propose a two-level model as the working substance to perform a quantum Otto heat engine surrounded by a cold thermal reservoir and a squeezed hot thermal reservoir. Taking advantage of this model we show a striking achievement, that is to attain unity efficiency even at non-null power.