In the last decade, the study of thermodynamic phenomena in ultra-small scales, where quantum mechanics becomes imperative, has gained a lot of attention. The possibility of controlling single quantum states in nowadays experimental setups has encouraged a more intense inquiry over the intersection between thermodynamics and quantum mechanics, which is known as quantum thermodynamics. Particularly relevant in this framework is the study of quantum heat engines, that is, quantum systems undergoing thermodynamic cycles. Thermodynamic cycles contain all the aspects of thermodynamics, thus its a good testbed for a better comprehension of the thermodynamics of quantum systems. Moreover, modelling quantum heat engines is crucial for the design of future ultra-small engines. Nonetheless, another aspect must be taken into account, finite-time operation. Its very important for the optimization of the output power of the engine. In this dissertation, we present a new model of finite-time quantum heat engines. By making use of collisional models, we construct a model in which a generic quantum chain experiences sequential pure heat and pure work strokes. Dictated by stroboscopic evolution, the engines state goes through a transient regime until the limit-cycle is reached. After the achievement of the limit-cycle, our results indicate that only the boundary sites of the quantum chain are relevant for the heat currents exchanged with the baths. By means of analytical and numerical methods, we present how the model is useful for optimizing the output power of stroke-based quantum heat engines, without decreasing their respective efficiencies. Lastly, we prove that there is a universal efficiency value, the Otto efficiency, for a whole family of models containing a specific kind of internal interactions. For completeness, other methods from the literature which deal with finite-time quantum heat engines are also presented and discussed.
In the last decade, the study of thermodynamic phenomena in ultra-small scales, where quantum mechanics becomes imperative, has gained a lot of attention. The possibility of controlling single quantum states in nowadays experimental setups has encouraged a more intense inquiry over the intersection between thermodynamics and quantum mechanics, which is known as quantum thermodynamics. Particularly relevant in this framework is the study of quantum heat engines, that is, quantum systems undergoing thermodynamic cycles. Thermodynamic cycles contain all the aspects of thermodynamics, thus its a good testbed for a better comprehension of the thermodynamics of quantum systems. Moreover, modelling quantum heat engines is crucial for the design of future ultra-small engines. Nonetheless, another aspect must be taken into account, finite-time operation. Its very important for the optimization of the output power of the engine. In this dissertation, we present a new model of finite-time quantum heat engines. By making use of collisional models, we construct a model in which a generic quantum chain experiences sequential pure heat and pure work strokes. Dictated by stroboscopic evolution, the engines state goes through a transient regime until the limit-cycle is reached. After the achievement of the limit-cycle, our results indicate that only the boundary sites of the quantum chain are relevant for the heat currents exchanged with the baths. By means of analytical and numerical methods, we present how the model is useful for optimizing the output power of stroke-based quantum heat engines, without decreasing their respective efficiencies. Lastly, we prove that there is a universal efficiency value, the Otto efficiency, for a whole family of models containing a specific kind of internal interactions. For completeness, other methods from the literature which deal with finite-time quantum heat engines are also presented and discussed.
The formulation of models describing quantum versions of heat engines plays an important role in the quest toward establishing the laws of thermodynamics in the quantum regime. Of particular importance is the description of stroke-based engines, which can operate at finite time. In this paper we put forth a framework for describing stroboscopic, two-stroke engines, in generic quantum chains. The framework is a generalization of the so-called SWAP engine and is based on a collisional model, which alternates between pure heat and pure work strokes. The transient evolution towards a limit cycle is also fully accounted for. Moreover, we show that once the limit cycle has been reached, the energy of the internal sites of the chain no longer changes, with the heat currents being associated exclusively to the boundary sites. Using a combination of analytical and numerical methods, we show that this type of engine offers multiple ways of optimizing the output power, without affecting the efficiency. Finally, we also show that there exists an entire class of models, characterized by a specific type of interchain interaction, which always operate at Otto efficiency, irrespective of the operating conditions of the reservoirs.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems. With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts. Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium. One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnots or operate in certain regimes unattainable using only classical resources. Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome. So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity. The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used. We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency. By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations. We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine. The same procedure was repeated for a 3-level system WS. The modes 1 and -1 was again very important, not only to the absolute value of the engines efficiency but to the regime of operation of the machine. The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value. This result appears to show some evidences that quantumness wont necessarily bring improvements to the operation of those machines.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.
Many models of heat engines have been studied with the tools of finite-time thermodynamics and an ensemble of independent quantum systems as the working fluid. Because of their convenient analytical properties, harmonic oscillators are the most frequently used example of a quantum system. We analyze different thermodynamical aspects with the final aim of the optimization of the performance of the engine in terms of the mechanical power provided during a finite-time Otto cycle. The heat exchange mechanism between the working fluid and the thermal reservoirs is provided by the Lindblad formalism. We describe an analytical method to find the limit cycle and give conditions for a stable limit cycle to exist. We explore the power production landscape as the duration of the four branches of the cycle are varied for short times, intermediate times, and special frictionless times. For short times we find a periodic structure with atolls of purely dissipative operation surrounding islands of divergent behavior where, rather than tending to a limit cycle, the working fluid accumulates more and more energy. For frictionless times the periodic structure is gone and we come very close to the global optimal operation. The global optimum is found and interestingly comes with a particular value of the cycle time.
Abstract The efficiency of a quantum heat engine is maximum when the unitary strokes of the quantum Otto cycle are adiabatic. On the other hand, this may not be always possible due to small energy gaps in the system, especially at the critical point (CP) where the gap between the ground state and the first excited state vanishes and the system gets excited. With the aim to regain this lost adiabaticity, we modify one of the unitary strokes of the Otto cycle by allowing the system to first evolve with a time dependent Hamiltonian as in the case of a usual Otto cycle, followed by an additional evolution with a different time independent Hamiltonian so that the system reaches a less excited state. This will help in increasing the magnitude of the heat absorbed from the hot bath so that the work output and efficiency of the engine can be increased. We demonstrate this method using an integrable model and a non-integrable model as the working medium and discuss the generality and limitations of this method. In the case of a two spin system, the optimal value for the time till which the system needs to be freely evolved is calculated analytically in the adiabatic limit. The results show that implementing this modified unitary stroke significantly improves the work output and efficiency of the engine, especially when it crosses the CP.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.