Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems. With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts. Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium. One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnots or operate in certain regimes unattainable using only classical resources. Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome. So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity. The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used. We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency. By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations. We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine. The same procedure was repeated for a 3-level system WS. The modes 1 and -1 was again very important, not only to the absolute value of the engines efficiency but to the regime of operation of the machine. The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value. This result appears to show some evidences that quantumness wont necessarily bring improvements to the operation of those machines.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Abstract This paper presents an analysis of quantum Otto heat engines operating in non-equilibrium. It explores the fundamental thermodynamic principles that govern these engines, focusing on efficiency, work output, and the impact of environmental factors such as thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to ideal scenarios, emphasizing the importance of considering both quantum effects and real-world limitations in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
Quantum heat engines are devices comprised of one or more quantum systems operating cyclically between two heat reservoirs to produce work.Although the laws of quantum mechanics rule these engines, this does not imply that these machines function in a quantum fashion, or exhibit a quantum advantage.Indeed, quantum heat engines have shown a remarkable similarity with classical models, thus raising the question of what is "quantum" in quantum thermodynamics.With the help of the P-representability concept, an expression called classicality function is introduced -allowing us to quantify the degree of non-classicality of a bosonic system.As an illustration, we consider a quantum heat engine consisting of a single bosonic mode as a working substance coupled to a cold thermal and hot squeezed thermal bath.For two specific protocols, i.e., a quantum Otto and a generalized cycle, we show that the non-classicality is a resource that can be used to perform thermodynamical tasks more efficiently.Furthermore, we present a theoretical framework to study how quantum features, such as entanglement or coherence, affect the classical formulations of thermodynamic axioms.
This paper presents an analysis of quantum Otto heat engines operating out of equilibrium. It explores the fundamental thermodynamic principles governing these engines, focusing on efficiency, work output, and the impact of environmental factors, including thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to idealized scenarios, underscoring the importance of accounting for both quantum effects and real-world constraints in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
During the last decades, there have been many theoretical and experimental advances both in the extension of thermodynamics to comprise microscopic systems out-of-equilibrium and in the understanding of quantum mechanics.Along with the state-of-the-art capability of controlling fragile quantum systems in a wide variety of physical platforms, this context has paved the way for the current strategic efforts to develop a thermodynamic theory of quantum systems.In this sense, the research field coined as quantum thermodynamics (QT) already plays a key role in the design and development of future quantum-based technologies.More specifically, QT aims both to apply the usual thermodynamic concepts and notions to describe arbitrary non-equilibrium quantum systems and to understand the emergence of classical thermodynamic behaviour from the underlying fundamentally quantum dynamics.However, despite all current progress, there is still no consolidated formalism for a general thermodynamic description of fully autonomous quantum objects.Besides, the lack of consensus on some central aspects, such as the definitions of quantum counterparts of thermodynamic quantities, is particularly notorious.In this thesis, we focus on the energetic analysis within autonomous quantum systems.To this aim, we propose a novel and general formalism for a dynamic description of the energy exchanges between interacting subsystems.From the Schmidt decomposition approach, we identify effective Hamiltonians as the representative operators for characterizing the local internal energies, whose expectation values satisfy the usual thermodynamic notion of energy additivity.In contrast to the currently used methodologies, such procedure treats the subsystems with equal footing and do not rely on any sort of approximations and additional hypotheses, e.g., semi-classical description, weak-coupling regime, strict energy conservation and Markovian dynamics.In short, our proposal contributes to the development of QT by providing a new formalism that does not suffer from the usual restrictive shortcomings and establishes a new and exact route for defining other general thermodynamic quantities to the quantum regime.