Quantum heat engines are devices comprised of one or more quantum systems operating cyclically between two heat reservoirs to produce work.Although the laws of quantum mechanics rule these engines, this does not imply that these machines function in a quantum fashion, or exhibit a quantum advantage.Indeed, quantum heat engines have shown a remarkable similarity with classical models, thus raising the question of what is "quantum" in quantum thermodynamics.With the help of the P-representability concept, an expression called classicality function is introduced -allowing us to quantify the degree of non-classicality of a bosonic system.As an illustration, we consider a quantum heat engine consisting of a single bosonic mode as a working substance coupled to a cold thermal and hot squeezed thermal bath.For two specific protocols, i.e., a quantum Otto and a generalized cycle, we show that the non-classicality is a resource that can be used to perform thermodynamical tasks more efficiently.Furthermore, we present a theoretical framework to study how quantum features, such as entanglement or coherence, affect the classical formulations of thermodynamic axioms.
Quantum heat engines are devices comprised of one or more quantum systems operating cyclically between two heat reservoirs to produce work.Although the laws of quantum mechanics rule these engines, this does not imply that these machines function in a quantum fashion, or exhibit a quantum advantage.Indeed, quantum heat engines have shown a remarkable similarity with classical models, thus raising the question of what is "quantum" in quantum thermodynamics.With the help of the P-representability concept, an expression called classicality function is introduced -allowing us to quantify the degree of non-classicality of a bosonic system.As an illustration, we consider a quantum heat engine consisting of a single bosonic mode as a working substance coupled to a cold thermal and hot squeezed thermal bath.For two specific protocols, i.e., a quantum Otto and a generalized cycle, we show that the non-classicality is a resource that can be used to perform thermodynamical tasks more efficiently.Furthermore, we present a theoretical framework to study how quantum features, such as entanglement or coherence, affect the classical formulations of thermodynamic axioms.
At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of P-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines and design optimal protocols for work extraction. For two specific cycles, a quantum Otto and a generalised one, we show that non-classicality is a fundamental resource for performing thermodynamic tasks more efficiently.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.
Quantum heat engines (QHE) are thermal machines where the working substance is quantum. In the extreme case the working medium can be a single particle or a few level quantum system. The study of QHE has shown a remarkable similarity with the standard thermodynamical models, thus raising the issue what is quantum in quantum thermodynamics. Our main result is thermodynamical equivalence of all engine type in the quantum regime of small action. They have the same power, the same heat, the same efficiency, and they even have the same relaxation rates and relaxation modes. Furthermore, it is shown that QHE have quantum-thermodynamic signature, i.e thermodynamic measurements can confirm the presence of quantum coherence in the device. The coherent work extraction mechanism enables power outputs that greatly exceed the power of stochastic (dephased) engines.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.
Quantum thermodynamics studies quantum effects in thermal machines. Both quantum coherence and quantum correlations have been theoretically shown to be a physical resource able to boost their performance. But when is a heat engine, which cyclically interacts with external reservoirs that unavoidably destroy its phase coherence, really quantum? We here use the Leggett-Garg inequality to assess the nonclassical properties of a paradigmatic two-level Otto engine with quantum friction. We provide the complete phase diagram characterizing the quantumness of the engine as a function of its parameters and distinguish three different phases: a quantum phase separated from a classical phase by a transition regime. We further derive an analytical expression for the quantum-to-classical transition temperature.
Quantum thermodynamics explores novel thermodynamic phenomena that emerge when interactions between macroscopic systems and microscopic quantum ones go into action. Among various issues, quantum heat engines, in particular, have attracted much attention as a critical step in theoretical formulation of quantum thermodynamics and investigation of efficient use of heat by means of quantum resources. In the present paper, we focus on heat absorption and emission processes as well as work extraction processes of a quantum Otto cycle. We describe the former as non-Markovian dynamics, and thereby find that the interaction energy between a macroscopic heat bath and a microscopic qubit is not negligible. Specifically, we reveal that the interaction energy is divided into the system and the bath in a region of the short interaction time and remains negative in the region of the long interaction time. In addition, a counterintuitive energy flow from the system and the interaction energy to the hot bath occurs in another region of the short interaction time. We quantify these effects by defining an index of non-Markovianity in terms of the interaction energy. With this behavior of the interaction energy, we show that a non-Markovian quantum Otto cycle can switch functions such as an engine as well as a heater or a heat pump by controlling the interaction time with the heat bath. In particular, the qubit itself loses its energy if we shorten the interaction time, and in this sense, the qubit is cooled through the cycle. This property has a possibility of being utilized for cooling the qubits in quantum computing. We also describe the work extraction from the microscopic system to a macroscopic system like us humans as an indirect measurement process by introducing a work storage as a new reservoir.