At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of P-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines and design optimal protocols for work extraction. For two specific cycles, a quantum Otto and a generalised one, we show that non-classicality is a fundamental resource for performing thermodynamic tasks more efficiently.
At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of P-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines and design optimal protocols for work extraction. For two specific cycles, a quantum Otto and a generalised one, we show that non-classicality is a fundamental resource for performing thermodynamic tasks more efficiently.
Quantum heat engines are devices comprised of one or more quantum systems operating cyclically between two heat reservoirs to produce work.Although the laws of quantum mechanics rule these engines, this does not imply that these machines function in a quantum fashion, or exhibit a quantum advantage.Indeed, quantum heat engines have shown a remarkable similarity with classical models, thus raising the question of what is "quantum" in quantum thermodynamics.With the help of the P-representability concept, an expression called classicality function is introduced -allowing us to quantify the degree of non-classicality of a bosonic system.As an illustration, we consider a quantum heat engine consisting of a single bosonic mode as a working substance coupled to a cold thermal and hot squeezed thermal bath.For two specific protocols, i.e., a quantum Otto and a generalized cycle, we show that the non-classicality is a resource that can be used to perform thermodynamical tasks more efficiently.Furthermore, we present a theoretical framework to study how quantum features, such as entanglement or coherence, affect the classical formulations of thermodynamic axioms.
Abstract This paper presents an analysis of quantum Otto heat engines operating in non-equilibrium. It explores the fundamental thermodynamic principles that govern these engines, focusing on efficiency, work output, and the impact of environmental factors such as thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to ideal scenarios, emphasizing the importance of considering both quantum effects and real-world limitations in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
Abstract A key focus of designing quantum thermal devices is the potential advantage that can be gleaned from genuine quantum effects when compared to classical devices. The recent experimental realization of the Pauli engine (Koch et al 2023 Nature 621 723)—where energy is extracted via changes in particle statistics as an alternative to conventional heat sources—has opened new avenues of research where quantum statistics can be considered as a thermodynamic resource. In this work we propose hybrid quantum heat engines which can utilize additional strokes that change the single particle statistics between bosonic and fermionic descriptions during the cycle. To accomplish this we consider the 1D Lieb–Liniger gas, in which the s-wave interactions can be tuned between the non-interacting and the hard-core limit, which are described by bosonic and fermionic statistics respectively. We show that by suitably choosing where to implement these statistical strokes during an Otto-like cycle in the quasi-static limit, the efficiency and work output can be significantly enhanced when compared to fully bosonic or fully fermionic engines. Furthermore, in the degenerate regime our engine can operate at the Carnot efficiency, due to the interplay between the different contributions of heat and work induced by the statistical strokes. Finally, we highlight how our thermodynamic cycles can realize other thermal operations, such as refrigerators, promising similar statistical enhancements for a wide range of temperatures.
This paper presents an analysis of quantum Otto heat engines operating out of equilibrium. It explores the fundamental thermodynamic principles governing these engines, focusing on efficiency, work output, and the impact of environmental factors, including thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to idealized scenarios, underscoring the importance of accounting for both quantum effects and real-world constraints in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quantum thermodynamic cycles. We find that there is no violation of the second law, even in the existence of such a demon, when the demon is included correctly as part of the working substance of the heat engine.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.