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arXiv:2503.19341 · Quantum Science and Technology

Leveraging quantum statistics to enhance heat engines

Keerthy Menon, Thomas Busch, Thomás Fogarty

Published Sep 2, 2025• 3 citations
arXivHTMLPDF

Abstract

Abstract A key focus of designing quantum thermal devices is the potential advantage that can be gleaned from genuine quantum effects when compared to classical devices. The recent experimental realization of the Pauli engine (Koch et al 2023 Nature 621 723)—where energy is extracted via changes in particle statistics as an alternative to conventional heat sources—has opened new avenues of research where quantum statistics can be considered as a thermodynamic resource. In this work we propose hybrid quantum heat engines which can utilize additional strokes that change the single particle statistics between bosonic and fermionic descriptions during the cycle. To accomplish this we consider the 1D Lieb–Liniger gas, in which the s-wave interactions can be tuned between the non-interacting and the hard-core limit, which are described by bosonic and fermionic statistics respectively. We show that by suitably choosing where to implement these statistical strokes during an Otto-like cycle in the quasi-static limit, the efficiency and work output can be significantly enhanced when compared to fully bosonic or fully fermionic engines. Furthermore, in the degenerate regime our engine can operate at the Carnot efficiency, due to the interplay between the different contributions of heat and work induced by the statistical strokes. Finally, we highlight how our thermodynamic cycles can realize other thermal operations, such as refrigerators, promising similar statistical enhancements for a wide range of temperatures.

DOI
10.1088/2058-9565/ae01d3

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Abstract Heat engines convert thermal energy into mechanical work both in the classical and quantum regimes1. However, quantum theory offers genuine non-classical forms of energy, different from heat, which so far have not been exploited in cyclic engines. Here we experimentally realize a quantum many-body engine fuelled by the energy difference between fermionic and bosonic ensembles of ultracold particles that follows from the Pauli exclusion principle2. We employ a harmonically trapped superfluid gas of6Li atoms close to a magnetic Feshbach resonance3that allows us to effectively change the quantum statistics from Bose–Einstein to Fermi–Dirac, by tuning the gas between a Bose–Einstein condensate of bosonic molecules and a unitary Fermi gas (and back) through a magnetic field4–10. The quantum nature of such a Pauli engine is revealed by contrasting it with an engine in the classical thermal regime and with a purely interaction-driven device. We obtain a work output of several 106vibrational quanta per cycle with an efficiency of up to 25%. Our findings establish quantum statistics as a useful thermodynamic resource for work production.
We propose a quantum heat engine based on a two-component Fermi gas with s-wave contact interaction, operating across the BCS-BEC crossover. The work is extracted from the statistical properties of the gas, which are controlled by the interaction, rather than relying solely on compression and expansion stages. Using the functional renormalization group formalism, we obtain the equation of state in a non-perturbative form along the crossover, encompassing the superfluid-normal phase transition. The cycle combines isentropic density strokes, isochoric thermalization, and isothermal interaction sweeps. This construction makes it possible to integrate features of both Otto and Carnot cycles, in which the system simultaneously saturates both efficiency limits without the net work vanishing. In the absence of density variations, the cycle reduces to a statistical Stirling-like engine, in which the work generated arises exclusively from the interaction, achieving efficiencies up to 38%38\%38%. A pronounced asymmetry emerges through the crossover, giving rise to distinct operating regimes depending on the trajectory followed in the phase diagram. Consequently, the same architecture can be tuned to function as an engine, refrigerator, accelerator, or heater. These findings highlight pairing correlations as a versatile thermodynamic resource for quantum heat machines.
Quantum heat engines, compared to their classical counterparts, offer many advantages due to quantum effects. The study of different cycle modes contributes to the improvement of heat engine efficiency. In this paper, based on a quantum hybrid heat engine, we compare three cycle modes involving Bell-type quantum weak measurement (without observing the results) and two heat baths at different temperatures, where quantum weak measurements play the role of heat source. Thus, there are two types of heat sources and three processes involving heat absorption or release in our model. In other words, we study a multi-stroke quantum hybrid heat engine. Moreover, we further investigate three types of cycle modes using a working substance composed of a three-particle XXZ spin chain. In the adiabatic stroke, we select three Hamiltonian parameters and vary them adiabatically from their initial to final values, comparing their effects on engine efficiency. In particular, we examine how the ordering of the weak-measurement stroke and the adiabatic stroke influences heat absorption, heat release, and engine efficiency. Additionally, we analyze the impact of the high-temperature bath’s temperature and the weak-measurement strength on the engine efficiency.
We have presented an analytical and numerical study of efficiency fluctuations in quantum Carnot and Otto engines with pistons operating under non-quasi-static adiabatic expansion and compression processes at constant speed, along with quasi-static isothermal (for the Carnot engine) or isochoric processes (for the Otto engine). We have considered the two-point measurement scheme during the adiabatic strokes in this regard. By considering each of the pistons as a single quantum particle in a 1-D box with a non-quasi-statically movable boundary, we capture the stochastic nature of the work output resulting from the unitary evolution of the quantum mechanical state of the system during non-equilibrium processes. Furthermore, we have explicitly shown how the piston speed during quantum non-equilibrium strokes introduces additional quantum fluctuations that modify the average efficiency of both the engines.
Particle-particle correlations, characterized by Glauber’s second-order correlation function, play an important role in the understanding of various phenomena in radio and optical astronomy, quantum and atom optics, particle physics, condensed matter physics, and quantum many-body theory. However, the relevance of such correlations to quantum thermodynamics has so far remained illusive. Here, we propose and investigate a class of quantum many-body thermal machines whose operation is directly enabled by second-order atom-atom correlations in an ultracold atomic gas. More specifically, we study quantum thermal machines that operate in a sudden interaction-quench Otto cycle and utilize a one-dimensional Lieb-Liniger gas of repulsively interacting bosons as the working fluid. The atom-atom correlations in such a gas are different to those of a classical ideal gas, and are a result of the interplay between interparticle interactions, quantum statistics, and thermal fluctuations. We show that operating these thermal machines in the intended regimes, such as a heat engine, refrigerator, thermal accelerator, or heater, would be impossible without such atom-atom correlations. Our results constitute a step forward in the design of conceptually new quantum thermodynamic devices which take advantage of uniquely quantum resources such as quantum coherence, correlations, and entanglement.
Abstract This paper presents an analysis of quantum Otto heat engines operating in non-equilibrium. It explores the fundamental thermodynamic principles that govern these engines, focusing on efficiency, work output, and the impact of environmental factors such as thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to ideal scenarios, emphasizing the importance of considering both quantum effects and real-world limitations in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.