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arXiv:2308.05266 · SciPost Physics

Quantum many-body thermal machines enabled by atom-atom correlations

Raymon S. Watson, Karen V. Kheruntsyan

Published Jun 16, 2025• 11 citations
arXivHTMLPDF

Abstract

Particle-particle correlations, characterized by Glauber’s second-order correlation function, play an important role in the understanding of various phenomena in radio and optical astronomy, quantum and atom optics, particle physics, condensed matter physics, and quantum many-body theory. However, the relevance of such correlations to quantum thermodynamics has so far remained illusive. Here, we propose and investigate a class of quantum many-body thermal machines whose operation is directly enabled by second-order atom-atom correlations in an ultracold atomic gas. More specifically, we study quantum thermal machines that operate in a sudden interaction-quench Otto cycle and utilize a one-dimensional Lieb-Liniger gas of repulsively interacting bosons as the working fluid. The atom-atom correlations in such a gas are different to those of a classical ideal gas, and are a result of the interplay between interparticle interactions, quantum statistics, and thermal fluctuations. We show that operating these thermal machines in the intended regimes, such as a heat engine, refrigerator, thermal accelerator, or heater, would be impossible without such atom-atom correlations. Our results constitute a step forward in the design of conceptually new quantum thermodynamic devices which take advantage of uniquely quantum resources such as quantum coherence, correlations, and entanglement.

DOI
10.21468/scipostphys.18.6.190

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Particle-particle correlations, characterized by Glauber’s second-order correlation function, play an important role in the understanding of various phenomena in radio and optical astronomy, quantum and atom optics, particle physics, condensed matter physics, and quantum many-body theory. However, the relevance of such correlations to quantum thermodynamics has so far remained illusive. Here, we propose and investigate a class of quantum many-body thermal machines whose operation is directly enabled by second-order atom-atom correlations in an ultracold atomic gas. More specifically, we study quantum thermal machines that operate in a sudden interaction-quench Otto cycle and utilize a one-dimensional Lieb-Liniger gas of repulsively interacting bosons as the working fluid. The atom-atom correlations in such a gas are different to those of a classical ideal gas, and are a result of the interplay between interparticle interactions, quantum statistics, and thermal fluctuations. We show that operating these thermal machines in the intended regimes, such as a heat engine, refrigerator, thermal accelerator, or heater, would be impossible without such atom-atom correlations. Our results constitute a step forward in the design of conceptually new quantum thermodynamic devices which take advantage of uniquely quantum resources such as quantum coherence, correlations, and entanglement.
The development of the theory of thermodynamics dates back nearly two centuries, to when the need arose to comprehend and enhance the performance of a novel technology of that era, the heat engine. Extending the classical concepts related to the properties of heat and work into the quantum realm forms the foundation of an emerging field of research known as quantum thermodynamics. To unify the disparate theories of classical thermodynamics and quantum mechanics, a thoroughly developed theoretical framework is necessary. Quantum heat engines provide a fundamental platform for this purpose. Many-body quantum heat engines, in particular, can provide important insights into the potential utilisation of exotic quantum phenomena, such as entanglement and quantum coherence, for building quantum devices that can surpass their classical counterparts in performance. 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Furthermore, to optimize the performance of this interaction-driven quantum Otto cycle in an experimental scenario, we undertake a comprehensive numerical investigation of the dynamics of the system-reservoir coupling during the heat transfer strokes. We model the heat transfer strokes by treating the working substance as an open quantum many-body system that is coupled to a reservoir.After providing an overview of recent advances in the field of quantum thermodynamics and the background theory of 1D Bose gases in Chapters 1 and 2 we present the main results of this thesis in Chapters 3, 4 and 5. In Chapter 3, we study the individual interaction-induced work strokes of the Otto cycle with a weakly interacting 1D Bose gas as the working fluid. We evaluate the instantaneity of the sudden quench, specifically, identifying the minimum timescales required to perform the sudden quench of the interaction strength without invoking the transverse dynamics. Knowledge of these timescales enables us to perform the sudden quench in an experimental setting while ensuring that the system retains its 1D characteristics and the theory of 1D Bose gas is applicable. Additionally, we determine the time scales governing the opposite scenario of near-adiabatic quench which corresponds to minimum irreversible work in the engine cycle and hence maximum efficiency. This will help us benchmark the sudden quench engine's performance compared to a nearly ideal (near-adiabatic) scenario corresponding to maximum efficiency.Next, in Chapter 4, we analyze the heat transfer strokes of the Otto cycle, where the system is coupled to a reservoir. Using the c-field approach, we simulate the coupling dynamics of the system with both finite and infinite-size reservoirs. During the heat transfer stroke of the quantum Otto cycle, we treat the working fluid as an open quantum many-body system that is in thermal and diffusive contact with another quantum many-body system serving as the reservoir. In our real-time dynamical simulations of the engine strokes, we use a c-field approach based on the stochastic projected Gross-Pitaevskii equation. This approach enables us to treat both the working fluid and the hot and cold reservoirs as independent quantum many-body systems with chemical potential and temperature imbalances. To model the heat transfer strokes of such an engine with a finite-size reservoir, we use a tunnel-coupled model of two quasicondensates that treats both the system and the reservoir microscopically. Our analysis incorporates the impact of both finite-time operation and finite-size reservoirs in the engine cycle to gain a deeper understanding of the operational feasibility of such engines. Our results indicate that, in contrast to the common assumption of near-instantaneous heat transfer between the system and the reservoir, the thermalisation time of the system during these heat transfer strokes is non-negligible when compared to the duration of work strokes even in the near-adiabatic quench. This observation holds true even in the case of coupling the system with an infinite reservoir during the heat transfer strokes. Moreover, we demonstrate that for a finite-size reservoir, the initial dynamics (namely fast initial energy transfer) in the tunnel-coupled model of two quasicondensates can be leveraged to reduce the total driving time and hence increase the power output of the engine. Finally, in Chapter 5, we explore an alternate protocol that involves performing chemical work on the system during the heat transfer strokes to boost the efficiency and power output of the quantum Otto engines with a 1D Bose gas as a working fluid. We compare the performance of the sudden quench engine with an engine driven by a near-adiabatic and a finite-time quench of the interaction strength with respect to the longitudinal dynamics. We then conclude the thesis by summarising our main findings and presenting open questions for future work in the final chapter, Chapter 6.
In this thesis, we explore various aspects of equilibrium and nonequilibrium thermodynamics for ultracold atomic gases, with a focus on the experimentally realisable one-dimensional (1D) Bose gas. This is a paradigmatic example of an interacting many-body system, which is integrable in the uniform limit and near-integrable otherwise. We first investigate a quantum thermodynamic Otto cycle driven by a quench of interaction strength of a 1D Bose gas. For the case of a sudden quench in a uniform 1D Bose gas, we demonstrate how the performance of this highly nonequilibrium quantum thermal machine may be expressed in terms of atom-atom correlations. Further, we derive a new Maxwell relation which allows one to express entropy, which is generally difficult to ascertain in quantum systems, in terms of Glauber's local second-order correlation function, which are experimentally measurable. We next perform benchmarks of GHD in order to ascertain the regimes where such a theory may be applied, and then utilize it to investigate the interaction strength-driven quantum Otto cycle in a harmonically trapped 1D Bose gas. However, to realise such an engine in an experimentally realistic manner would require modelling thermalisation with external reservoirs, which is currently beyond the scope of GHD. Yet, the classical ccc-field stochastic-projected Gross-Pitaevskii equation (SPGPE) method is capable of simulating tunnel-coupling pairs of 1D Bose gases in the weakly interacting regime. We therefore utilise this numerical method to simulate the \emph{full} quantum Otto engine cycle, realised through a single working fluid tunnel-coupled to two 1D Bose gases, which constitute the external (hot and cold) reservoirs.
In this paper we study a quantum Otto thermal machine where the working substance is composed of N identical qubits coupled to a single mode of a bosonic field, where the atoms and the field interact with a reservoir, as described by the so-called open Dicke model. By controlling the relevant and experimentally accessible parameters of the model we show that it is possible to build a universal quantum heat machine (UQHM) that can function as an engine, refrigerator, heater, or accelerator. The heat and work exchanges are computed taking into account the growth of the number N of atoms as well as the coupling regimes characteristic of the Dicke model for several ratios of temperatures of the two thermal reservoirs. The analysis of quantum features such as entanglement and second-order correlation shows that these quantum resources do not affect either the efficiency or the performance of the UQHM based on the open Dicke model. In addition, we show that the improvement in both efficiency and coefficient of performance of our UQHM occurs for regions around the critical value of the phase transition parameter of the model.
Advances in experimental control of interacting quantum many-body systems with multiple tunable parameters-such as ultracold atomic gases and trapped ions-are driving rapid progress in quantum thermodynamics and enabling the design of quantum thermal machines. In this work, we utilize a sudden quench approximation as a means to investigate the operation of a quantum thermodynamic Otto cycle in which multiple parameters are simultaneously controllable. The method applies universally to many-body systems where such control is available, and therefore provides general principles for investigating their operation as a working medium in quantum thermal machines. We investigate application of this multi-parameter quench protocol in an experimentally realistic one-dimensional Bose gas, as well as in the transverse-field Ising model. We find that such a multi-parameter Otto cycle, when operating as an engine, outperforms not only its constituent single-parameter Otto cycles in terms of the net work and efficiency, but also the combined net work of its constituent engine cycles when added together independently. We also find that a similar multi-parameter enhancement applies to the coefficient of performance when the Otto cycle operates as a refrigerator.
In this paper we study a quantum Otto thermal machine where the working substance is composed of N identical qubits coupled to a single mode of a bosonic field, where the atoms and the field interact with a reservoir, as described by the so-called open Dicke model. By controlling the relevant and experimentally accessible parameters of the model we show that it is possible to build a universal quantum heat machine (UQHM) that can function as an engine, refrigerator, heater or accelerator. The heat and work exchanges are computed taking into account the growth of the number N of atoms as well as the coupling regimes characteristic of the Dicke model for several ratios of temperatures of the two thermal reservoirs. The analysis of quantum features such as entanglement and second-order correlation shows that these quantum resources do not affect either the efficiency or the performance of the UQHM based on the open Dicke Model. In addition, we show that the improvement in both efficiency and coefficient of performance of our UQHM occurs for regions around the critical value of the phase transition parameter of the model.
Abstract A key focus of designing quantum thermal devices is the potential advantage that can be gleaned from genuine quantum effects when compared to classical devices. The recent experimental realization of the Pauli engine (Koch et al 2023 Nature 621 723)—where energy is extracted via changes in particle statistics as an alternative to conventional heat sources—has opened new avenues of research where quantum statistics can be considered as a thermodynamic resource. In this work we propose hybrid quantum heat engines which can utilize additional strokes that change the single particle statistics between bosonic and fermionic descriptions during the cycle. To accomplish this we consider the 1D Lieb–Liniger gas, in which the s-wave interactions can be tuned between the non-interacting and the hard-core limit, which are described by bosonic and fermionic statistics respectively. We show that by suitably choosing where to implement these statistical strokes during an Otto-like cycle in the quasi-static limit, the efficiency and work output can be significantly enhanced when compared to fully bosonic or fully fermionic engines. Furthermore, in the degenerate regime our engine can operate at the Carnot efficiency, due to the interplay between the different contributions of heat and work induced by the statistical strokes. Finally, we highlight how our thermodynamic cycles can realize other thermal operations, such as refrigerators, promising similar statistical enhancements for a wide range of temperatures.