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arXiv:1612.03582 · Entropy

The Quantum Harmonic Otto Cycle

Ronnie Kosloff, Yair Rezek

Published Mar 23, 2017• 373 citations
arXivHTMLPDF

Abstract

The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.

DOI
10.3390/e19040136

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The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.
Many models of heat engines have been studied with the tools of finite-time thermodynamics and an ensemble of independent quantum systems as the working fluid. Because of their convenient analytical properties, harmonic oscillators are the most frequently used example of a quantum system. We analyze different thermodynamical aspects with the final aim of the optimization of the performance of the engine in terms of the mechanical power provided during a finite-time Otto cycle. The heat exchange mechanism between the working fluid and the thermal reservoirs is provided by the Lindblad formalism. We describe an analytical method to find the limit cycle and give conditions for a stable limit cycle to exist. We explore the power production landscape as the duration of the four branches of the cycle are varied for short times, intermediate times, and special frictionless times. For short times we find a periodic structure with atolls of purely dissipative operation surrounding islands of divergent behavior where, rather than tending to a limit cycle, the working fluid accumulates more and more energy. For frictionless times the periodic structure is gone and we come very close to the global optimal operation. The global optimum is found and interestingly comes with a particular value of the cycle time.
In this work we considered the quantum Otto cycle within an optimization framework. The goal was maximizing the power for a heat engine or maximizing the cooling power for a refrigerator. In the field of finite-time quantum thermodynamics it is common to consider frictionless trajectories since these have been shown to maximize the work extraction during the adiabatic processes. Furthermore, for frictionless cycles, the energy of the system decouples from the other degrees of freedom, thereby simplifying the mathematical treatment. Instead, we considered general limit cycles and we used analytical techniques to compute the derivative of the work production over the whole cycle with respect to the time allocated for each of the adiabatic processes. By doing so, we were able to directly show that the frictionless cycle maximizes the work production, implying that the optimal power production must necessarily allow for some friction generation so that the duration of the cycle is reduced.
The unavoidable irreversible loss of power in a heat engine is found to be of quantum origin. Following thermodynamic tradition, a model quantum heat engine operating in an Otto cycle is analysed, where the working medium is composed of an ensemble of harmonic oscillators and changes in volume correspond to changes in the curvature of the potential well. Equations of motion for quantum observables are derived for the complete cycle of operation. These observables are sufficient to determine the state of the system and with it all thermodynamical variables. Once the external controls are set, the engine settles to a limit cycle. Conditions for optimal work, power and entropy production are derived. At high temperatures and quasistatic operating conditions, the efficiency at maximum power coincides with the endoreversible result . The optimal compression ratio varies from in the quasistatic limit where the irreversibility is dominated by heat conductance to in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions, the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.
Abstract We investigate the optimal performance of the quantum Otto engine and refrigeration cycles of a time-dependent harmonic oscillator under a trade-off figure of merit for both adiabatic and nonadiabatic (sudden-switch) frequency modulations. For heat engines (refrigerators), the chosen trade-off figure of merit is an objective function defined by the product of efficiency (coefficient of performance) and work output (cooling load), thus representing a compromise between them. We obtain analytical expressions for the efficiency and coefficient of performance of the harmonic Otto cycle for the optimal performance of the thermal machine in various operational regimes. Particularly, in the sudden-switch regime, we discuss the implications of the nonadiabatic driving on the performance of the thermal machine under consideration and obtain analytic expressions for the maximum achievable efficiency and coefficient of performance of the harmonic Otto thermal machine. Particularly, we show that the quantum harmonic Otto cycle driven by sudden-switch protocol cannot work as a heat engine or refrigerator in the low-temperature limit. Finally, we show that in the high-temperature limit, the frictional effects give rise to a richer structure of the phase diagram of the harmonic Otto cycle. We identify the parametric regime for the operation of the Otto cycle as a heat engine, refrigerator, accelerator, and heater.
The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio varies from the square root of the temperature ratio in the quasistatic limit where their reversibility is dominated by heat conductance to the temperature ratio to the power of 1/4 in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.
We analyze the performance of a quantum Otto cycle, employing a time-dependent harmonic oscillator as the working fluid undergoing sudden expansion and compression strokes during the adiabatic stages, coupled to a squeezed reservoir. First, we show that the maximum efficiency that our engine can achieve is 1/2 only, which is in contrast with earlier studies claiming unit efficiency under the effect of a squeezed reservoir. Then, in the high-temperature limit, we obtain analytic expressions for the upper bound on the efficiency as well as on the coefficient of performance of the Otto cycle. The obtained bounds are independent of the parameters of the system and depend on the reservoir parameters only. Additionally, with a hot squeezed thermal bath, we obtain an analytic expression for the efficiency at maximum work which satisfies the derived upper bound. Further, in the presence of squeezing in the cold reservoir, we specify an operational regime for the Otto refrigerator otherwise forbidden in the standard case. Finally, we find the cost of creating a squeezed state from the thermal state and show that in order to harvest the benefits of squeezing, it is sufficient to squeeze only one mode of the reservoir in resonance with the transition frequency of the working fluid. Further, we show that when the cost of squeezing is included in the definition of the operational efficiency of the engine, the advantages of squeezing fade away. Still, being purely quantum mechanical fuel in nature, squeezed reservoirs are beneficial in their own way by providing us with more compact energy storage medium or offering effectively high-temperature baths without being actually too hot.