Many models of heat engines have been studied with the tools of finite-time thermodynamics and an ensemble of independent quantum systems as the working fluid. Because of their convenient analytical properties, harmonic oscillators are the most frequently used example of a quantum system. We analyze different thermodynamical aspects with the final aim of the optimization of the performance of the engine in terms of the mechanical power provided during a finite-time Otto cycle. The heat exchange mechanism between the working fluid and the thermal reservoirs is provided by the Lindblad formalism. We describe an analytical method to find the limit cycle and give conditions for a stable limit cycle to exist. We explore the power production landscape as the duration of the four branches of the cycle are varied for short times, intermediate times, and special frictionless times. For short times we find a periodic structure with atolls of purely dissipative operation surrounding islands of divergent behavior where, rather than tending to a limit cycle, the working fluid accumulates more and more energy. For frictionless times the periodic structure is gone and we come very close to the global optimal operation. The global optimum is found and interestingly comes with a particular value of the cycle time.
Many models of heat engines have been studied with the tools of finite-time thermodynamics and an ensemble of independent quantum systems as the working fluid. Because of their convenient analytical properties, harmonic oscillators are the most frequently used example of a quantum system. We analyze different thermodynamical aspects with the final aim of the optimization of the performance of the engine in terms of the mechanical power provided during a finite-time Otto cycle. The heat exchange mechanism between the working fluid and the thermal reservoirs is provided by the Lindblad formalism. We describe an analytical method to find the limit cycle and give conditions for a stable limit cycle to exist. We explore the power production landscape as the duration of the four branches of the cycle are varied for short times, intermediate times, and special frictionless times. For short times we find a periodic structure with atolls of purely dissipative operation surrounding islands of divergent behavior where, rather than tending to a limit cycle, the working fluid accumulates more and more energy. For frictionless times the periodic structure is gone and we come very close to the global optimal operation. The global optimum is found and interestingly comes with a particular value of the cycle time.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.
In this work we considered the quantum Otto cycle within an optimization framework. The goal was maximizing the power for a heat engine or maximizing the cooling power for a refrigerator. In the field of finite-time quantum thermodynamics it is common to consider frictionless trajectories since these have been shown to maximize the work extraction during the adiabatic processes. Furthermore, for frictionless cycles, the energy of the system decouples from the other degrees of freedom, thereby simplifying the mathematical treatment. Instead, we considered general limit cycles and we used analytical techniques to compute the derivative of the work production over the whole cycle with respect to the time allocated for each of the adiabatic processes. By doing so, we were able to directly show that the frictionless cycle maximizes the work production, implying that the optimal power production must necessarily allow for some friction generation so that the duration of the cycle is reduced.
We discuss the limit cycle regime of a finite-time quantum Otto cycle with a frictionless two-dimensional anisotropic Ising model as the working fluid. From Onsager's exact equilibrium solution, we first find optimal parameters for the operational modes of work extraction and cooling for infinitely slow cycles. The equilibrium points in these optimal cycles correspond to different phases of the model, such that the nonequilibrium dynamics during the cycle bypasses the phase transition. Finite-time cycles allow for finite power extraction or cooling currents, but for such cycles, we point out that-already within the regime of weak system-reservoir coupling-energetic changes of the system during dissipative strokes may contain a significant portion of coupling and decoupling control work and should thus not be directly identified with heat. For ultrafast cycles, the required control work spoils performance, such that to maximize work extraction or cooling heat per cycle time, there is an optimal cycle duration. We also find that net-zero-energy transitions may lead to undesired reservoir heating.
We investigate the finite-power performance of quantum heat engines working in the linear response regime where the temperature gradient is small. The engine cycles with working substances of ideal harmonic systems consist of two heat transfer and two adiabatic processes, such as the Carnot cycle, Otto cycle, and Brayton cycle. By analyzing the optimal protocol under maximum power we derive the explicitly analytic expression for the irreversible entropy production, which becomes the low dissipation form in the long duration limit. Assuming the engine to be endoreversible, we derive the universal expression for the efficiency at maximum power, which agrees well with that obtained from the phenomenological heat transfer laws holding in the classical thermodynamics. Through appropriate identification of the thermodynamic fluxes and forces that a linear relation connects, we find that the quantum engines under consideration are tightly coupled, and the universality of efficiency at maximum power is confirmed at the linear order in the temperature gradient.
Quantum heat machines, encompassing heat engines, refrigerators, heaters, and accelerators, represent the forefront of quantum thermodynamics, offering a novel paradigm for converting heat energy into useful mechanical work. Leveraging quantum mechanical principles, these machines promise superior efficiency and performance compared to classical counterparts, with potential applications in renewable energy and quantum computing. This paper investigates a quantum Otto engine operating in both ideal and finite-time scenarios, employing a two-level system interacting with a harmonic oscillator within the framework of the anisotropic quantum Rabi-Stark model (AQRSM) as the working medium. This model is notable for exhibiting both first-order and continuous quantum phase transitions. By focusing on quantum heat engines, our study reveals that these phase transitions critically modulate the efficiency and power of AQRSM-based engines, outperforming quantum engines fueled by working medium with harmonic spectrum. Additionally, we explore the impacts of quantum friction and conduct limit cycle analysis in finite-time operations, providing insights into optimizing quantum heat engines for practical implementation.
The operation of autonomous finite-time quantum heat engines relies on the existence of a stable limit cycle in which the dynamics becomes periodic. The two main questions that naturally arise are therefore whether such a limit cycle will eventually be reached and, once it has, what the state of the system is within the limit cycle. In this paper we show that the application of Floquet's theory to Lindblad dynamics offers clear answers to both questions. By moving to a generalized rotating frame, we show that it is possible to identify a single object, the Floquet Liouvillian, which encompasses all operating properties of the engine. First, its spectrum dictates the convergence to a limit cycle. Second, the state within the limit cycle is precisely its zero eigenstate, therefore reducing the problem to that of determining the steady state of a time-independent master equation. To illustrate the usefulness of this theory, we apply it to a harmonic oscillator subject to a time-periodic work protocol and time-periodic dissipation, an open-system generalization of the Ermakov-Lewis theory. The use of this theory to implement a finite-time Carnot engine subject to continuous frequency modulations is also discussed.