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Physical Review A

Ergotropic Mpemba effect in non-Markovian quantum systems

Yan Li, Wenlin Li, Xingli Li

Published Aug 20, 2025• 13 citations
Publisher

Abstract

The Mpemba effect has garnered growing attention and diverse interpretations within the realm of quantum physics. Recently, Medina et al. [Phys. Rev. Lett. 134, 220402 (2025)] introduced the ergotropic Mpemba effect in quantum batteries governed by Markovian dynamics, highlighting the anomalous phenomenon where batteries in higher ergotropy states discharge faster than those in lower ergotropy states. Building on this foundation, our research proposes an all-optical scheme to realize the ergotropic Mpemba effect in open quantum systems, and further investigates its implications in systems exhibiting non-Markovian dynamics. We find that the ergotropic Mpemba effect persists in non-Markovian dynamics. In the strong non-Markovian regime, prior to the occurrence of the ergotropic Mpemba effect, the ergotropy evolution shows multiple crossings, which we refer to as the quasiergotropic Mpemba effect. Moreover, we derive the analytical solution for the critical point at which the ergotropic Mpemba effect occurs, and we establish the necessary conditions for this effect to emerge. Finally, we propose an experimental scheme based on continuous-variable quantum circuits to realize our theoretical prediction.

DOI
10.1103/5xrr-x2rm

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The Mpemba effect has garnered growing attention and diverse interpretations within the realm of quantum physics. Recently, Medina et al. [Phys. Rev. Lett. 134, 220402 (2025)] introduced the ergotropic Mpemba effect in quantum batteries governed by Markovian dynamics, highlighting the anomalous phenomenon where batteries in higher ergotropy states discharge faster than those in lower ergotropy states. Building on this foundation, our research proposes an all-optical scheme to realize the ergotropic Mpemba effect in open quantum systems, and further investigates its implications in systems exhibiting non-Markovian dynamics. We find that the ergotropic Mpemba effect persists in non-Markovian dynamics. In the strong non-Markovian regime, prior to the occurrence of the ergotropic Mpemba effect, the ergotropy evolution shows multiple crossings, which we refer to as the quasiergotropic Mpemba effect. Moreover, we derive the analytical solution for the critical point at which the ergotropic Mpemba effect occurs, and we establish the necessary conditions for this effect to emerge. Finally, we propose an experimental scheme based on continuous-variable quantum circuits to realize our theoretical prediction.
The quantum Mpemba effect is a counterintuitive phenomenon in which a state initially farther from equilibrium relaxes more rapidly than one that starts nearer to equilibrium. In the context of finite-dimensional quantum batteries interacting with an environment, we introduce the notion of an ergotropic Mpemba crossing (EMC), defined by the intersection of ergotropy trajectories during the dynamics. For qubit batteries subjected to amplitude damping noise, we derive a condition for the occurrence of EMC in terms of the relative coherence of the initial states and fully characterize the region of state space that exhibits EMC with respect to a fixed reference state. Interestingly, our analysis reveals that under anisotropic Pauli noise, the emergence of EMC is jointly governed by the coherence and the energy of the initial states. To elucidate the physical origin of EMC, we decompose ergotropy into coherent and incoherent contributions and show that, in qubit systems, the coherent component plays a crucial role for EMC, an observation that strikingly does not extend to three-level batteries, providing the dimensional role in observing EMC. Further, by extending our analysis to non-Markovian environments, we demonstrate that, unlike the Markovian case, non-Markovian dynamics can give rise to multiple Mpemba crossings, with the total number of crossings always being odd. Also, we propose a set-up showing that EMC can be utilized to suppress the ergotropic loss, occurred due to dissipation. Moreover, analyzing the connection between the EMC and the conventional state Mpemba effect reveals that, for qubits, an EMC necessarily entails a state Mpemba crossing, while this correspondence breaks down for qutrits, where EMCs may arise without any state Mpemba crossing.
Quantum Mpemba effect describes an anomalous phenomenon of accelerated relaxation which is of fundamental interest in the field of nonequilibrium thermodynamics. Conventional theories on this phenomenon strongly rely on the Born-Markovian approximation resulting in a Lindblad-type master equation whose evolution is governed by a Liouvillian superoperator. It has been demonstrated that exceptional points of the Liouvillian superoperator can induce the Mpemba effect in Markovian regimes. Moving beyond this Markovian limit, we here propose a mechanism for realizing the quantum Mpemba effect in a general non-Markovian relaxation process by means of non-Markovian exceptional points. We verify the feasibility of this mechanism within a dissipative quantum harmonic oscillator model, which is exactly solvable and experimentally practical. Providing new insight into the interesting non-equilibrium dynamics, our work paves a way to accelerate the transfer of energy and information in quantum systems.
Anomalous thermal relaxation is ubiquitous in nonequilibrium statistical mechanics. An emblematic example of this is the Mpemba effect, where an initially "hot" system cools faster than an initially "cooler" one. This effect has recently been studied in a variety of different classical and quantum settings. In this Letter, we find a novel signature of the Mpemba effect in the context of quantum batteries. We identify situations where batteries in higher charge states can discharge faster than less charged states. Specifically, we consider a quantum battery encoded in a single bosonic mode that is charged using unitary Gaussian operations. We show that the ergotropy, used here as a dynamical indicator of the energy stored in the battery, can be recast as a phase space relative entropy between the system's state and the unitarily connected passive state, at each time. Our formalism allows us to compute the ergotropy analytically under dissipative dynamics and allows us to understand the conditions which give rise to a Mpemba effect. We also find situations where two batteries charged to the same value using different operations can discharge at different rates.
Since its rediscovery in the twentieth century, the Mpemba effect, where a far-from-equilibrium state may relax faster than a state closer to equilibrium, has been extensively studied in classical systems and has recently received attention in quantum systems. Many theories explaining this counter-intuitive behavior in classical systems rely on memory effects. However, in quantum systems, the relation between the Mpemba effect and memory has remained unexplored. In this Letter, we consider general non-Markovian open quantum systems and reveal new classes of quantum Mpemba effects, with no analog in Markovian quantum dynamics. Generically, open quantum dynamics possess a finite memory time and a unique steady state. Because of non-Markovian dynamics, even if the system is initialized in the steady state it can take a long time to relax back. We find other initial states that reach the steady state much faster. Most notably, we demonstrate that there can be an initial state in which the system reaches the steady state within the finite memory time itself, giving the fastest possible relaxation to stationarity. We verify the effect for quantum dot systems coupled to electronic reservoirs in equilibrium and nonequilibrium setups at weak, intermediate and strong coupling. Our Letter provides new insights into the rich physics underlying accelerated relaxation in quantum systems.
The quantum Mpemba effect concerns with anomalous relaxation of quantum states that evolves either under unitary or non-unitary dynamics. In the context of open quantum systems, while most studies focus on quantum states evolving under completely positive trace-presing dynamics described by the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) master equation, we demonstrate that an analogous effect can arise at the level of operators. In particular, we show that operators that evolves under the adjoint Liouvillian -- despite not being a trace-preserving map -- can still exhibit a genuine Mpemba effect. We derive general conditions under which this phenomenon can occur and validate our predictions for three different open quantum setups. Our results broaden the scope of the Mpemba effect in quantum systems and provide a framework for controlling the relaxation of physically relevant observables.
In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.