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arXiv:2512.13509

Some Mechanisms for the Quantum Mpemba Effect

Rodrigo F. Saliba, Vitor M. Pereira, Raphael C. Drumond

quant-phSubmitted Dec 15, 2025• Announced Dec 16, 2025• 0 citations• Revised Oct 28, 2026 (v3)
v1 · Dec 15, 2025v2 · May 1, 2026v3 · Oct 28, 2026
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Abstract

In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.

Comments
11 pages, 13 figures

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In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.
Since its rediscovery in the twentieth century, the Mpemba effect, where a far-from-equilibrium state may relax faster than a state closer to equilibrium, has been extensively studied in classical systems and has recently received attention in quantum systems. Many theories explaining this counter-intuitive behavior in classical systems rely on memory effects. However, in quantum systems, the relation between the Mpemba effect and memory has remained unexplored. In this Letter, we consider general non-Markovian open quantum systems and reveal new classes of quantum Mpemba effects, with no analog in Markovian quantum dynamics. Generically, open quantum dynamics possess a finite memory time and a unique steady state. Because of non-Markovian dynamics, even if the system is initialized in the steady state it can take a long time to relax back. We find other initial states that reach the steady state much faster. Most notably, we demonstrate that there can be an initial state in which the system reaches the steady state within the finite memory time itself, giving the fastest possible relaxation to stationarity. We verify the effect for quantum dot systems coupled to electronic reservoirs in equilibrium and nonequilibrium setups at weak, intermediate and strong coupling. Our Letter provides new insights into the rich physics underlying accelerated relaxation in quantum systems.
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The quantum Mpemba effect (QME) describes the counterintuitive phenomenon in which a system farther from equilibrium reaches steady state faster than one closer to equilibrium. However, ambiguity in defining a suitable distance measure between quantum states has led to varied interpretations across different contexts. Here we propose the intrinsic quantum Mpemba effect (IQME), defined using the trajectory length traced by the quantum state as a more appropriate measure of distance--distinct from previous trajectory-independent metrics. By treating quantum states as points in a Riemannian space defined by statistical distance, the trajectory length emerges as a more natural and accurate characterization of the counterintuitive dynamics, drawing an analogy to the classical Brachistochrone problem. We demonstrate the existence of IQME in Markovian systems and extend its definition to quantum circuits, thereby establishing a unified framework applicable to both open and closed systems. Notably, we observe an IQME in a U(1)U(1)U(1)-symmetric circuit, offering new insights into the rates of quantum thermalization for different initial states. This work deepens our understanding of quantum state evolution and lays the foundation for accurately capturing novel quantum dynamical behaviour.
Abstract Non-equilibrium dynamics have become a central research focus, exemplified by the counterintuitive Mpemba effect where initially hotter systems can cool faster than colder ones. Studied extensively in both classical and quantum regimes, this phenomenon reveals diverse and complex behaviors across different systems. This review provides a concise overview of the quantum Mpemba effect (QME), specifically emphasizing its connection to symmetry breaking and restoration in closed quantum many-body systems. We begin by outlining the classical Mpemba effect and its quantum counterparts, summarizing key findings. Subsequently, we introduce entanglement asymmetry and charge variance as key metrics for probing the QME from symmetry perspectives. Leveraging these tools, we analyze the early- and late-time dynamics of these quantities under Hamiltonian evolution and random unitary circuits. We conclude by discussing significant challenges and promising avenues for future research.
We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.
The quantum Mpemba effect (QMpE) describes an anomalous thermalization phenomenon in which quantum states initially far from equilibrium can approach thermal equilibrium faster than states that begin closer to it. While this effect has been extensively studied in various frameworks, its practical implications for quantum information processing remain largely unexplored. We investigate the relationship between QMpE and quantum thermometry, focusing on non-equilibrium scenarios where measurements are performed during early-stage thermalization. In a Markovian model, we rigorously prove that the initial states that are optimal for thermometry exhibit QMpE with high probability and thermalize faster than most initial states. Our results reveal a fundamental connection between quantum thermodynamics and thermometry, suggesting that QMpE can be harnessed to enhance temperature estimation with quantum probes.