We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.
We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.
Ergodicity breaking and slow relaxation are intriguing aspects of nonequilibrium dynamics both in classical and quantum settings. These phenomena are typically associated with phase transitions, e.g., the emergence of metastable regimes near a first-order transition or scaling dynamics in the vicinity of critical points. Despite being of fundamental interest the associated divergent timescales are a hindrance when trying to explore steady-state properties. Here we show that the relaxation dynamics of Markovian open quantum systems can be accelerated exponentially by devising an optimal unitary transformation that is applied to the quantum system immediately before the actual dynamics. This initial "rotation" is engineered in such a way that the state of the quantum system no longer excites the slowest decaying dynamical mode. We illustrate our idea-which is inspired by the so-called Mpemba effect, i.e., water freezing faster when initially heated up-by showing how to achieve an exponential speeding-up in the convergence to stationarity in Dicke models, and how to avoid metastable regimes in an all-to-all interacting spin system.
Quantum Mpemba effect occurs when a quantum system, residing far away from the steady state, relaxes faster than a relatively nearer state. We look for the presence of this highly counterintuitive effect in the relaxation dynamics of the operators within the open quantum system setting. Since the operators evolve under a non-trace preserving map, the trace distance of an operator is not a monotonically decaying function of time, unlike its quantum state counterpart. Consequently, the trace distance can not serve as a reliable measure for detecting the Mpemba effect in operator dynamics. We circumvent this problem by defining a \textit{dressed} distance between operators that decays monotonically with time, enabling a generalized framework to explore the Mpemba-like effect for operators. Applying the formalism to various open quantum system settings, we find that, interestingly, in the single qubit case, only accelerated relaxation of operators is possible, while genuine Mpemba-like effects emerge in higher-dimensional systems such as qutrits and beyond. Furthermore, we demonstrate the existence of Mpemba-like effects in nonlocal, non-equilibrium operators, such as current, in a double-quantum-dot setup. Our results, besides offering fundamental insight about the occurrence of the Mpemba-like effect under non-trace preserving dynamics, open avenues for new experimental studies where quicker relaxation of observables could be of significant interest.
Ergodicity breaking and slow relaxation are intriguing aspects of nonequilibrium dynamics both in classical and quantum settings. These phenomena are typically associated with phase transitions, e.g., the emergence of metastable regimes near a first-order transition or scaling dynamics in the vicinity of critical points. Despite being of fundamental interest the associated divergent timescales are a hindrance when trying to explore steady-state properties. Here we show that the relaxation dynamics of Markovian open quantum systems can be accelerated exponentially by devising an optimal unitary transformation that is applied to the quantum system immediately before the actual dynamics. This initial "rotation"is engineered in such a way that the state of the quantum system no longer excites the slowest decaying dynamical mode. We illustrate our idea - which is inspired by the so-called Mpemba effect, i.e., water freezing faster when initially heated up - by showing how to achieve an exponential speeding-up in the convergence to stationarity in Dicke models, and how to avoid metastable regimes in an all-to-all interacting spin system.
The Mpemba effect, where a state farther from equilibrium relaxes faster than one closer to it, is a striking phenomenon in both classical and quantum systems. In open quantum systems, however, the quantum Mpemba effect (QME) typically occurs only for specifically chosen initial states, which limits its universality. Here we present a general and experimentally feasible strategy to realize both QME and anti-QME. By applying a temporary bond-dissipation quench, we selectively suppresses or enhances slow relaxation modes, thereby reshaping relaxation pathways independently of both the system and the initial state. We demonstrate this mechanism in systems with dephasing and boundary dissipation, and outline feasible cold-atom implementations. Our results establish controllable dissipation as a versatile tool for quantum control, accelerated relaxation, and efficient nonequilibrium protocols.
The Mpemba effect refers to the counterintuitive situation in which a system initially farther from equilibrium can relax faster than one that starts closer to it. In quantum systems, the effect is enriched by the presence of coherent dynamics, dissipation, and metastable manifolds associated with long-lived Liouvillian modes. Here we demonstrate a giant Mpemba effect in open quantum systems, where relaxation can be either hyper-accelerated or dramatically slowed depending on the initial state. We focus on weakly-coupled particle-conserving bosonic networks, each of which independently relaxes rapidly to a unique stationary state. When a weak coherent interaction is introduced, the composite system typically develops slow metastable modes and a hierarchy of relaxation timescales. We show that by tailoring the interaction Hamiltonian, these slow modes can be effectively suppressed for a broad class of initial states satisfying a minimal global requirement, enabling ultrafast relaxation even when the system starts far from equilibrium. Conversely, other initial states-sometimes arbitrarily close to the stationary state-may remain trapped in the metastable manifold and decay anomalously slowly. This mechanism provides a general route to engineer giant Mpemba effects, offering new possibilities for controlling dissipative dynamics, accelerating state preparation, and manipulating relaxation processes in complex quantum devices.
In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.