The quantum Mpemba effect concerns with anomalous relaxation of quantum states that evolves either under unitary or non-unitary dynamics. In the context of open quantum systems, while most studies focus on quantum states evolving under completely positive trace-presing dynamics described by the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) master equation, we demonstrate that an analogous effect can arise at the level of operators. In particular, we show that operators that evolves under the adjoint Liouvillian -- despite not being a trace-preserving map -- can still exhibit a genuine Mpemba effect. We derive general conditions under which this phenomenon can occur and validate our predictions for three different open quantum setups. Our results broaden the scope of the Mpemba effect in quantum systems and provide a framework for controlling the relaxation of physically relevant observables.
The quantum Mpemba effect concerns with anomalous relaxation of quantum states that evolves either under unitary or non-unitary dynamics. In the context of open quantum systems, while most studies focus on quantum states evolving under completely positive trace-presing dynamics described by the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) master equation, we demonstrate that an analogous effect can arise at the level of operators. In particular, we show that operators that evolves under the adjoint Liouvillian -- despite not being a trace-preserving map -- can still exhibit a genuine Mpemba effect. We derive general conditions under which this phenomenon can occur and validate our predictions for three different open quantum setups. Our results broaden the scope of the Mpemba effect in quantum systems and provide a framework for controlling the relaxation of physically relevant observables.
Quantum Mpemba effect occurs when a quantum system, residing far away from the steady state, relaxes faster than a relatively nearer state. We look for the presence of this highly counterintuitive effect in the relaxation dynamics of the operators within the open quantum system setting. Since the operators evolve under a non-trace preserving map, the trace distance of an operator is not a monotonically decaying function of time, unlike its quantum state counterpart. Consequently, the trace distance can not serve as a reliable measure for detecting the Mpemba effect in operator dynamics. We circumvent this problem by defining a \textit{dressed} distance between operators that decays monotonically with time, enabling a generalized framework to explore the Mpemba-like effect for operators. Applying the formalism to various open quantum system settings, we find that, interestingly, in the single qubit case, only accelerated relaxation of operators is possible, while genuine Mpemba-like effects emerge in higher-dimensional systems such as qutrits and beyond. Furthermore, we demonstrate the existence of Mpemba-like effects in nonlocal, non-equilibrium operators, such as current, in a double-quantum-dot setup. Our results, besides offering fundamental insight about the occurrence of the Mpemba-like effect under non-trace preserving dynamics, open avenues for new experimental studies where quicker relaxation of observables could be of significant interest.
The quantum Mpemba effect (QMPE), an anomalous relaxation phenomenon, has been demonstrated in both closed and open Hermitian quantum systems. While some studies have linked the QMPE to Liouvillian exceptional points---non-Hermitian features emerged at the Liouvillian level---in open Hermitian quantum systems, it remains largely unexplored whether the QMPE can occur in intrinsic non-Hermitian systems, where non-Hermiticity is inherent at the Hamiltonian level. Here, we demonstrate unequivocally the occurrence of QMPE in experimentally realizable parity-time symmetric qubit systems immersed in a bosonic bath. Using established quantifiers for QMPE, we show numerically that the QMPE persists across parameter regimes both near and far from Hamiltonian and Liouvillian exceptional points, but disappears entirely when a Hermitian Hamiltonian is restored. Interestingly, neither Hamiltonian nor Liouvillian exceptional points demarcate the boundaries of the QMPE regime. To complement numerical results, we develop an analytical description based on a long-time approximation of the relaxation dynamics of quantifiers. This approach allows us to decipher the number of intersections between two dynamical trajectories of quantifier starting from two initial conditions in the validity regime of the long-time approximation, thereby providing additional information that delineates the parameter regimes supporting the genuine QMPE. We further demonstrate the robustness of QMPE against increasing the number of qubits and dephasing effect. Our findings not only broaden the scope of the QMPE but also suggest its intricate interplay with non-Hermitian features beyond exceptional points.
Quantum Mpemba effect describes an anomalous phenomenon of accelerated relaxation which is of fundamental interest in the field of nonequilibrium thermodynamics. Conventional theories on this phenomenon strongly rely on the Born-Markovian approximation resulting in a Lindblad-type master equation whose evolution is governed by a Liouvillian superoperator. It has been demonstrated that exceptional points of the Liouvillian superoperator can induce the Mpemba effect in Markovian regimes. Moving beyond this Markovian limit, we here propose a mechanism for realizing the quantum Mpemba effect in a general non-Markovian relaxation process by means of non-Markovian exceptional points. We verify the feasibility of this mechanism within a dissipative quantum harmonic oscillator model, which is exactly solvable and experimentally practical. Providing new insight into the interesting non-equilibrium dynamics, our work paves a way to accelerate the transfer of energy and information in quantum systems.
We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
These notes are a short introduction to the mathematical theory of open quantum systems. They are meant to serve as an entry point into a broad research area which has applications across the quantum sciences dealing with systems subjected to external noise. The guiding idea is to let the key structures of the theory emerge from a concrete model. By working through the dissipative Jaynes-Cummings model the reader will dis- cover explicitly how irreversible dynamics arises from a unitary system-reservoir evolution. The notions of the continuous mode limit, correlation functions, spectral density appear in a natural manner and lead to the evolution equation of the open system in form of a master equation. This sets the stage for the more general analysis of completely positive, trace preserving (CPTP) maps and the study of quantum dynamical semigroups. We motivate and prove the Kraus representation theorem, the dilation theorem and the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) theorem. Working through the exercises (for which full solutions are supplied) will reinforce the ideas introduced in the main text.