Anomalous thermal relaxation is ubiquitous in nonequilibrium statistical mechanics. An emblematic example of this is the Mpemba effect, where an initially "hot" system cools faster than an initially "cooler" one. This effect has recently been studied in a variety of different classical and quantum settings. In this Letter, we find a novel signature of the Mpemba effect in the context of quantum batteries. We identify situations where batteries in higher charge states can discharge faster than less charged states. Specifically, we consider a quantum battery encoded in a single bosonic mode that is charged using unitary Gaussian operations. We show that the ergotropy, used here as a dynamical indicator of the energy stored in the battery, can be recast as a phase space relative entropy between the system's state and the unitarily connected passive state, at each time. Our formalism allows us to compute the ergotropy analytically under dissipative dynamics and allows us to understand the conditions which give rise to a Mpemba effect. We also find situations where two batteries charged to the same value using different operations can discharge at different rates.
Anomalous thermal relaxation is ubiquitous in nonequilibrium statistical mechanics. An emblematic example of this is the Mpemba effect, where an initially "hot" system cools faster than an initially "cooler" one. This effect has recently been studied in a variety of different classical and quantum settings. In this Letter, we find a novel signature of the Mpemba effect in the context of quantum batteries. We identify situations where batteries in higher charge states can discharge faster than less charged states. Specifically, we consider a quantum battery encoded in a single bosonic mode that is charged using unitary Gaussian operations. We show that the ergotropy, used here as a dynamical indicator of the energy stored in the battery, can be recast as a phase space relative entropy between the system's state and the unitarily connected passive state, at each time. Our formalism allows us to compute the ergotropy analytically under dissipative dynamics and allows us to understand the conditions which give rise to a Mpemba effect. We also find situations where two batteries charged to the same value using different operations can discharge at different rates.
The Mpemba effect has garnered growing attention and diverse interpretations within the realm of quantum physics. Recently, Medina et al. [Phys. Rev. Lett. 134, 220402 (2025)] introduced the ergotropic Mpemba effect in quantum batteries governed by Markovian dynamics, highlighting the anomalous phenomenon where batteries in higher ergotropy states discharge faster than those in lower ergotropy states. Building on this foundation, our research proposes an all-optical scheme to realize the ergotropic Mpemba effect in open quantum systems, and further investigates its implications in systems exhibiting non-Markovian dynamics. We find that the ergotropic Mpemba effect persists in non-Markovian dynamics. In the strong non-Markovian regime, prior to the occurrence of the ergotropic Mpemba effect, the ergotropy evolution shows multiple crossings, which we refer to as the quasiergotropic Mpemba effect. Moreover, we derive the analytical solution for the critical point at which the ergotropic Mpemba effect occurs, and we establish the necessary conditions for this effect to emerge. Finally, we propose an experimental scheme based on continuous-variable quantum circuits to realize our theoretical prediction.
The quantum Mpemba effect is a counterintuitive phenomenon in which a state initially farther from equilibrium relaxes more rapidly than one that starts nearer to equilibrium. In the context of finite-dimensional quantum batteries interacting with an environment, we introduce the notion of an ergotropic Mpemba crossing (EMC), defined by the intersection of ergotropy trajectories during the dynamics. For qubit batteries subjected to amplitude damping noise, we derive a condition for the occurrence of EMC in terms of the relative coherence of the initial states and fully characterize the region of state space that exhibits EMC with respect to a fixed reference state. Interestingly, our analysis reveals that under anisotropic Pauli noise, the emergence of EMC is jointly governed by the coherence and the energy of the initial states. To elucidate the physical origin of EMC, we decompose ergotropy into coherent and incoherent contributions and show that, in qubit systems, the coherent component plays a crucial role for EMC, an observation that strikingly does not extend to three-level batteries, providing the dimensional role in observing EMC. Further, by extending our analysis to non-Markovian environments, we demonstrate that, unlike the Markovian case, non-Markovian dynamics can give rise to multiple Mpemba crossings, with the total number of crossings always being odd. Also, we propose a set-up showing that EMC can be utilized to suppress the ergotropic loss, occurred due to dissipation. Moreover, analyzing the connection between the EMC and the conventional state Mpemba effect reveals that, for qubits, an EMC necessarily entails a state Mpemba crossing, while this correspondence breaks down for qutrits, where EMCs may arise without any state Mpemba crossing.
The highly complicated nature of far from equilibrium systems can lead to a complete breakdown of the physical intuition developed in equilibrium. A famous example of this is the Mpemba effect, which states that nonequilibrium states may relax faster when they are further from equilibrium or, put another way, hot water can freeze faster than warm water. Despite possessing a storied history, the precise criteria and mechanisms underpinning this phenomenon are still not known. Here, we study a quantum version of the Mpemba effect that takes place in closed many-body systems with a U(1) conserved charge: in certain cases a more asymmetric initial configuration relaxes and restores the symmetry faster than a more symmetric one. In contrast to the classical case, we establish the criteria for this to occur in arbitrary integrable quantum systems using the recently introduced entanglement asymmetry. We describe the quantum Mpemba effect in such systems and relate the properties of the initial state, specifically its charge fluctuations, to the criteria for its occurrence. These criteria are expounded using exact analytic and numerical techniques in several examples, a free fermion model, the Rule 54 cellular automaton, and the Lieb-Liniger model.
The Mpemba effect, where a hotter system cools faster than a colder one under otherwise identical conditions, has been extensively studied in classical systems. In this work, we present the quantum analogue of the Mpemba effect using a dissipative qubit, which is referred to as the canonical quantum Mpemba effect. We demonstrate that, under the identical conditions, the relaxation dynamics of a qubit initialized in a thermal state with a higher temperature can be exponentially faster than those of a colder thermal state. Strikingly, this acceleration is determined solely by the initial temperature of the system, independent of other parameters. The relaxation is confirmed to be a genuine cooling process via the effective steady state temperature, mirroring its classical counterpart. Last, we propose a practical classical quantum hybrid algorithmic quantum circuit to realize this effect using superconducting qubits experimentally.
The Mpemba effect (ME)—where hot systems cool faster than colder ones—has intrigued both classical and quantum thermodynamics. Compared to classical systems, quantum systems add complexity due to quantum correlations. Recent works have explored anomalous relaxation and Mpemba-like effects in several quantum systems, considering isolated systems at zero temperature or open systems in contact with reservoirs under Markovian or non-Markovian dynamics. However, these models typically assume an initial unentangled system–bath state, overlooking the role of initial system–environment correlations. Here we propose a type of quantum ME, distinct from the strong ME, originating solely from initial system–bath entanglement. It is shown that the degree of initial entanglement significantly influences the early relaxation dynamics, with certain conditions causing backflow and retarded thermalization. As an example, we investigate the spontaneous emission of a two-level atom in a photonic waveguide at zero temperature, where an initial atom-photon entangled state results in delayed relaxation and a pronounced ME. These findings highlight the crucial role of quantum correlations in thermalization processes and open new avenues for identifying and engineering quantum Mpemba phenomena. Controlling relaxation dynamics through system–environment entanglement may have potential applications in quantum thermal machines, state initialization protocols, and quantum information processing, where precise control over thermalization is essential.
We demonstrate the quantum Mpemba effect in a quantum dot coupled to two reservoirs, described by the Anderson model. We show that the system temperatures starting from two different initial values (hot and cold) cross each other at finite time (and thereby reverse their identities; i.e., hot becomes cold and vice versa) to generate thermal quantum Mpemba effect. The slowest relaxation mode believed to play the dominating role in Mpemba effect in Markovian systems does not contribute to such anomalous relaxation in the present model. In this connection, our analytical result provides necessary condition for producing quantum Mpemba effect in the density matrix elements of the quantum dot, as a combined effect of the remaining relaxation modes.