Splitting of photoluminescent emission from nitrogen–vacancy centers in diamond induced by ion-damage-induced stress
P. Olivero, Federico Bosia, Barbara A. Fairchild +4 more
We report a systematic investigation on the spectral splitting of negatively charged, nitrogen–vacancy (NV − ) photoluminescent emission in single-crystal diamond induced by strain engineering. The stress fields arise from MeV ion-induced conversion of diamond to amorphous and graphitic material in regions proximal to the centers of interest. In low-nitrogen sectors of a high-pressure–high-temperature diamond, clearly distinguishable spectral components in the NV − emission develop over a range of ∼4.8 THz corresponding to distinct alignment of sub-ensembles which were mapped with micron spatial resolution. This method provides opportunities for the creation and selection of aligned NV − centers for ensemble quantum information protocols.
arXiv:1302.2539•New Journal of Physics•Apr 17, 2013•31 citations