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Journal of Quantitative Spectroscopy and Radiative Transfer

Spectral profiles of strongly saturated resonance transitions in high-density rb vapor

Vladimir A. Sautenkov, Sergey A. Saakyan, Andrey A. Bobrov, Nikita Morozov, Boris B. Zelener

Published Nov 21, 2021• 6 citations
Publisher
DOI
10.1016/j.jqsrt.2021.108007

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A new method and its principle are presented for measuring the each component gas pressures in Rubidium (Rb) by the analysis of absorption spectral profile. The experiment system is set up to obtain Rb absorption spectra. And then each component gas pressures in atom vapor cell is estimated. First, the relationships between transmittance of probe light, atom density and absorption cross section are introduced, and the factors which influence the absorption spectral profile and methods to measure gas pressures are given. Second, the frequency-dependence curves of transmittance and the absorption spectra are obtained through tuning the laser frequency through the Rb D1 transition. Finally, the gas pressures of Rb, N2 and He are achieved, through fitting absorption spectral profile referring to half-width and minimum transmittance value of absorption spectra. The experiment results show that gas pressures in Rb atom vapor cell can be accurately measured by absorption spectrometric methods, which will be helpful for the following study of atom vapor cell. The gas pressures of N2 and He measured by the experiments are well matched with design values. The Rb gas pressure is 30%~50% less than the saturated vapor pressure and the suppression may be due to the adsorption of the cell surfaces coated with octadecyltrichlorosilane (OTS) film.
Abstract In strong magnetic fields (0.1–6 kG), many atomic lines closely spaced in frequency appear in the absorption spectrum of alkali metal vapors. Due to the small frequency interval between them and the Doppler broadening of the atomic lines, they are overlapped. For spectral separation and study of individual atomic lines, it is necessary to ensure their spectral narrowing. It is shown that this can be done using the saturated absorption method in an atomic vapor contained in a 30 μm-thick cell filled with Rb vapor. All 10 atomic transitions of Rb D1 line are spectrally very well resolved in the second derivative of the saturated absorption spectrum. Complete resolution of atomic transitions makes this method useful for the determination of a wide range of magnetic fields. The theoretical curves describe the experimental results very well.