Topological phases are quantum phases of matter that appear close to absolute zero temperature. In contrast to commonly known condensed phases of matter, such as a magnet or a superconductor, distinct topological phases may have the same symmetry. Instead, these phases are distinguished by the topology of the electronic wavefunction. Already the single-particle excitations described by band theory in an insulator or a metal or by Bogoliubov-de Gennes theory in a superconductor may have novel anomalous properties associated to their topology. This topological band theory is the subject of this thesis. We aim towards identifying the anomalous boundary and defect states associated to the topology of the band structure in crystalline insulators and superconductors. Furthermore, we determine criteria to easily identify the topological phases from the band structure of a given insulator or superconductor. In Chapter 2 we show that crystalline topological insulators and superconductors may host anomalous gapless or in-gap excitations on corners of a two-dimensional crystal or hinges of a three-dimensional crystal. These topological phases are called "second-order" according to the codimension "2" of their anomalous boundary states. We discuss the precise conditions for their appearance and when they can be linked to the bulk topology. Our discussion includes mirror, twofold-rotation and inversion as crystalline symmetries. In Chapter 3 we discuss the appearance of anomalous gapless or ingap states at defects in a crystalline insulator or superconductor. In particular, we link the existence of anomalous states at disclinations -- lattice defects that violate a rotation symmetry only locally -- to second-order topological crystalline phases. As a side product, we identify the possible contributions of other topological phases to the disclination anomaly. The results of this chapter allow to determine precisely how the disclination anomaly is linked to the bulk topology. In Chapter 4 we present how to construct "symmetry-based indicators" for topological superconductors that admit a description within the Bogoliubov-de Gennes framework. Symmetry-based indicators are necessary criteria for a given Bogoliubov-de Gennes Hamiltonian to realize a topological crystalline phase with anomalous boundary exitations. These criteria are formulated in terms of data from a small set of high-symmetry momenta only. Our approach guarantees to extract the maximal information on the anomalous boundary exitations that can be extracted from a point-wise evaluation of the Bogoliubov-de Gennes Hamiltonian. In the limit of weak superconducting pairing, our criteria can be formulated in terms of data from the normal-state band structure alone.
Topological phases are quantum phases of matter that appear close to absolute zero temperature. In contrast to commonly known condensed phases of matter, such as a magnet or a superconductor, distinct topological phases may have the same symmetry. Instead, these phases are distinguished by the topology of the electronic wavefunction. Already the single-particle excitations described by band theory in an insulator or a metal or by Bogoliubov-de Gennes theory in a superconductor may have novel anomalous properties associated to their topology. This topological band theory is the subject of this thesis. We aim towards identifying the anomalous boundary and defect states associated to the topology of the band structure in crystalline insulators and superconductors. Furthermore, we determine criteria to easily identify the topological phases from the band structure of a given insulator or superconductor. In Chapter 2 we show that crystalline topological insulators and superconductors may host anomalous gapless or in-gap excitations on corners of a two-dimensional crystal or hinges of a three-dimensional crystal. These topological phases are called "second-order" according to the codimension "2" of their anomalous boundary states. We discuss the precise conditions for their appearance and when they can be linked to the bulk topology. Our discussion includes mirror, twofold-rotation and inversion as crystalline symmetries. In Chapter 3 we discuss the appearance of anomalous gapless or ingap states at defects in a crystalline insulator or superconductor. In particular, we link the existence of anomalous states at disclinations -- lattice defects that violate a rotation symmetry only locally -- to second-order topological crystalline phases. As a side product, we identify the possible contributions of other topological phases to the disclination anomaly. The results of this chapter allow to determine precisely how the disclination anomaly is linked to the bulk topology. In Chapter 4 we present how to construct "symmetry-based indicators" for topological superconductors that admit a description within the Bogoliubov-de Gennes framework. Symmetry-based indicators are necessary criteria for a given Bogoliubov-de Gennes Hamiltonian to realize a topological crystalline phase with anomalous boundary exitations. These criteria are formulated in terms of data from a small set of high-symmetry momenta only. Our approach guarantees to extract the maximal information on the anomalous boundary exitations that can be extracted from a point-wise evaluation of the Bogoliubov-de Gennes Hamiltonian. In the limit of weak superconducting pairing, our criteria can be formulated in terms of data from the normal-state band structure alone.
We study a link between the ground-state topology and the topology of the lattice via the presence of anomalous states at disclinations -- topological lattice defects that violate a rotation symmetry only locally. We first show the existence of anomalous disclination states, such as Majorana zero-modes or helical electronic states, in second-order topological phases by means of Volterra processes. Using the framework of topological crystals to construct d-dimensional crystalline topological phases with rotation and translation symmetry, we then identify all contributions to (d-2)-dimensional anomalous disclination states from weak and first-order topological phases. We perform this procedure for all Cartan symmetry classes of topological insulators and superconductors in two and three dimensions and determine whether the correspondence between bulk topology, boundary signatures, and disclination anomaly is unique.
The imposition of crystalline symmetries is known to lead to a rich variety of insulating and superconducting topological phases. These include higher-order topological phases and obstructed atomic limits with and without filling anomalies. We here comprehensively classify such topological crystalline phases (TCPs) with mirror, twofold rotation, and inversion symmetries in the presence of disorder that preserves the crystalline symmetry on average. We find that the inclusion of disorder leads to a simplification of the classification in comparison to the clean case. We also find that, while clean TCPs evade a general bulk-boundary principle, disordered TCPs admit a complete bulk-boundary correspondence, according to which (bulk) topological phases are topologically equivalent if and only if they have the same anomalous boundary states and filling anomaly. We corroborate the stability of disordered TCPs by way of field-theoretic, numerical, and symmetry-based analyses in various case studies. While the boundary signatures of most disordered TCPs are similar to their clean counterparts, the addition of disorder to certain mirror-symmetric TCPs results in novel higher-order statistical topological phases, in which zero-energy hinge states have critical wave-function statistics, while remaining protected from Anderson localization.
The classification of distinct phases of matter is a central theme in condensed matter physics. A phase of matter can be viewed as an equivalence class of physical states that share a certain set of properties. In the case of topological quantum matter, these properties are associated with topological invariants that take specific values for each equivalence class. Perturbing a gapped state that corresponds to a given topological phase (i.e., smoothly deforming the Hamiltonian of the system) does not affect the topological invariant, as long as the bulk energy gap remains finite. The value of this invariant changes only if the system undergoes a quantum phase transition, which is signaled by the collapse of the gap. Full topological protection can only emerge in interacting systems and requires the presence of long-range entanglement, which is at the origin of intrinsic topological order. However, topological properties protected by symmetries emerge even in noninteracting systems and, perhaps surprisingly, can be described within the framework of good old band theory of solids. Systems belonging to this category are generically called topological insulators, after the class of materials that is largely responsible for the recent surge in research on topological matter. In addition, topological band theory considerations can also be applied to superconductors (and superfluids), as described at the mean-field level using Bogoliubov–de Gennes theory. This chapter summarizes the key ideas behind the topological classification of noninteracting systems and discusses the basic properties of various classes of topological insulators and superconductors. For in-depth discussions and related developments the reader is referred to a number of books [ 54 , 175 , 469 ] and review papers [ 23 , 239 , 240 , 421 ] specifically dedicated to this subject.
Topological insulators and superconductors are subsets of (almost) noninteracting symmetry protected topological (SPT) phases. More generally, SPT phases represent equivalence classes of (equilibrium) gapped quantum states with short-range entanglement that are protected by certain symmetries. Two quantum states are “equivalent” if they can be adiabatically deformed into one another without closing the bulk gap. Thus, quantum states belonging to different SPT phases cannot be smoothly deformed into each other without a phase transition, as long as the underlying symmetry is preserved. However, upon removing the symmetry all SPT states can be adiabatically deformed to a trivial product state (e.g., an atomic insulator) without undergoing a phase transition. In this chapter, we generalize our discussion of (almost) noninteracting topological states by removing some of the explicit and implicit constraints underlying the classification and properties of topological insulators and superconductors discussed in Chapter 3 . In Section 4.1 , we enlarge the type of symmetries that protect the topological phases by supplementing internal symmetries (e.g., time-reversal and particle-hole symmetries) with crystalline symmetries (e.g., mirror and rotation symmetries) and discuss topological crystalline insulators and superconductors , a subsets of SPT phases protected by internal and crystalline symmetries. In Section 4.2 , we remove the requirement of having a finite (bulk) gap and discuss Weyl semimetals – crystalline systems characterized by topologically protected bulk band degeneracy points separated in momentum space, which support low energy excitations that are massless chiral fermions, i.e., Weyl fermions. Finally, in Section 4.3 , we remove the condition of thermodynamic equilibrium and consider topological quantum states in periodically driven systems, focusing on the so-called Floquet topological insulators , which exhibit a richer topological structure than their static counterparts. We note that aspects regarding the effects of particle-particle interactions, including the emergence of topological order in systems with long-range entanglement, will be addressed in Chapter 5 . We also point out that the areas summarized in this chapter have grown tremendously in recent years and continue to grow; even a brief mentioning of all recent developments would be impossible within the constraints of a book chapter. Instead, we point out the key elements that determine the nontrivial topology of the quantum systems mentioned above, discuss specific manifestations of their topological properties (e.g., the presence of protected gapless states), and provide representative examples.
This dissertation discusses extensions of the theory of polarization in crystalline insulators. The notion that electronic wave functions of energy bands in crystalline insulators have Berry phases associated with the positions of electronic charge is at the basis of our understanding of topological band theory. We show, by using the Berry phase formulation and generalizations of it, as well as by exact diagonalization of tight-binding models, that crystalline insulators can generate charge and polarization patterns compatible with the notion of quadrupole and octupole electric moments. In the presence of certain symmetries, these moments are quantized, and their boundary signatures fractionalized. These higher multipole moments then correspond to new symmetry-protected topological phases (SPTs). A salient signature of these SPTs is the existence of zero-dimensional, corner-localized mid-gap energy states. We then study topological crystalline superconductors, in which these zero-dimensional mid-gap states amount to the existence of Majorana bound states (MBS). We thoroughly classify these systems when rotational group symmetries are enforced, and investigate the existence of zero-dimensional MBS trapped at topological defects in these crystals. The finding of these higher multipole moments or generalizations of them to other platforms constitute a new paradigm for the realization of symmetry protected topological phases.
The natural existence of crystalline symmetry in real materials manifests the importance of understanding crystalline symmetry-protected topological phases, especially for interacting systems. In this paper, we systematically construct and classify all the point-group crystalline topological superconductors and insulators in three-dimensional (3D) interacting fermion systems using the novel concept of a topological crystal. The corresponding higher-order topological surface theory can also be systematically studied via higher-order bulk-boundary correspondence. In particular, we discover several intrinsically interacting topological phases that cannot be realized in any free-fermion systems. Moreover, the crystalline equivalence principle for 3D interacting fermionic systems is also verified, with an additional subtle “twist” on the spin of fermions.