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arXiv:1403.3331 · Physical Review B

Topology of crystalline insulators and superconductors

Ken Shiozaki, Masatoshi Sato

Published Oct 10, 2014• 508 citations
arXivHTMLPDF

Abstract

We complete a classification of topological phases and their topological defects in crystalline insulators and superconductors. We consider topological phases and defects described by noninteracting Bloch and Bogoliubov--de Gennes Hamiltonians that support additional order-two spatial symmetry, besides any of 10 classes of symmetries defined by time-reversal symmetry and particle-hole symmetry. The additional order-two spatial symmetry we consider is general and it includes ${\mathbit{Z}}_{2}$ global symmetry, mirror reflection, twofold rotation, inversion, and their magnetic point group symmetries. We find that the topological periodic table shows a periodicity in the number of flipped coordinates under the order-two spatial symmetry, in addition to the Bott periodicity in the space dimensions. Various symmetry-protected topological phases and gapless modes will be identified and discussed in a unified framework. We also present topological classification of symmetry-protected Fermi points. The bulk classification and the surface Fermi point classification provide a realization of the bulk-boundary correspondence in terms of the $K$ theory.

DOI
10.1103/physrevb.90.165114

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We complete a classification of topological phases and their topological defects in crystalline insulators and superconductors. We consider topological phases and defects described by noninteracting Bloch and Bogoliubov--de Gennes Hamiltonians that support additional order-two spatial symmetry, besides any of 10 classes of symmetries defined by time-reversal symmetry and particle-hole symmetry. The additional order-two spatial symmetry we consider is general and it includes \mathbitZ2{\mathbit{Z}}_{2}\mathbitZ2​ global symmetry, mirror reflection, twofold rotation, inversion, and their magnetic point group symmetries. We find that the topological periodic table shows a periodicity in the number of flipped coordinates under the order-two spatial symmetry, in addition to the Bott periodicity in the space dimensions. Various symmetry-protected topological phases and gapless modes will be identified and discussed in a unified framework. We also present topological classification of symmetry-protected Fermi points. The bulk classification and the surface Fermi point classification provide a realization of the bulk-boundary correspondence in terms of the KKK theory.
Topological phases are quantum phases of matter that appear close to absolute zero temperature. In contrast to commonly known condensed phases of matter, such as a magnet or a superconductor, distinct topological phases may have the same symmetry. Instead, these phases are distinguished by the topology of the electronic wavefunction. Already the single-particle excitations described by band theory in an insulator or a metal or by Bogoliubov-de Gennes theory in a superconductor may have novel anomalous properties associated to their topology. This topological band theory is the subject of this thesis. We aim towards identifying the anomalous boundary and defect states associated to the topology of the band structure in crystalline insulators and superconductors. Furthermore, we determine criteria to easily identify the topological phases from the band structure of a given insulator or superconductor. In Chapter 2 we show that crystalline topological insulators and superconductors may host anomalous gapless or in-gap excitations on corners of a two-dimensional crystal or hinges of a three-dimensional crystal. These topological phases are called "second-order" according to the codimension "2" of their anomalous boundary states. We discuss the precise conditions for their appearance and when they can be linked to the bulk topology. Our discussion includes mirror, twofold-rotation and inversion as crystalline symmetries. In Chapter 3 we discuss the appearance of anomalous gapless or ingap states at defects in a crystalline insulator or superconductor. In particular, we link the existence of anomalous states at disclinations -- lattice defects that violate a rotation symmetry only locally -- to second-order topological crystalline phases. As a side product, we identify the possible contributions of other topological phases to the disclination anomaly. The results of this chapter allow to determine precisely how the disclination anomaly is linked to the bulk topology. In Chapter 4 we present how to construct "symmetry-based indicators" for topological superconductors that admit a description within the Bogoliubov-de Gennes framework. Symmetry-based indicators are necessary criteria for a given Bogoliubov-de Gennes Hamiltonian to realize a topological crystalline phase with anomalous boundary exitations. These criteria are formulated in terms of data from a small set of high-symmetry momenta only. Our approach guarantees to extract the maximal information on the anomalous boundary exitations that can be extracted from a point-wise evaluation of the Bogoliubov-de Gennes Hamiltonian. In the limit of weak superconducting pairing, our criteria can be formulated in terms of data from the normal-state band structure alone.
Topological insulators and superconductors are subsets of (almost) noninteracting symmetry protected topological (SPT) phases. More generally, SPT phases represent equivalence classes of (equilibrium) gapped quantum states with short-range entanglement that are protected by certain symmetries. Two quantum states are “equivalent” if they can be adiabatically deformed into one another without closing the bulk gap. Thus, quantum states belonging to different SPT phases cannot be smoothly deformed into each other without a phase transition, as long as the underlying symmetry is preserved. However, upon removing the symmetry all SPT states can be adiabatically deformed to a trivial product state (e.g., an atomic insulator) without undergoing a phase transition. In this chapter, we generalize our discussion of (almost) noninteracting topological states by removing some of the explicit and implicit constraints underlying the classification and properties of topological insulators and superconductors discussed in Chapter 3 . In Section 4.1 , we enlarge the type of symmetries that protect the topological phases by supplementing internal symmetries (e.g., time-reversal and particle-hole symmetries) with crystalline symmetries (e.g., mirror and rotation symmetries) and discuss topological crystalline insulators and superconductors , a subsets of SPT phases protected by internal and crystalline symmetries. In Section 4.2 , we remove the requirement of having a finite (bulk) gap and discuss Weyl semimetals – crystalline systems characterized by topologically protected bulk band degeneracy points separated in momentum space, which support low energy excitations that are massless chiral fermions, i.e., Weyl fermions. Finally, in Section 4.3 , we remove the condition of thermodynamic equilibrium and consider topological quantum states in periodically driven systems, focusing on the so-called Floquet topological insulators , which exhibit a richer topological structure than their static counterparts. We note that aspects regarding the effects of particle-particle interactions, including the emergence of topological order in systems with long-range entanglement, will be addressed in Chapter 5 . We also point out that the areas summarized in this chapter have grown tremendously in recent years and continue to grow; even a brief mentioning of all recent developments would be impossible within the constraints of a book chapter. Instead, we point out the key elements that determine the nontrivial topology of the quantum systems mentioned above, discuss specific manifestations of their topological properties (e.g., the presence of protected gapless states), and provide representative examples.
The imposition of crystalline symmetries is known to lead to a rich variety of insulating and superconducting topological phases. These include higher-order topological phases and obstructed atomic limits with and without filling anomalies. We here comprehensively classify such topological crystalline phases (TCPs) with mirror, twofold rotation, and inversion symmetries in the presence of disorder that preserves the crystalline symmetry on average. We find that the inclusion of disorder leads to a simplification of the classification in comparison to the clean case. We also find that, while clean TCPs evade a general bulk-boundary principle, disordered TCPs admit a complete bulk-boundary correspondence, according to which (bulk) topological phases are topologically equivalent if and only if they have the same anomalous boundary states and filling anomaly. We corroborate the stability of disordered TCPs by way of field-theoretic, numerical, and symmetry-based analyses in various case studies. While the boundary signatures of most disordered TCPs are similar to their clean counterparts, the addition of disorder to certain mirror-symmetric TCPs results in novel higher-order statistical topological phases, in which zero-energy hinge states have critical wave-function statistics, while remaining protected from Anderson localization.
The natural existence of crystalline symmetry in real materials manifests the importance of understanding crystalline symmetry-protected topological phases, especially for interacting systems. In this paper, we systematically construct and classify all the point-group crystalline topological superconductors and insulators in three-dimensional (3D) interacting fermion systems using the novel concept of a topological crystal. The corresponding higher-order topological surface theory can also be systematically studied via higher-order bulk-boundary correspondence. In particular, we discover several intrinsically interacting topological phases that cannot be realized in any free-fermion systems. Moreover, the crystalline equivalence principle for 3D interacting fermionic systems is also verified, with an additional subtle “twist” on the spin of fermions.
Three dimensional topological insulator represents a class of novel quantum phases hosting robust gapless boundary excitations, which is protected by global symmetries such as time reversal, charge conservation and spin rotational symmetry. In this work we systematically study another class of topological phases of weakly interacting electrons protected by spatial inversion symmetry, which generally don't support stable gapless boundary states. We classify these inversion-symmetric topological insulators and superconductors in the framework of K-theory, and construct their lattice models. We also discuss quantized response functions of these inversion-protected topological phases, which serve as their experimental signatures.
The celebrated tenfold way of Altland-Zirnbauer symmetry classes discern any quantum system by its pattern of nonspatial symmetries.It lays at the core of the periodic table of topological insulators and superconductors which provided a complete classification of weakly interacting electrons' noncrystalline topological phases for all symmetry classes.Over recent years, a plethora of topological phenomena with diverse surface states has been discovered in crystalline materials.In this paper, we obtain an exhaustive classification of topologically distinct ground states as well as topological phases with anomalous surface states of crystalline topological insulators and superconductors for key space-groups, layer-groups, and rod-groups.This is done in a unified manner for the full tenfold way of Altland-Zirnbauer nonspatial symmetry classes.We establish a comprehensive paradigm that harnesses the modern mathematical framework of equivariant spectra; it allows us to obtain results applicable to generic topological classification problems.In particular, this paradigm provides efficient computational tools that enable an inherently unified treatment of the full tenfold way.