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Quantum thermal cycles based on non-resonant exchange interactions

Nicolò Piccione, Gabriele De Chiara, Bruno Bellomo

Published Oct 7, 2020• 1 citation
OpenAlex

Abstract

We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, non-resonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of equivalent Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.

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We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, nonresonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of ``equivalent'' Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.

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We put forward four schemes of a coupled-qubit quantum Otto machine, a generalization of the single-qubit quantum Otto machine, based on work and heat transfer between an internal system consisting of a coupled pair of qubits and an external environment consisting of two heat baths and two work storages. The four schemes of our model are defined by the positions of attaching the heat baths, which play a key role in the power of the coupled-qubit engine. First, for the single-qubit heat engine, we find a maximum-power relation, and the fact that its efficiency at the maximum power is equal to the Otto efficiency, which is greater than the Curzon-Ahlborn efficiency. Second, we compare the coupled-qubit engines to the single-qubit engine from the point of view of achieving the maximum power based on the same energy-level change for work production and find that the coupling between the two qubits can lead to greater powers but the system efficiency at the maximum power is lower than the single-qubit system's efficiency and the Curzon-Ahlborn efficiency. Published by the American Physical Society 2024

arXiv:2305.08440•Physical Review Research•May 15, 2024•6 citations
We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, non-resonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of equivalent Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.
We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, nonresonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of ``equivalent'' Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.
Algebraic methods for solving time-dependent Hamiltonians are used to investigate the performance of quantum thermal machines. We investigate the thermodynamic properties of an engine formed by two coupled qubits, performing an Otto cycle. The thermal interaction occurs with two baths at different temperatures, while work is associated with the interaction with an arbitrary time-dependent magnetic field that varies in intensity and direction. For the coupling, we consider the 1D isotropic Heisenberg model, which allows us to describe the system by means of the irreducible representation of the su(2)\mathrm{su}(2)su(2) Lie algebra within the triplet subspace. We also inspect different settings of the temperatures and frequencies of the cycle, and investigate the corresponding operation regimes. We describe how these regimes can change with the speed of the protocol. Finally, we compare the weak and strong coupling regimes, and conclude that for the weak case the efficiency is optimal and can surpass the value of the classical Otto cycle. For low temperatures of the heat baths, we show that losses due to quantum friction are reduced in the strong coupling limit.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
We propose a thermodynamic cycle similar to the Otto cycle with a two-qubit working substance such that one of its isochoric strokes is provided by a controllable quantum measurement. We show that the measurement device can affect the working substance in four possible ways, as well as the energy exchanges between the working substance and an external work source during the isentropic strokes take place in two possible ways. By these considerations, we obtain eight thermal machines, each of which works individually in engine, accelerator, or refrigerator modes. We show that, for half of the obtained thermal machines, the applied quantum measurement causes their respective performances to go higher than the corresponding regular Otto limits, while the remainder go lower than the mentioned limits. Interestingly, it is shown that the performance of each thermal machine explicitly depends on the strength parameters of applied measurement, which in turn are related to coupling constants of the working substance and measurement device. These findings highlight that the role of generalized measurements as nonequilibrium quantum resources is not always constructive in powering the thermal machines.
We put forward four schemes of a coupled-qubit quantum Otto machine, a generalization of the single-qubit quantum Otto machine, based on work and heat transfer between an internal system consisting of a coupled pair of qubits and an external environment consisting of two heat baths and two work storages. The four schemes of our model are defined by the positions of attaching the heat baths, which play a key role in the power of the coupled-qubit engine. First, for the single-qubit heat engine, we find a maximum-power relation, and the fact that its efficiency at the maximum power is equal to the Otto efficiency, which is greater than the Curzon-Ahlborn efficiency. Second, we compare the coupled-qubit engines to the single-qubit engine from the point of view of achieving the maximum power based on the same energy-level change for work production and find that the coupling between the two qubits can lead to greater powers but the system efficiency at the maximum power is lower than the single-qubit system's efficiency and the Curzon-Ahlborn efficiency. Published by the American Physical Society 2024