We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, non-resonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of equivalent Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, non-resonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of equivalent Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.

Oct 7, 20201 citation

Maximum power of coupled-qubit Otto engines

Jingyi Gao, Naomichi Hatano

We put forward four schemes of a coupled-qubit quantum Otto machine, a generalization of the single-qubit quantum Otto machine, based on work and heat transfer between an internal system consisting of a coupled pair of qubits and an external environment consisting of two heat baths and two work storages. The four schemes of our model are defined by the positions of attaching the heat baths, which play a key role in the power of the coupled-qubit engine. First, for the single-qubit heat engine, we find a maximum-power relation, and the fact that its efficiency at the maximum power is equal to the Otto efficiency, which is greater than the Curzon-Ahlborn efficiency. Second, we compare the coupled-qubit engines to the single-qubit engine from the point of view of achieving the maximum power based on the same energy-level change for work production and find that the coupling between the two qubits can lead to greater powers but the system efficiency at the maximum power is lower than the single-qubit system's efficiency and the Curzon-Ahlborn efficiency. Published by the American Physical Society 2024We put forward four schemes of a coupled-qubit quantum Otto machine, a generalization of the single-qubit quantum Otto machine, based on work and heat transfer between an internal system consisting of a coupled pair of qubits and an external environment consisting of two heat baths and two work storages. The four schemes of our model are defined by the positions of attaching the heat baths, which play a key role in the power of the coupled-qubit engine. First, for the single-qubit heat engine, we find a maximum-power relation, and the fact that its efficiency at the maximum power is equal to the Otto efficiency, which is greater than the Curzon-Ahlborn efficiency. Second, we compare the coupled-qubit engines to the single-qubit engine from the point of view of achieving the maximum power based on the same energy-level change for work production and find that the coupling between the two qubits can lead to greater powers but the system efficiency at the maximum power is lower than the single-qubit system's efficiency and the Curzon-Ahlborn efficiency. Published by the American Physical Society 2024

arXiv:2305.08440Physical Review ResearchMay 15, 20246 citations

The Quantum Harmonic Otto Cycle

Ronnie Kosloff, Yair Rezek

The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.

arXiv:1612.03582EntropyMar 23, 2017373 citations

Maximum Power and Corresponding Efficiency for Two-Level Quantum Heat Engines and Refrigerators

Paolo Andrea Erdman, Vasco Cavina, Rosario Fazio +2 more

We study how to achieve the ultimate power in the simplest, yet non trivial, model of a thermal machine, namely a two-level quantum system coupled to two thermal baths. We find that, regardless of the microscopic details and of the operating mode of the thermal machine, the maximum power is achieved through an Otto cycle in which the controls are rapidly switched between two extremal values. A closed formula for the maximum power is derived, and the experimental feasibility of the protocol is discussed. Our findings extend the analysis done in the literature on the efficiency at maximum power (EMP) to engines operating at the ultimate performace, which is strongly away from the quasi static regime, and shed new light on the universal role of the EMP. In particular we show that by employing proper energy filters to mediate the system-baths interactions, both the EMP of heat engines and the coefficient of performance at maximum power of refrigerators can approach Carnot's bound with arbitrary accuracy.We study how to achieve the ultimate power in the simplest, yet non trivial, model of a thermal machine, namely a two-level quantum system coupled to two thermal baths. We find that, regardless of the microscopic details and of the operating mode of the thermal machine, the maximum power is achieved through an Otto cycle in which the controls are rapidly switched between two extremal values. A closed formula for the maximum power is derived, and the experimental feasibility of the protocol is discussed. Our findings extend the analysis done in the literature on the efficiency at maximum power (EMP) to engines operating at the ultimate performace, which is strongly away from the quasi static regime, and shed new light on the universal role of the EMP. In particular we show that by employing proper energy filters to mediate the system-baths interactions, both the EMP of heat engines and the coefficient of performance at maximum power of refrigerators can approach Carnot's bound with arbitrary accuracy.

Dec 12, 20187 citations

Algebraic approach to a nonadiabatic coupled Otto cycle

Alan Duriez, D. Martínez-Tibaduiza, Antonio Zelaquett Khoury

Algebraic methods for solving time-dependent Hamiltonians are used to investigate the performance of quantum thermal machines. We investigate the thermodynamic properties of an engine formed by two coupled qubits, performing an Otto cycle. The thermal interaction occurs with two baths at different temperatures, while work is associated with the interaction with an arbitrary time-dependent magnetic field that varies in intensity and direction. For the coupling, we consider the 1D isotropic Heisenberg model, which allows us to describe the system by means of the irreducible representation of the $\mathrm{su}(2)$ Lie algebra within the triplet subspace. We also inspect different settings of the temperatures and frequencies of the cycle, and investigate the corresponding operation regimes. We describe how these regimes can change with the speed of the protocol. Finally, we compare the weak and strong coupling regimes, and conclude that for the weak case the efficiency is optimal and can surpass the value of the classical Otto cycle. For low temperatures of the heat baths, we show that losses due to quantum friction are reduced in the strong coupling limit.Algebraic methods for solving time-dependent Hamiltonians are used to investigate the performance of quantum thermal machines. We investigate the thermodynamic properties of an engine formed by two coupled qubits, performing an Otto cycle. The thermal interaction occurs with two baths at different temperatures, while work is associated with the interaction with an arbitrary time-dependent magnetic field that varies in intensity and direction. For the coupling, we consider the 1D isotropic Heisenberg model, which allows us to describe the system by means of the irreducible representation of the $\mathrm{su}(2)$ Lie algebra within the triplet subspace. We also inspect different settings of the temperatures and frequencies of the cycle, and investigate the corresponding operation regimes. We describe how these regimes can change with the speed of the protocol. Finally, we compare the weak and strong coupling regimes, and conclude that for the weak case the efficiency is optimal and can surpass the value of the classical Otto cycle. For low temperatures of the heat baths, we show that losses due to quantum friction are reduced in the strong coupling limit.

arXiv:2208.04917Physical Review ADec 19, 20224 citations

Efficiency of Harmonic Quantum Otto Engines at Maximal Power

Sebastian Deffner

Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon-Ahlborn efficiency. This is rather remarkable as the Curzon-Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as Curzon and Ahlborn's original treatment. We find that for endoreversible Otto cycles in classical harmonic oscillators the efficiency at maximal power is, indeed, given by the Curzon-Ahlborn efficiency. However, we also find that the efficiency of Otto engines made of quantum harmonic oscillators is significantly larger.Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon-Ahlborn efficiency. This is rather remarkable as the Curzon-Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as Curzon and Ahlborn's original treatment. We find that for endoreversible Otto cycles in classical harmonic oscillators the efficiency at maximal power is, indeed, given by the Curzon-Ahlborn efficiency. However, we also find that the efficiency of Otto engines made of quantum harmonic oscillators is significantly larger.

arXiv:1810.09371EntropyNov 15, 2018109 citations

\mathrm{su}(2)

Lie algebra within the triplet subspace. We also inspect different settings of the temperatures and frequencies of the cycle, and investigate the corresponding operation regimes. We describe how these regimes can change with the speed of the protocol. Finally, we compare the weak and strong coupling regimes, and conclude that for the weak case the efficiency is optimal and can surpass the value of the classical Otto cycle. For low temperatures of the heat baths, we show that losses due to quantum friction are reduced in the strong coupling limit.