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arXiv:1810.09371 · Entropy

Efficiency of Harmonic Quantum Otto Engines at Maximal Power

Sebastian Deffner

Published Nov 15, 2018• 109 citations
arXivHTMLPDF

Abstract

Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon-Ahlborn efficiency. This is rather remarkable as the Curzon-Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as Curzon and Ahlborn's original treatment. We find that for endoreversible Otto cycles in classical harmonic oscillators the efficiency at maximal power is, indeed, given by the Curzon-Ahlborn efficiency. However, we also find that the efficiency of Otto engines made of quantum harmonic oscillators is significantly larger.

DOI
10.3390/e20110875

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Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon-Ahlborn efficiency. This is rather remarkable as the Curzon-Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as Curzon and Ahlborn's original treatment. We find that for endoreversible Otto cycles in classical harmonic oscillators the efficiency at maximal power is, indeed, given by the Curzon-Ahlborn efficiency. However, we also find that the efficiency of Otto engines made of quantum harmonic oscillators is significantly larger.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.
We study a quantum Otto engine at finite time, where the working substance is composed of a two-level system interacting with a harmonic oscillator, described by the quantum Rabi model. We obtain the limit cycle and calculate the total work extracted, efficiency, and power of the engine by numerically solving the master equation describing the open system dynamics. We relate the total work extracted and the efficiency at maximum power with the quantum correlations embedded in the working substance, which we consider through entanglement of formation and quantum discord. Interestingly, we find that the engine can overcome the Curzon-Ahlborn efficiency when the working substance is in the ultrastrong coupling regime. This high-efficiency regime roughly coincides with the cases where the entanglement in the working substance experiences the greatest reduction in the hot isochoric stage. Our results highlight the efficiency performance of correlated working substances for quantum heat engines.
We put forward four schemes of a coupled-qubit quantum Otto machine, a generalization of the single-qubit quantum Otto machine, based on work and heat transfer between an internal system consisting of a coupled pair of qubits and an external environment consisting of two heat baths and two work storages. The four schemes of our model are defined by the positions of attaching the heat baths, which play a key role in the power of the coupled-qubit engine. First, for the single-qubit heat engine, we find a maximum-power relation, and the fact that its efficiency at the maximum power is equal to the Otto efficiency, which is greater than the Curzon-Ahlborn efficiency. Second, we compare the coupled-qubit engines to the single-qubit engine from the point of view of achieving the maximum power based on the same energy-level change for work production and find that the coupling between the two qubits can lead to greater powers but the system efficiency at the maximum power is lower than the single-qubit system's efficiency and the Curzon-Ahlborn efficiency. Published by the American Physical Society 2024
From an entropy-based formulation of the first law of thermodynamics in the quantum regime, we investigate the performance of Otto-like and Carnot-like engines for a single-qubit working medium. Within this framework, the first law includes an additional contribution-coherence work-that quantifies the energetic cost of deviating the quantum trajectory from its natural unitary evolution. We focus on the efficiency of the heat-to-coherence work conversion and show that the Carnot cycle achieves the classical Carnot efficiency, while the performance of the Otto cycle is upper-bounded by the Carnot efficiency corresponding to the extreme temperatures of the cycle. We identify entropy generation during the isochoric stages as the key source of irreversibility limiting the Otto cycle's efficiency.
We consider the efficiency at maximum power of a quantum Otto engine, which uses a spin or a harmonic system as its working substance and works between two heat reservoirs at constant temperatures Th{T}_{h}Th​ and Tc{T}_{c}Tc​ (<Th)(<{T}_{h})(<Th​). Although the behavior of spin-1/21/21/2 system differs substantially from that of the harmonic system in that they obey two typical quantum statistics, the efficiencies at maximum power based on these two different kinds of quantum systems are bounded from the upper side by the same expression ${\ensuremath{\eta}}_{\mathrm{mp}}\ensuremath{\le}{\ensuremath{\eta}}_{+}\ensuremath{\equiv}{\ensuremath{\eta}}_{C}^{2}/[{\ensuremath{\eta}}_{C}\ensuremath{-}(1\ensuremath{-}{\ensuremath{\eta}}_{C})ln(1\ensuremath{-}{\ensuremath{\eta}}_{C})]$ with ${\ensuremath{\eta}}_{C}=1\ensuremath{-}{T}_{c}/{T}_{h}$ as the Carnot efficiency. This expression ${\ensuremath{\eta}}_{\mathrm{mp}}$ possesses the same universality of the CA efficiency ${\ensuremath{\eta}}_{\mathrm{CA}}=1\ensuremath{-}\sqrt{1\ensuremath{-}{\ensuremath{\eta}}_{C}}$ at small relative temperature difference. Within the context of irreversible thermodynamics, we calculate the Onsager coefficients and show that the value of ${\ensuremath{\eta}}_{\mathrm{CA}}$ is indeed the upper bound of EMP for an Otto engine working in the linear-response regime.
Thermodynamic constraints impose a trade-off between power and efficiency in heat engines, preventing the simultaneous achievement of high power and high efficiency. For classical microscopic engines, explicit inequalities have been discovered, demonstrating the inherent inevitability of this power-efficiency trade-off. However, extensions of these results to quantum engines have so far been limited to cases of slow operation. In this study, we derive a power-efficiency trade-off relation for a paradigmatic quantum engine operating within a finite time, specifically the Otto cycle of a quantum harmonic oscillator. By utilizing a phase-space approach based on quasiprobability representations, we establish a universal trade-off relation applicable to arbitrary time-dependent protocols during the adiabatic processes. Our results reveal that the power of the quantum engine vanishes as the efficiency approaches the quantum-mechanical efficiency bound, which is stricter than the Carnot bound. Furthermore, we identify the conditions under which the upper bound is attained, which indicate maximum power is achieved when the generation of quantum coherence is reduced, and the difference in time durations of the isochoric processes increases. These findings are validated through numerical calculations, which confirm their applicability across various types of protocols for heat engine cycles.