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Annales Universitatis Paedagogicae Cracoviensis Studia Mathematica

Solutions of the time-independent Schrödinger equation by uniformization on the unit circle

Kazimierz Rajchel

Published Oct 31, 2019• 0 citations
Publisher

Abstract

Abstract The idea presented here of a general quantization rule for bound states is mainly based on the Riccati equation which is a result of the transformed, time-independent, one-dimensional Schrödinger equation. The condition imposed on the logarithmic derivative of the ground state function W 0 allows to present the Riccati equation as the unit circle equation with winding number equal to one which, by appropriately chosen transformations, can be converted into the unit circle equation with multiple winding number. As a consequence, a completely new quantization condition, which gives exact results for any quantum number, is obtained.

DOI
10.2478/aupcsm-2019-0012

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Abstract The idea presented here of a general quantization rule for bound states is mainly based on the Riccati equation which is a result of the transformed, time-independent, one-dimensional Schrödinger equation. The condition imposed on the logarithmic derivative of the ground state function W 0 allows to present the Riccati equation as the unit circle equation with winding number equal to one which, by appropriately chosen transformations, can be converted into the unit circle equation with multiple winding number. As a consequence, a completely new quantization condition, which gives exact results for any quantum number, is obtained.
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The method of Froman and Froman for proving exact quantization conditions is reviewed. This formalism, unlike the usual WKB approximation to which it bears a close resemblance, requires consideration of the behavior of the potential everywhere it is defined. This approach leads to proofs that certain quantization conditions are exact without having to compare the results to solutions of the Schrödinger equation obtained by other means. Using the formalism, we prove the correctness of all previously known exact quantization rules for the one-dimensional and radial cases. Furthermore, it is shown that exact quantization rules can be proved for two other potentials. For one of these, no analytic solutions to the Schrödinger equation are known. For the latter case, the proof is checked by numerical integration of the Schrödinger equation for a special case.
A simple procedure has been found for the general solution of the time-independent Schrödinger equation (SE) with the help of quantization of potential area in one dimension without making any approximation. Energy values are not dependent on wave functions. So, to find the energy values, it is enough to find the classic turning points of the potential function. Two different solutions were obtained, namely, symmetric and antisymmetric in bound states. These normalized wave functions are always periodic. It is enough to take the integral of the square root of the potential energy function to find the normalized wave functions. If these calculations cannot be made analytically, they should then be performed by numerical methods. The SE has been solved for a particle in many one-dimension and the spherical symmetric central potential wells as examples. Their energies and normalized wave functions were found as examples. These solutions were also applied to the theories of scattering and alpha decay. The results obtained with the experimental values were compared with the calculated values. One was seen to be very fit.
Analytical solutions to the time-dependent Shrödinger equation in one dimension are developed for time-independent potentials, one consisting of an infinite wall and a repulsive delta function. An exact solution is obtained by means of a convolution of time-independent solutions spanning the given Hilbert space with appropriately chosen spectral functions. Square-integrability and the boundary conditions are satisfied. The probability for the particle to be found inside the potential well is calculated and shown to exhibit non-exponential decay decreasing at large times as t−3t^{-3}t−3. The result is generalized for all square-integrable solutions to this problem.