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Journal of Mathematical Physics

Exact Quantization Conditions

C. Rosenzweig, Joseph B. Krieger

Published Jun 1, 1968• 64 citations
Publisher

Abstract

The method of Froman and Froman for proving exact quantization conditions is reviewed. This formalism, unlike the usual WKB approximation to which it bears a close resemblance, requires consideration of the behavior of the potential everywhere it is defined. This approach leads to proofs that certain quantization conditions are exact without having to compare the results to solutions of the Schrödinger equation obtained by other means. Using the formalism, we prove the correctness of all previously known exact quantization rules for the one-dimensional and radial cases. Furthermore, it is shown that exact quantization rules can be proved for two other potentials. For one of these, no analytic solutions to the Schrödinger equation are known. For the latter case, the proof is checked by numerical integration of the Schrödinger equation for a special case.

DOI
10.1063/1.1664651

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American Journal of Physics•Apr 1, 1971•0 citations
The method of Froman and Froman for proving exact quantization conditions is reviewed. This formalism, unlike the usual WKB approximation to which it bears a close resemblance, requires consideration of the behavior of the potential everywhere it is defined. This approach leads to proofs that certain quantization conditions are exact without having to compare the results to solutions of the Schrödinger equation obtained by other means. Using the formalism, we prove the correctness of all previously known exact quantization rules for the one-dimensional and radial cases. Furthermore, it is shown that exact quantization rules can be proved for two other potentials. For one of these, no analytic solutions to the Schrödinger equation are known. For the latter case, the proof is checked by numerical integration of the Schrödinger equation for a special case.
By employing coordinate transformations, a generalized WKB quantization condition is derived which includes a modified WKB quantization rule and the related higher-order integrals. It is observed that a necessary condition for the first-order integral to give an exact quantization rule is the vanishing of the higher-order integrals. When this condition is satisfied, the resulting quantization condition is of the form of all previously known exact-quantization rules. The higher-order integrals are shown to vanish for certain cases of interest. An error in Paper I [C. Rosenzweig and J. B. Krieger, J. Math. Phys. 9, 849 (1968)] is noted and an examination of the higher-order integrals shows that a proposed quantization rule given there is not exact.
An algebraic reformulation of the Bohr - Sommerfeld (BS) quantization rule is suggested and applied to the study of bound states in one-dimensional quantum wells. The energies obtained with the present quantization rule are compared to those obtained with the usual BS and WKB quantization rules and with the exact solution of the Schrödinger equation. We find that, in diverse cases of physical interest in molecular physics, the present quantization rule not only yields a good approximation to the exact solution of the Schrödinger equation, but yields more precise energies than those obtained with the usual BS and/or WKB quantization rules. Among the examples considered numerically are the Poeschl - Teller potential and several anharmonic oscillator potentials, which simulate molecular vibrational spectra and the problem of an isolated quantum well structure subject to an external electric field.
Abstract. – An exact quantization rule for the Schrödinger equation is presented. In the exact quantization rule, in addition to Nπ, there is an integral term, called the quantum correction. For the exactly solvable systems we find that the quantum correction is an invariant, independent of the number of nodes in the wave function. In those systems, the energy levels of all the bound states can be easily calculated from the exact quantization rule and the solution for the ground state, which can be obtained by solving the Riccati equation. With this new method, we re-calculate the energy levels for the one-dimensional systems with a finite square well, with the Morse potential, with the symmetric and asymmetric Rosen-Morse potentials, and with the first and the second Pöschl-Teller potentials, for the harmonic oscillators both in one dimension and in three dimensions, and for the hydrogen atom. In the development of quantum mechanics, the Bohr-Sommerfeld quantization rules of the old quantum theory [1] occupy a position intermediate between classical and quantum mechanics. The WKB approximation [2–4] is a method for the approximate treatment of the Schrödinger wave function with another quantization rule [1]. Both quantization rules are approximate. We are going to derive an exact quantization rule for the one-dimensional Schrödinger equation: d2 ψ(x) = −2M dx2 2 [E − V (x)] ψ(x), (1) ¯h where M is the mass of the particle, and the potential V (x) is a piecewise continuous real function of x satisfying for definiteness V (x)> E, − ∞ < x < xA or xB < x < ∞, V (x) = E, x = xA or x = xB, V (x) < E, xA < x < xB, (2) where xA and xB are two turning points. Between two turning points, the momentum is k(x) = √ 2M [E − V (x)]/¯h.
A formalism that utilizes the analytic transfer matrix technique is applied to the Schr\"odinger equation. This approach leads to proofs that the phase loss at a turning point is exactly equal to \ensuremath{\pi}. We also show the existence of the phase contributions devoted by the scattered subwaves, which to our knowledge, have never been taken into account in previous works. Subsequently, an exact quantization condition, which differs essentially from the WKB method, is introduced for arbitrary potential wells.
The WKB wavefunctions for one-dimensional nonrelativistic problems are derived by a simple transformation method. By applying the Liouville substitution to Schrödinger's equation and then neglecting certain “small” terms in the transformed equation, one arrives at the WKB solutions. The terms neglected in obtaining the WKB solutions are explicit. No asymptotic expansions are used in the derivation. Use of a known criterion from the theory of differential equations gives assurance that the WKB solutions are asymptotic to exact solutions of Schrödinger's equation in certain cases.